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Chert () is a hard, fine-grained
sedimentary rock Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
composed of
microcrystalline A microcrystalline material is a crystallized substance or rock that contains small crystals visible only through microscopic examination. There is little agreement on the range of crystal sizes that should be regarded as microcrystalline, but the ...
or
cryptocrystalline Cryptocrystalline is a rock microstructure, rock texture made up of such minute crystals that its crystalline nature is only vaguely revealed even microscopically in thin section by transmitted polarized light. Among the sedimentary rocks, chert a ...
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
, the mineral form of
silicon dioxide Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
(SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a chemical precipitate or a
diagenetic Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a ...
replacement, as in
petrified wood Petrified wood, also known as petrified tree (from Ancient Greek meaning 'rock' or 'stone'; literally 'wood turned into stone'), is the name given to a special type of ''fossilized wood'', the fossilized remains of terrestrial vegetation. ''P ...
. Chert is typically composed of the petrified remains of
siliceous ooze Siliceous ooze is a type of biogenic pelagic sediment located on the deep ocean floor. Siliceous oozes are the least common of the deep sea sediments, and make up approximately 15% of the ocean floor. Oozes are defined as sediments which contain a ...
, the biogenic sediment that covers large areas of the deep ocean floor, and which contains the silicon skeletal remains of
diatom A diatom (Neo-Latin ''diatoma''), "a cutting through, a severance", from el, διάτομος, diátomos, "cut in half, divided equally" from el, διατέμνω, diatémno, "to cut in twain". is any member of a large group comprising sev ...
s, silicoflagellates, and
radiolaria The Radiolaria, also called Radiozoa, are protozoa of diameter 0.1–0.2 mm that produce intricate mineral skeletons, typically with a central capsule dividing the cell (biology), cell into the inner and outer portions of endoplasm and Ecto ...
ns.
Precambrian The Precambrian (or Pre-Cambrian, sometimes abbreviated pꞒ, or Cryptozoic) is the earliest part of Earth's history, set before the current Phanerozoic Eon. The Precambrian is so named because it preceded the Cambrian, the first period of the ...
cherts are notable for the presence of fossil
cyanobacteria Cyanobacteria (), also known as Cyanophyta, are a phylum of gram-negative bacteria that obtain energy via photosynthesis. The name ''cyanobacteria'' refers to their color (), which similarly forms the basis of cyanobacteria's common name, blu ...
. In addition to
microfossils A microfossil is a fossil that is generally between 0.001 mm and 1 mm in size, the visual study of which requires the use of light or electron microscopy. A fossil which can be studied with the naked eye or low-powered magnification, ...
, chert occasionally contains
macrofossil Macrofossils, also known as megafossils, are preserved organic remains large enough to be visible without a microscope. The term ''macrofossil'' stands in opposition to the term microfossil. Microfossils, by contrast, require substantial magnific ...
s. However, some chert is devoid of any fossils. Chert varies greatly in color (from white to black), but most often manifests as gray, brown, grayish brown and light green to rusty redW.L. Roberts, T.J. Campbell, G.R. Rapp Jr., "Encyclopedia of Mineralogy, Second Edition", 1990. R.S. Mitchell, "Dictionary of Rocks", 1985. (occasionally dark green); its color is an expression of trace elements present in the rock, and both red and green are most often related to traces of iron (in its oxidized and reduced forms, respectively).


Description

In
petrology Petrology () is the branch of geology that studies rocks and the conditions under which they form. Petrology has three subdivisions: igneous, metamorphic, and sedimentary petrology. Igneous and metamorphic petrology are commonly taught together ...
, the term "chert" refers generally to all chemically precipitated
sedimentary rocks Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles t ...
composed primarily of
microcrystalline A microcrystalline material is a crystallized substance or rock that contains small crystals visible only through microscopic examination. There is little agreement on the range of crystal sizes that should be regarded as microcrystalline, but the ...
,
cryptocrystalline Cryptocrystalline is a rock microstructure, rock texture made up of such minute crystals that its crystalline nature is only vaguely revealed even microscopically in thin section by transmitted polarized light. Among the sedimentary rocks, chert a ...
and microfibrous
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
. Most cherts are nearly pure silica, with less than 5% other minerals (mostly
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
,
dolomite Dolomite may refer to: *Dolomite (mineral), a carbonate mineral *Dolomite (rock), also known as dolostone, a sedimentary carbonate rock *Dolomite, Alabama, United States, an unincorporated community *Dolomite, California, United States, an unincor ...
,
clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
,
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
, and organic matter.) However, cherts range from very pure cherts with over 99% silica content to impure nodular cherts with less than 65% silica content. Aluminium is the most abundant minor element, followed by iron and
manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...
or
potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosphe ...
,
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...
, and
calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to ...
. Extracrystalline water (tiny inclusions of water within and around the quartz grains) make up less than 1% of most cherts. The
Folk classification The Folk classification, in geology, is a technical descriptive classification of sedimentary rocks devised by Robert L. Folk, an influential sedimentary petrologist and Professor Emeritus at the University of Texas. Folk's sandstone (clastic) c ...
divides chert into three textural categories. Granular microquartz is the component of chert consisting of roughly equidimensional
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
grains, ranging in size from a fraction of a micron to 20 microns, but most typically 8 to 10 microns.
Chalcedony Chalcedony ( , or ) is a cryptocrystalline form of silica, composed of very fine intergrowths of quartz and moganite. These are both silica minerals, but they differ in that quartz has a trigonal crystal structure, while moganite is monoclinic. ...
is a microfibrous variety of quartz, consisting of radiating bundles of very thin crystals about 100 microns long. Megaquartz is composed of equidimensional grains over 20 microns in size. Most chert is microcrystalline quartz with minor chalcedony and sometimes
opal Opal is a hydrated amorphous form of silica (SiO2·''n''H2O); its water content may range from 3 to 21% by weight, but is usually between 6 and 10%. Due to its amorphous property, it is classified as a mineraloid, unlike crystalline forms ...
, but cherts range from nearly pure opal to nearly pure quartz chert. However, little opal is over 60 million years old. Opaline chert often contains visible fossils of
diatoms A diatom (New Latin, Neo-Latin ''diatoma''), "a cutting through, a severance", from el, διάτομος, diátomos, "cut in half, divided equally" from el, διατέμνω, diatémno, "to cut in twain". is any member of a large group com ...
,
radiolarians The Radiolaria, also called Radiozoa, are protozoa of diameter 0.1–0.2 mm that produce intricate mineral skeletons, typically with a central capsule dividing the cell into the inner and outer portions of endoplasm and ectoplasm. The elab ...
, and
glass sponge Hexactinellid sponges are sponges with a skeleton made of four- and/or six-pointed siliceous spicules, often referred to as glass sponges. They are usually classified along with other sponges in the phylum Porifera, but some researchers consider ...
spicules Spicules are any of various small needle-like anatomical structures occurring in organisms Spicule may also refer to: *Spicule (sponge), small skeletal elements of sea sponges *Spicule (nematode), reproductive structures found in male nematodes ( ...
. Chert is found in settings as diverse as
hot spring A hot spring, hydrothermal spring, or geothermal spring is a spring produced by the emergence of geothermally heated groundwater onto the surface of the Earth. The groundwater is heated either by shallow bodies of magma (molten rock) or by circ ...
deposits (''
siliceous sinter Geyserite, or siliceous sinter, is a form of opaline silica that is often found as crusts or layers around hot springs and geysers. Botryoidal geyserite is known as fiorite. Geyserite is porous due to the silica enclosing many small cavities. Si ...
''),
banded iron formation Banded iron formations (also known as banded ironstone formations or BIFs) are distinctive units of sedimentary rock consisting of alternating layers of iron oxides and iron-poor chert. They can be up to several hundred meters in thickness a ...
(''
jaspilite Jaspillite, or ''jaspilite'' also ''itabirite'', is a chemical rock formed similar to chert, but is generally quite iron rich. It is also known as ''jasper taconite''. Jaspillite is typically a banded mixture of hematite and quartz common in the ...
''), or
alkaline lake A soda lake or alkaline lake is a lake on the strongly alkaline side of neutrality, typically with a pH, pH value between 9 and 12. They are characterized by high concentrations of carbonate salts, typically sodium carbonate (and related salt com ...
s. However, most chert is found either as ''bedded chert'' or as ''nodular chert''. Bedded chert is more common in
Precambrian The Precambrian (or Pre-Cambrian, sometimes abbreviated pꞒ, or Cryptozoic) is the earliest part of Earth's history, set before the current Phanerozoic Eon. The Precambrian is so named because it preceded the Cambrian, the first period of the ...
beds, but nodular chert became more common in the
Phanerozoic The Phanerozoic Eon is the current geologic eon in the geologic time scale, and the one during which abundant animal and plant life has existed. It covers 538.8 million years to the present, and it began with the Cambrian Period, when anima ...
as the total volume of chert in the rock record diminished. Bedded chert is rare after the early
Mesozoic The Mesozoic Era ( ), also called the Age of Reptiles, the Age of Conifers, and colloquially as the Age of the Dinosaurs is the second-to-last era of Earth's geological history, lasting from about , comprising the Triassic, Jurassic and Cretaceo ...
. Chert became moderately abundant during the
Devonian The Devonian ( ) is a geologic period and system of the Paleozoic era, spanning 60.3 million years from the end of the Silurian, million years ago (Mya), to the beginning of the Carboniferous, Mya. It is named after Devon, England, whe ...
and
Carboniferous The Carboniferous ( ) is a geologic period and system of the Paleozoic that spans 60 million years from the end of the Devonian Period million years ago ( Mya), to the beginning of the Permian Period, million years ago. The name ''Carbonifero ...
and again became moderately abundant from the
Jurassic The Jurassic ( ) is a Geological period, geologic period and System (stratigraphy), stratigraphic system that spanned from the end of the Triassic Period million years ago (Mya) to the beginning of the Cretaceous Period, approximately Mya. The J ...
to the present.


Bedded chert

Bedded chert, also known as ribbon chert, takes the form of thinly bedded layers (a few centimeters to a meter in thickness) of nearly pure chert separated by very thin layers of silica-rich
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
. It is usually black to green in color, and the full sequence of beds may be several hundred meters thick. The shale is typically black shale, sometimes with
pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), lust ...
, indicating deposition in an
anoxic The term anoxia means a total depletion in the level of oxygen, an extreme form of hypoxia or "low oxygen". The terms anoxia and hypoxia are used in various contexts: * Anoxic waters, sea water, fresh water or groundwater that are depleted of diss ...
environment. Bedded chert is most often found in association with
turbidites A turbidite is the geologic deposit of a turbidity current, which is a type of amalgamation of fluidal and sediment gravity flow responsible for distributing vast amounts of clastic sediment into the deep ocean. Sequencing Turbidites were ...
, deep water
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
, submarine
volcanic rock Volcanic rock (often shortened to volcanics in scientific contexts) is a rock formed from lava erupted from a volcano. In other words, it differs from other igneous rock by being of volcanic origin. Like all rock types, the concept of volcanic r ...
,
ophiolite An ophiolite is a section of Earth's oceanic crust and the underlying upper mantle that has been uplifted and exposed above sea level and often emplaced onto continental crustal rocks. The Greek word ὄφις, ''ophis'' (''snake'') is found i ...
s, and
mélange In geology, a mélange is a large-scale breccia, a mappable body of rock characterized by a lack of continuous bedding and the inclusion of fragments of rock of all sizes, contained in a fine-grained deformed matrix. The mélange typically cons ...
s on
active margin Active may refer to: Music * ''Active'' (album), a 1992 album by Casiopea * Active Records, a record label Ships * ''Active'' (ship), several commercial ships by that name * HMS ''Active'', the name of various ships of the British Royal ...
s of
tectonic plate Plate tectonics (from the la, label=Late Latin, tectonicus, from the grc, τεκτονικός, lit=pertaining to building) is the generally accepted scientific theory that considers the Earth's lithosphere to comprise a number of large te ...
s.
Sedimentary structures Sedimentary structures include all kinds of features in sediments and sedimentary rocks, formed at the time of deposition. Sediments and sedimentary rocks are characterized by bedding, which occurs when layers of sediment, with different partic ...
are rare in bedded cherts. The typically high purity of bedded chert, like the high purity of other chemically precipitated rock, points to deposition in areas where there is little influx of
detrital Detritus (; adj. ''detrital'' ) is particles of rock derived from pre-existing rock through weathering and erosion.Essentials of Geology, 3rd Ed, Stephen Marshak, p G-7 A fragment of detritus is called a clast.Essentials of Geology, 3rd Ed, Stephen ...
sediments (such as river water laden with silt and clay particles.) Such impurities as are present include
authigenic Authigenesis is the process whereby a mineral or sedimentary rock deposit is generated where it is found or observed. Such deposits are described as authigenic. Authigenic sedimentary minerals form during sedimentation by precipitation or recrys ...
pyrite and hematite, formed in the sediments after they were deposited, in addition to traces of detrital minerals. Seawater typically contains between 0.01 and 11
parts per million In science and engineering, the parts-per notation is a set of pseudo-units to describe small values of miscellaneous dimensionless quantities, e.g. mole fraction or mass fraction. Since these fractions are quantity-per-quantity measures, they ...
(ppm) of silica, with around 1 ppm being typical. This is far below saturation, indicating that silica cannot normally be precipitated from seawater through inorganic processes. The silica is instead extracted from seawater by living organisms, such as diatoms, radiolarians, and glass sponges, which can efficiently extract silica even from very unsaturated water, and which are estimated to presently produce of opal per year in the world's oceans. Diatoms can double their numbers eight times a day under ideal conditions (though doubling once per day is more typical in normal seawater) and can extract silica from water with as little as 0.1 ppm silica. The organisms protect their skeletons from dissolution by "armoring" them with metal ions. Once the organisms die, their skeletons will quickly dissolve unless they accumulate on the ocean bottom and are buried, forming siliceous ooze that is 30% to 60% silica. Thus, bedded cherts are typically composed mostly of fossil remains of organisms that secrete silica skeletons, which are usually altered by solution and recrystallization. The skeletons of these organisms are composed of opal-A, an amorphous form of silica, lacking long-range crystal structure. This is gradually transformed to opal-CT, a microcrystalline form of silica composed mostly of bladed crystals of
cristobalite Cristobalite is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, SiO2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the ...
and
tridymite Tridymite is a high-temperature polymorph of silica and usually occurs as minute tabular white or colorless pseudo-hexagonal crystals, or scales, in cavities in felsic volcanic rocks. Its chemical formula is Si O2. Tridymite was first described ...
. Much opal-CT takes the form of ''lepispheres'', which are clusters of bladed crystals about 10 microns in diameter. Opal-CT in turn transforms to microquartz. In deep ocean water, the transition to opal-CT occurs at a temperature of about while the transition to microquartz occurs at a temperature of about . However, the transition temperature varies considerably, and the transition is hastened by the presence of
magnesium hydroxide Magnesium hydroxide is the inorganic compound with the chemical formula Mg(OH)2. It occurs in nature as the mineral brucite. It is a white solid with low solubility in water (). Magnesium hydroxide is a common component of antacids, such as milk ...
, which provides a nucleus for the recrystallization. Megaquartz forms at elevated temperatures typical of
metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chem ...
. There is evidence that the variety of chert called porcelainite, which is characterized by a high content of opal-CT, recrystallizes at very shallow depths. The Caballos Novaculite of Texas also shows signs of very shallow water deposition, including shallow water sedimentary structures and
evaporite An evaporite () is a water-soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as ocea ...
pseudomorphs In mineralogy, a pseudomorph is a mineral or mineral compound that appears in an atypical form (crystal system), resulting from a substitution process in which the appearance and dimensions remain constant, but the original mineral is replaced by ...
, which are casts of crystals of soluble minerals that could only have formed in near-surface conditions. This novaculate appears to have formed by replacement of carbonate fecal pellets by chert.


Subvarieties

Bedded cherts can be further subdivided by the kinds of organisms that produced the silica skeletons. ''Diatomaceous chert'' consists of beds and lenses of
diatomite Diatomaceous earth (), diatomite (), or kieselgur/kieselguhr is a naturally occurring, soft, siliceous sedimentary rock that can be crumbled into a fine white to off-white powder. It has a particle size ranging from more than 3  μm to le ...
which were converted during
diagenesis Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a ...
into dense, hard chert. Beds of marine diatomaceous chert comprising
strata In geology and related fields, a stratum ( : strata) is a layer of rock or sediment characterized by certain lithologic properties or attributes that distinguish it from adjacent layers from which it is separated by visible surfaces known as ei ...
several hundred meters thick have been reported from sedimentary sequences such as the
Miocene The Miocene ( ) is the first geological epoch of the Neogene Period and extends from about (Ma). The Miocene was named by Scottish geologist Charles Lyell; the name comes from the Greek words (', "less") and (', "new") and means "less recen ...
Monterey Formation The Monterey Formation is an extensive Miocene oil-rich geological sedimentary formation in California, with outcrops of the formation in parts of the California Coast Ranges, Peninsular Ranges, and on some of California's off-shore islands ...
of California and occur in rocks as old as the
Cretaceous The Cretaceous ( ) is a geological period that lasted from about 145 to 66 million years ago (Mya). It is the third and final period of the Mesozoic Era, as well as the longest. At around 79 million years, it is the longest geological period of th ...
. Diatoms were the dominant siliceous organism responsible for extracting silica from seawater from the
Jurassic The Jurassic ( ) is a Geological period, geologic period and System (stratigraphy), stratigraphic system that spanned from the end of the Triassic Period million years ago (Mya) to the beginning of the Cretaceous Period, approximately Mya. The J ...
and later. ''
Radiolarite Radiolarite is a Siliceous ooze, siliceous, comparatively hard, fine-grained, chert-like, and homogeneous sedimentary rock that is composed predominantly of the microscopic remains of radiolarians. This term is also used for Friability, indura ...
'' consists mostly of remains of radiolarians. When the remains are well-cemented with silica, it is known as ''radiolarian chert''. Many show evidence of a deep-water origin, but some appear to have formed in water as shallow as , perhaps in
shelf sea A continental shelf is a portion of a continent that is submerged under an area of relatively shallow water, known as a shelf sea. Much of these shelves were exposed by drops in sea level during glacial periods. The shelf surrounding an island ...
s where upwelling of nutrient-rich deep ocean water support high organic productivity. Radiolarians dominated the extraction of silica from seawater prior to the Jurassic. ''Spicularite'' is chert composed of spicules of glass sponges and other invertebrates. When densely cemented, it is known as ''spicular chert''. They are found in association with
glauconite Glauconite is an iron potassium phyllosilicate ( mica group) mineral of characteristic green color which is very friable and has very low weathering resistance. It crystallizes with a monoclinic geometry. Its name is derived from the Greek () m ...
-rich
sandstone Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks. Most sandstone is composed of quartz or feldspar (both silicates) ...
,
black shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especiall ...
,
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay par ...
-rich
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
,
phosphorite Phosphorite, phosphate rock or rock phosphate is a non-detrital sedimentary rock that contains high amounts of phosphate minerals. The phosphate content of phosphorite (or grade of phosphate rock) varies greatly, from 4% to 20% phosphorus pentoxi ...
s, and other nonvolcanic rocks typical of water a few hundred meters deep. Some bedded cherts appear devoid of fossils even under close microscopic examination. Their origin is uncertain, but they may form from fossil remains that are completely dissolved in fluids that then migrate to precipitate their silica load in a nearby bed. Eolian quartz has also been suggested as a source of silica for chert beds.
Precambrian The Precambrian (or Pre-Cambrian, sometimes abbreviated pꞒ, or Cryptozoic) is the earliest part of Earth's history, set before the current Phanerozoic Eon. The Precambrian is so named because it preceded the Cambrian, the first period of the ...
bedded cherts are common, making up 15% of middle Precambrian sedimentary rock, and may have been deposited nonbiologically in oceans more saturated in silica than the modern ocean. The high degree of silica saturation was due either to intense volcanic activity or to the lack of modern organisms that remove silica from seawater.


Nodular chert

Nodular chert is most common in limestone but may also be found in
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
s and sandstones. It is less common in
dolomite Dolomite may refer to: *Dolomite (mineral), a carbonate mineral *Dolomite (rock), also known as dolostone, a sedimentary carbonate rock *Dolomite, Alabama, United States, an unincorporated community *Dolomite, California, United States, an unincor ...
. Nodular chert in
carbonate rock Carbonate rocks are a class of sedimentary rocks composed primarily of carbonate minerals. The two major types are limestone, which is composed of calcite or aragonite (different crystal forms of CaCO3), and dolomite rock (also known as dolosto ...
s is found as oval to irregular nodules. These vary in size from powdery quartz particles to nodules several meters in size. The nodules are most typically along bedding planes or
stylolite Stylolites (Greek: ''stylos'', pillar; ''lithos'', stone) are serrated surfaces within a rock mass at which mineral material has been removed by pressure dissolution, in a deformation process that decreases the total volume of rock. Minerals whi ...
(dissolution) surfaces, where fossil organisms tended to accumulate and provided a source of dissolved silica, but they are sometimes found cutting across bedding surfaces, where the chert fills fossil burrows,
fluid escape structures Sedimentary structures include all kinds of features in sediments and sedimentary rocks, formed at the time of deposition. Sediments and sedimentary rocks are characterized by bedding, which occurs when layers of sediment, with different partic ...
, or fractures. Nodules under a few centimeters in size tend to be egg-shaped, while larger nodules form irregular bodies with knobby surfaces. The outer few centimeters of large nodules may show
desiccation Desiccation () is the state of extreme dryness, or the process of extreme drying. A desiccant is a hygroscopic (attracts and holds water) substance that induces or sustains such a state in its local vicinity in a moderately sealed container. ...
cracks with secondary chert, which likely formed at the same time as the nodule. Calcareous fossils are occasionally present that have been completely silicified. Where chert occurs in chalk or
marl Marl is an earthy material rich in carbonate minerals, clays, and silt. When hardened into rock, this becomes marlstone. It is formed in marine or freshwater environments, often through the activities of algae. Marl makes up the lower part o ...
, it is usually called
flint Flint, occasionally flintstone, is a sedimentary cryptocrystalline form of the mineral quartz, categorized as the variety of chert that occurs in chalk or marly limestone. Flint was widely used historically to make stone tools and start fir ...
. Nodular chert is often dark in color with a white weathering rind. Most chert nodules have textures suggesting they were formed by diagenetic replacement, where silica was deposited in place of calcium carbonate or
clay mineral Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay minerals ...
s. This may have taken place where
meteoric water Meteoric water is the water derived from precipitation (snow and rain). This includes water from lakes, rivers, and icemelts, which all originate from precipitation indirectly. While the bulk of rainwater or meltwater from snow and ice reaches the ...
(water derived from snow or rain) mixed with saltwater in the sediment beds, where carbon dioxide was trapped, producing an environment supersaturated with silica and undersaturated with calcium carbonate. Nodular chert is particularly common in continental shelf environments. In the
Permian Basin (North America) The Permian Basin is a large sedimentary basin in the southwestern part of the United States. The basin contains the Mid-Continent oil province, Mid-continent oil field province. This sedimentary basin is located in western Texas and southeast ...
, chert nodules and chertified fossils are abundant in basin limestones, but there is little in the carbonate buildup zone itself. This may reflect dissolution of opal where carbonate is being actively deposited, a lack of siliceous organisms in these environments, or removal of siliceous skeletons by strong currents that redeposit the siliceous material in the deep basin. The silica in nodular chert likely precipitates as opal-A, based on internal banding in nodules, and may recrystallize directly to microquartz without first recrystallizing to opal-CT. Some nodular chert may precipitate directly as microquartz, due to low levels of supersaturation of silica.


Other occurrences

The
banded iron formation Banded iron formations (also known as banded ironstone formations or BIFs) are distinctive units of sedimentary rock consisting of alternating layers of iron oxides and iron-poor chert. They can be up to several hundred meters in thickness a ...
s of
Precambrian The Precambrian (or Pre-Cambrian, sometimes abbreviated pꞒ, or Cryptozoic) is the earliest part of Earth's history, set before the current Phanerozoic Eon. The Precambrian is so named because it preceded the Cambrian, the first period of the ...
age are composed of alternating layers of chert and
iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of whic ...
s. Nonmarine cherts may form in saline alkaline lakes as thin lenses or nodules showing sedimentary structures suggestive of
evaporite An evaporite () is a water-soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as ocea ...
origin. Such cherts are forming today in the alkaline lakes of the
East African Rift Valley The East African Rift (EAR) or East African Rift System (EARS) is an active continental rift zone in East Africa. The EAR began developing around the onset of the Miocene, 22–25 million years ago. In the past it was considered to be part of a ...
. These lakes are characterized by
sodium carbonate Sodium carbonate, , (also known as washing soda, soda ash and soda crystals) is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield moderately alkaline solutions ...
brines with very high pH that can contain as much as 2700 ppm silica. Episodes of runoff of fresh water into the lakes lowers the pH and precipitates the unusual
sodium silicate Sodium silicate is a generic name for chemical compounds with the formula or ·, such as sodium metasilicate , sodium orthosilicate , and sodium pyrosilicate . The anions are often polymeric. These compounds are generally colorless transparent ...
minerals
magadiite Magadiite is a hydrous sodium silicate mineral (NaSi7O13(OH)3·4(H2O)) which precipitates from alkali brines as an evaporite phase. It forms as soft (Mohs hardness of 2) white powdery monoclinic crystal masses. The mineral is unstable and decompose ...
or kenyaite, After burial and
diagenesis Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a ...
, these are altered to Magadi-type chert. The
Morrison Formation The Morrison Formation is a distinctive sequence of Late Jurassic, Upper Jurassic sedimentary rock found in the western United States which has been the most fertile source of dinosaur fossils in North America. It is composed of mudstone, sandsto ...
contains Magadi-type chert that may have formed in the alkaline Lake T'oo'dichi'. Chert may also form from replacement of
calcrete Caliche () is a sedimentary rock, a hardened natural cement of calcium carbonate that binds other materials—such as gravel, sand, clay, and silt. It occurs worldwide, in aridisol and mollisol soil orders—generally in arid or semiarid regions, ...
in fossil soils (
paleosols In the geosciences, paleosol (''palaeosol'' in Great Britain and Australia) is an ancient soil that formed in the past. The precise definition of the term in geology and paleontology is slightly different from its use in soil science. In geolo ...
) by silica dissolved from overlying
volcanic ash Volcanic ash consists of fragments of rock, mineral crystals, and volcanic glass, created during volcano, volcanic eruptions and measuring less than 2 mm (0.079 inches) in diameter. The term volcanic ash is also often loosely used t ...
beds.


Fossils

The
cryptocrystalline Cryptocrystalline is a rock microstructure, rock texture made up of such minute crystals that its crystalline nature is only vaguely revealed even microscopically in thin section by transmitted polarized light. Among the sedimentary rocks, chert a ...
nature of chert, combined with its above average ability to resist
weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), ...
, recrystallization and
metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chem ...
has made it an ideal rock for preservation of early life forms. For example: * The 3.2 Ga chert of the
Fig Tree Formation The Fig Tree Formation, also called Fig Tree Group, is a stromatolite-containing geological formation in South Africa. The rock contains fossils of microorganisms, microscopic life forms of about 3.26 billion years old. Identified organisms includ ...
in the Barberton Mountains between
Eswatini Eswatini ( ; ss, eSwatini ), officially the Kingdom of Eswatini and formerly named Swaziland ( ; officially renamed in 2018), is a landlocked country in Southern Africa. It is bordered by Mozambique to its northeast and South Africa to its no ...
and South Africa preserved non-colonial
unicellular A unicellular organism, also known as a single-celled organism, is an organism that consists of a single cell, unlike a multicellular organism that consists of multiple cells. Organisms fall into two general categories: prokaryotic organisms and ...
bacteria-like fossils. * The Gunflint Chert of western Ontario (1.9 to 2.3 Ga) preserves not only bacteria and
cyanobacteria Cyanobacteria (), also known as Cyanophyta, are a phylum of gram-negative bacteria that obtain energy via photosynthesis. The name ''cyanobacteria'' refers to their color (), which similarly forms the basis of cyanobacteria's common name, blu ...
but also organisms believed to be ammonia-consuming and some that resemble
green algae The green algae (singular: green alga) are a group consisting of the Prasinodermophyta and its unnamed sister which contains the Chlorophyta and Charophyta/Streptophyta. The land plants (Embryophytes) have emerged deep in the Charophyte alga as ...
and fungus-like organisms. * The Apex Chert (3.4 Ga) of the
Pilbara craton The Pilbara Craton is an old and stable part of the continental lithosphere located in the Pilbara region of Western Australia. The Pilbara Craton is one of only two pristine Archaean 3.6–2.7 Ga (billion years ago) crusts identified on the ...
, Australia preserved eleven taxa of
prokaryotes A prokaryote () is a single-celled organism that lacks a nucleus and other membrane-bound organelles. The word ''prokaryote'' comes from the Greek πρό (, 'before') and κάρυον (, 'nut' or 'kernel').Campbell, N. "Biology:Concepts & Connec ...
. However, these findings have been disputed. * The Bitter Springs Formation of the
Amadeus Basin The Amadeus Basin is a large (~170,000 km2) intracratonic sedimentary basin in central Australia, lying mostly within the southern Northern Territory, but extending into the state of Western Australia. Origins The Amadeus Basin is named ...
, Central Australia, preserves 850 Ma cyanobacteria and algae. * The
Rhynie chert The Rhynie chert is a Lower Devonian sedimentary deposit exhibiting extraordinary fossil detail or completeness (a Lagerstätte). It is exposed near the village of Rhynie, Aberdeenshire, Scotland; a second unit, the Windyfield chert, is located ...
(410 Ma) of Scotland has remains of a
Devonian The Devonian ( ) is a geologic period and system of the Paleozoic era, spanning 60.3 million years from the end of the Silurian, million years ago (Mya), to the beginning of the Carboniferous, Mya. It is named after Devon, England, whe ...
land flora and fauna with preservation so perfect that it allows cellular studies of the fossils.


Prehistoric and historic uses

Chert is of only modest economic importance today as a source of silica (quartz sand being much more important.) However, chert deposits may be associated with valuable deposits of iron,
uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
, manganese,
phosphorite Phosphorite, phosphate rock or rock phosphate is a non-detrital sedimentary rock that contains high amounts of phosphate minerals. The phosphate content of phosphorite (or grade of phosphate rock) varies greatly, from 4% to 20% phosphorus pentoxi ...
, and petroleum.


Tools

In prehistoric times, chert was often used as a raw material for the construction of
stone tool A stone tool is, in the most general sense, any tool made either partially or entirely out of stone. Although stone tool-dependent societies and cultures still exist today, most stone tools are associated with prehistoric (particularly Stone Ag ...
s. Like
obsidian Obsidian () is a naturally occurring volcanic glass formed when lava extrusive rock, extruded from a volcano cools rapidly with minimal crystal growth. It is an igneous rock. Obsidian is produced from felsic lava, rich in the lighter elements s ...
, as well as some
rhyolite Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral ...
s,
felsite Felsite is a very fine-grained volcanic rock that may or may not contain larger crystals. Felsite is a field term for a light-colored rock that typically requires petrographic examination or chemical analysis for more precise definition. Color i ...
s,
quartzite Quartzite is a hard, non- foliated metamorphic rock which was originally pure quartz sandstone.Essentials of Geology, 3rd Edition, Stephen Marshak, p 182 Sandstone is converted into quartzite through heating and pressure usually related to tect ...
s, and other
tool stone A tool is an object that can extend an individual's ability to modify features of the surrounding environment or help them accomplish a particular task. Although many animals use simple tools, only human beings, whose use of stone tools dates bac ...
s used in
lithic reduction In archaeology, in particular of the Stone Age, lithic reduction is the process of fashioning stones or rocks from their natural state into tools or weapons by removing some parts. It has been intensely studied and many archaeological industries ...
, chert fractures in a
Hertzian cone A Hertzian cone is the cone produced when an object passes through a solid, such as a bullet through glass. More technically, it is a cone of force that propagates through a brittle, amorphous, or cryptocrystalline solid material from a point of ...
when struck with sufficient force. This results in
conchoidal Conchoidal fracture describes the way that brittle materials break or fracture when they do not follow any natural planes of separation. Mindat.org defines conchoidal fracture as follows: "a fracture with smooth, curved surfaces, typically sli ...
fractures, a characteristic of all minerals with no cleavage planes. In this kind of fracture, a cone of force propagates through the material from the point of impact, eventually removing a full or partial cone; this result is familiar to anyone who has seen what happens to a plate-glass window when struck by a small object, such as an
air gun An air gun or airgun is a gun that fires projectiles pneumatically with compressed air or other gases that are mechanically pressurized ''without'' involving any chemical reactions, in contrast to a firearm, which pressurizes gases ''chemica ...
projectile. The partial Hertzian cones produced during lithic reduction are called flakes, and exhibit features characteristic of this sort of breakage, including
striking platform In lithic reduction In archaeology, in particular of the Stone Age, lithic reduction is the process of fashioning stones or rocks from their natural state into tools or weapons by removing some parts. It has been intensely studied and many arch ...
s, bulbs of force, and occasionally
eraillure In lithic analysis (a subdivision of archaeology), an eraillure is a flake removed from a lithic flake's bulb of force, which is a lump left on the ventral surface of a flake after it is detached from a core of tool stone during the process of lith ...
s, which are small secondary flakes detached from the flake's bulb of force. When a chert stone is struck against an iron-bearing surface, sparks result. This makes chert an excellent tool for starting fires, and both flint and common chert were used in various types of fire-starting tools, such as
tinderbox A tinderbox, or patch box, is a container made of wood or metal containing flint, firesteel, and tinder (typically charcloth, but possibly a small quantity of dry, finely divided fibrous matter such as hemp), used together to help kindle a fire ...
es, throughout history. A primary historic use of common chert and flint was for
flintlock Flintlock is a general term for any firearm that uses a flint-striking lock (firearm), ignition mechanism, the first of which appeared in Western Europe in the early 16th century. The term may also apply to a particular form of the mechanism its ...
firearms A firearm is any type of gun designed to be readily carried and used by an individual. The term is legally defined further in different countries (see Legal definitions). The first firearms originated in 10th-century China, when bamboo tubes c ...
, in which the chert striking a metal plate produces a spark that ignites a small reservoir containing
black powder Gunpowder, also commonly known as black powder to distinguish it from modern smokeless powder, is the earliest known chemical explosive. It consists of a mixture of sulfur, carbon (in the form of charcoal) and potassium nitrate (saltpeter). Th ...
, discharging the firearm.


Construction

Cherts are subject to problems when used as concrete aggregates. Deeply weathered chert develops surface pop-outs when used in concrete that undergoes freezing and thawing because of the high porosity of weathered chert. The other concern is that certain cherts undergo an alkali-silica reaction with high-alkali cements. This reaction leads to cracking and expansion of concrete and ultimately to failure of the material.


Varieties

There are numerous varieties of chert, classified based on their visible, microscopic and physical characteristics. Some of the more common varieties are: *
Flint Flint, occasionally flintstone, is a sedimentary cryptocrystalline form of the mineral quartz, categorized as the variety of chert that occurs in chalk or marly limestone. Flint was widely used historically to make stone tools and start fir ...
is a compact microcrystalline quartz. It was originally the name for chert found in
chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Chalk ...
or marly limestone formations formed by a replacement of calcium carbonate with
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
. Commonly found as nodules, this variety was often used in past times to make bladed tools. Today, some geologists refer to any dark gray to black chert as flint. The dark color is from inclusions of organic matter. Among non-geologists, the distinction between "flint" and "chert" is often one of quality – chert being lower quality than flint. This usage of the terminology is particularly prevalent in Great Britain where most true flint (found in chalk formations) was of better quality than "common chert" (from limestone formations). * "Common chert" is a variety of chert which forms in limestone formations by replacement of calcium carbonate with silica. This is the most abundantly found variety of chert. It is generally considered to be less attractive for producing gem stones and bladed tools than flint. *
Jasper Jasper, an aggregate of microgranular quartz and/or cryptocrystalline chalcedony and other mineral phases,Kostov, R. I. 2010. Review on the mineralogical systematics of jasper and related rocks. – Archaeometry Workshop, 7, 3, 209-213PDF/ref> ...
is a variety of chert formed as primary deposits, found in or in connection with magmatic formations which owes its red color to hematite inclusions. Jasper frequently also occurs in black, yellow or even green (depending on the type of iron it contains). Jasper is usually opaque to near opaque. Jasper is also present in banded iron formation, where it is described as jaspilite. * Radiolarite is a variety of chert formed as primary deposits and containing
radiolarian The Radiolaria, also called Radiozoa, are protozoa of diameter 0.1–0.2 mm that produce intricate mineral skeletons, typically with a central capsule dividing the cell into the inner and outer portions of endoplasm and ectoplasm. The elab ...
microfossils. Many show evidence of a deep-water origin, but some appear to have formed in water as shallow as , * Chalcedony is a microfibrous quartz. *
Agate Agate () is a common rock formation, consisting of chalcedony and quartz as its primary components, with a wide variety of colors. Agates are primarily formed within volcanic and metamorphic rocks. The ornamental use of agate was common in Ancie ...
is distinctly banded chalcedony with successive layers differing in color or value. *
Onyx Onyx primarily refers to the parallel banded variety of chalcedony, a silicate mineral. Agate and onyx are both varieties of layered chalcedony that differ only in the form of the bands: agate has curved bands and onyx has parallel bands. The c ...
is a banded agate with layers in parallel lines, often black and white (''sardonyx''). * Magadi-type chert is a variety that forms from a sodium silicate precursor in highly alkaline lakes such as
Lake Magadi Lake Magadi is the southernmost lake in the Kenyan Rift Valley, lying in a catchment of faulted volcanic rocks, north of Tanzania's Lake Natron. During the dry season, it is 80% covered by soda and is well known for its wading birds, including f ...
in Kenya. *
Novaculite Novaculite, also called Arkansas Stone, is a microcrystalline to cryptocrystalline rock type that consists of silica in the form of chert or flint. It is commonly white to grey or black in color, with a specific gravity that ranges from 2.2 to 2.5 ...
is a very dense, fine-grained, and uniform form of very pure white chert with a high content of extracrystalline water. It is most common in the mid-
Paleozoic The Paleozoic (or Palaeozoic) Era is the earliest of three geologic eras of the Phanerozoic Eon. The name ''Paleozoic'' ( ;) was coined by the British geologist Adam Sedgwick in 1838 by combining the Greek words ''palaiós'' (, "old") and ' ...
rocks of
Texas Texas (, ; Spanish language, Spanish: ''Texas'', ''Tejas'') is a state in the South Central United States, South Central region of the United States. At 268,596 square miles (695,662 km2), and with more than 29.1 million residents in 2 ...
,
Oklahoma Oklahoma (; Choctaw language, Choctaw: ; chr, ᎣᎧᎳᎰᎹ, ''Okalahoma'' ) is a U.S. state, state in the South Central United States, South Central region of the United States, bordered by Texas on the south and west, Kansas on the nor ...
, and
Arkansas Arkansas ( ) is a landlocked state in the South Central United States. It is bordered by Missouri to the north, Tennessee and Mississippi to the east, Louisiana to the south, and Texas and Oklahoma to the west. Its name is from the Osage ...
in the south-central United States, where it has undergone some
metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chem ...
. * Porcelanite is a term used for fine-grained siliceous rocks with a texture and a fracture resembling those of unglazed porcelain. It likely forms in shallow water and is composed mostly of opal-CT. * Tripolitic chert (or tripoli) is a light-colored porous friable siliceous (largely chalcedonic) sedimentary rock, which results from the weathering (decalcification) of chert or siliceous limestone. *
Siliceous sinter Geyserite, or siliceous sinter, is a form of opaline silica that is often found as crusts or layers around hot springs and geysers. Botryoidal geyserite is known as fiorite. Geyserite is porous due to the silica enclosing many small cavities. Si ...
is porous, low-density, light-colored siliceous rock deposited by waters of hot springs and geysers. *
Mozarkite Mozarkite is a form of chert (flint). It is the state rock of Missouri. The name is a portmanteau, formed from ''Mo'' (Missouri), ''zark'' (Ozarks), and ''ite'' (meaning rock). Mozarkite consists essentially of silica (quartz - SiO2) with varyin ...
a varicolored, easily polished Ordovician chert that takes a high polish. It is the state rock of Missouri. Other lesser used archaic terms for chert are firestone and silex.


See also

* ** ** not to be confused with
Concretion A concretion is a hard, compact mass of matter formed by the precipitation of mineral cement within the spaces between particles, and is found in sedimentary rock or soil. Concretions are often ovoid or spherical in shape, although irregular ...
** ** ** * ** , archaeological artefacts of the
Clovis culture The Clovis culture is a prehistoric Paleoamerican culture, named for distinct stone and bone tools found in close association with Pleistocene fauna, particularly two mammoths, at Blackwater Locality No. 1 near Clovis, New Mexico, in 1936 ...
in
New Mexico ) , population_demonym = New Mexican ( es, Neomexicano, Neomejicano, Nuevo Mexicano) , seat = Santa Fe , LargestCity = Albuquerque , LargestMetro = Tiguex , OfficialLang = None , Languages = English, Spanish ( New Mexican), Navajo, Ker ...
** , a prehistoric chert mine in Alba County, Romania


References


External links


Photo & note re: Fig Tree Formation


* Schopf, J.W. (1999) ''Cradle of Life: The Discovery of Earth's Earliest Fossils'', Princeton University Press, 336 p. 

{{Authority control Firelighting using percussion Sedimentary rocks Lithics Quartz varieties