Cellulosic Sugars
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Cellulosic sugars are derived from non-food
biomass Biomass is plant-based material used as a fuel for heat or electricity production. It can be in the form of wood, wood residues, energy crops, agricultural residues, and waste from industry, farms, and households. Some people use the terms bi ...
(e.g. wood, agricultural residues, municipal solid waste). The biomass is primarily composed of carbohydrate polymers
cellulose Cellulose is an organic compound with the formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units. Cellulose is an important structural component of the primary cell wall ...
,
hemicellulose A hemicellulose (also known as polyose) is one of a number of heteropolymer, heteropolymers (matrix polysaccharides), such as arabinoxylans, present along with cellulose in almost all embryophyte, terrestrial plant cell walls.Scheller HV, Ulvskov H ...
, and an aromatic polymer (lignin). The hemicellulose is a polymer of mainly five-carbon sugars C5H10O5 (
xylose Xylose ( grc, ξύλον, , "wood") is a sugar first isolated from wood, and named for it. Xylose is classified as a monosaccharide of the aldopentose type, which means that it contains five carbon atoms and includes an aldehyde functional gro ...
). and the cellulose is a polymer of six-carbon sugar C6H12O6 (
glucose Glucose is a simple sugar with the molecular formula . Glucose is overall the most abundant monosaccharide, a subcategory of carbohydrates. Glucose is mainly made by plants and most algae during photosynthesis from water and carbon dioxide, using ...
). Cellulose fibers are considered to be a plant’s structural building blocks and are tightly bound to lignin, but the biomass can be deconstructed using
Acid hydrolysis In organic chemistry, acid hydrolysis is a hydrolysis process in which a protic acid is used to catalyze the cleavage of a chemical bond via a nucleophilic substitution reaction, with the addition of the elements of water (H2O). For example, in th ...
,
enzymatic hydrolysis In biochemistry, enzymatic hydrolysis is a process in which enzymes facilitate the cleavage of bonds in molecules with the addition of the elements of water (i.e. hydrolysis). It plays an important role in the digestion of food. It may be used t ...
, organosolv dissolution, autohydrolysis or
supercritical hydrolysis Supercritical hydrolysis is a chemical engineering process in which water in the supercritical state can be employed to achieve a variety of reactions within seconds. To cope with the extremely short times of reaction on an industrial scale, the pro ...
. A more recent mechanical method offers hope that at last, a more economic and waste free method has been found although it is still to scale and is not yet commercial. Biomass (cellulose, hemicellulose and lignocellulose) contain vast amounts of fermentable sugars. These sugars may be produced from a wide variety of feedstocks and can be converted into a multitude of
biochemical Biochemistry or biological chemistry is the study of chemical processes within and relating to living organisms. A sub-discipline of both chemistry and biology, biochemistry may be divided into three fields: structural biology, enzymology an ...
,
biofuel Biofuel is a fuel that is produced over a short time span from biomass, rather than by the very slow natural processes involved in the formation of fossil fuels, such as oil. According to the United States Energy Information Administration (E ...
, and polymer products by either biological, mechanical or chemical routes. __TOC__


Industrial use

In January 2012,
BASF BASF Societas Europaea, SE () is a German multinational corporation, multinational chemical company and the List of largest chemical producers, largest chemical producer in the world. Its headquarters is located in Ludwigshafen, Germany. The ...
invested in Pennsylvania-base
Renmatix
to produce low-cost, large volume quantities of industrial sugar from lignocellulosic biomass (wood, cane bagasse or straw). Renmatix is currently the only commercial player utilizing supercritical hydrolysis as a route to cellulosic sugar production. Renmatix is working with multiple partners on development of commercial scale facilities with the capability to produce more than 100,000 tons of cellulosic sugars annually. The company has a world-class technical center in Pennsylvania and production operations at the Integrated Plantrose Complex (IPC) in Kennesaw, Georgia and the Feedstock Processing Facility (FPF) in Rome, New York. In June 2013, Renmatix also entered a joint development agreement (JDA) with
UPM UPM may refer to: * Ultra-pure metal * UPM (company), UPM-Kymmene Oyj, a pulp and paper company * Union pour la méditerrannée, Mediterranean Community * Union for a Popular Movement, opposition party of France * Unit production manager, someone ...
, a Finnish pulp, paper and timber manufacturer, to convert woody biomass into low-cost sugar intermediates for subsequent downstream processing into biochemicals. In December 2013, Renmatix and Virent announced a strategic collaboration to convert affordable cellulosic sugars to renewable chemicals and bio-based packaging materials. In March 2015, French Energy Group,
Total S.A. TotalEnergies SE is a French multinational integrated energy and petroleum company founded in 1924 and one of the seven supermajor oil companies. Its businesses cover the entire oil and gas chain, from crude oil and natural gas exploration and ...
entered a joint development agreement (JDA) with Renmatix to use the Plantrose technology to extract second-generation sugars from biomass and develop sustainable and profitable biomolecules for products of interest. Biotechnology Penetration in the Chemical Industry World Biobased Market Penetration 2010-2025 In the first quarter of 2013
American Process Inc.
announced the start-up of cellulosic sugar production using their patented AVAP® technology at their demonstration plant in Thomaston, GA. The AVAP process uses ethanol and sulfur dioxide (SO2) to fractionate biomass into its pure components: cellulose, hemicellulose sugars and lignin. In early 2013 GranBio, a Brazilian pioneer in biofuels and biochemicals, completed the acquisition of an equity investment in API. Since that time, API has fermented both five-carbon and six-carbon sugars into high value bio-chemicals and biofuels in partnership with fermentation companies throughout the world.


Applications

Cellulosic sugars are used as renewable resources for biochemical and
biofuel Biofuel is a fuel that is produced over a short time span from biomass, rather than by the very slow natural processes involved in the formation of fossil fuels, such as oil. According to the United States Energy Information Administration (E ...
s industries and can be used to produce intermediates by fermentative processes. The availability of industrial sugars from renewable resources, in sufficient quantities and at a favorable cost enables the products to be cost-competitive to
fossil fuel A fossil fuel is a hydrocarbon-containing material formed naturally in the Earth's crust from the remains of dead plants and animals that is extracted and burned as a fuel. The main fossil fuels are coal, oil, and natural gas. Fossil fuels m ...
based products. A 2012 study by Nexant estimates that in the future, it will be possible and potentially economically viable to produce any type of sugar-based chemical product from biomass due to developments in cellulosic processing.
Cellulosic Biofuels Industry Progress Report
”, Advanced Ethanol Council, (2012-2013)


References

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