Carbonate Mudstone
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Mudstone, a type of
mudrock Mudrocks are a class of fine-grained siliciclastic sedimentary rocks. The varying types of mudrocks include siltstone, claystone, mudstone, slate, and shale. Most of the particles of which the stone is composed are less than and are too ...
, is a fine-grained sedimentary rock whose original constituents were clays or
mud A MUD (; originally multi-user dungeon, with later variants multi-user dimension and multi-user domain) is a Multiplayer video game, multiplayer Time-keeping systems in games#Real-time, real-time virtual world, usually Text-based game, text-bas ...
s. Mudstone is distinguished from ''
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
'' by its lack of
fissility In nuclear engineering, fissile material is material capable of sustaining a nuclear fission Nuclear chain reaction#Fission chain reaction, chain reaction. By definition, fissile material can sustain a chain reaction with neutrons of thermal ene ...
(parallel layering).Blatt, H., and R.J. Tracy, 1996, ''Petrology.'' New York, New York, W. H. Freeman, 2nd ed, 529 pp. The term ''mudstone'' is also used to describe carbonate rocks ( limestone or
dolomite Dolomite may refer to: *Dolomite (mineral), a carbonate mineral *Dolomite (rock), also known as dolostone, a sedimentary carbonate rock *Dolomite, Alabama, United States, an unincorporated community *Dolomite, California, United States, an unincor ...
) that are composed predominantly of carbonate mud. However, in most contexts, the term refers to
siliciclastic Siliciclastic (or ''siliclastic'') rocks are clastic noncarbonate sedimentary rocks that are composed primarily of silicate minerals, such as quartz or clay minerals. Siliciclasic rock types include mudrock, sandstone Sandstone is a clastic ...
mudstone, composed mostly of silicate minerals. The NASA Curiosity rover has found deposits of mudstone on Mars that contain organic substances such as
propane Propane () is a three-carbon alkane with the molecular formula . It is a gas at standard temperature and pressure, but compressible to a transportable liquid. A by-product of natural gas processing and petroleum refining, it is commonly used a ...
, benzene and toluene.


Definition

There is not a single definition of mudstone that has gained general acceptance,Boggs 2006, p.143 though there is wide agreement that mudstones are fine-grained sedimentary rocks, composed mostly of silicate grains with a
grain size Grain size (or particle size) is the diameter of individual grains of sediment, or the lithified particles in clastic rocks. The term may also be applied to other granular materials. This is different from the crystallite size, which refer ...
less than . Individual grains this size are too small to be distinguished without a microscope, which means that most classifications emphasize texture rather than mineral composition,Boggs 2006, p.143 and mudstones have historically received less attention from petrologists than have sandstones. The simplest definition is that a mudstone is a fine-grained clastic sedimentary rock that is not laminated or fissile. Most definitions also include a requirement that the rock contain significant amounts of both silt- and clay-sized grains. One common requirement is that a mudstone is a mudrock (a rock containing more than 50% silt- to clay-sized particles) in which between a third and two-thirds of the mud (silt and clay) fraction is clay particles. Another definition is that mudstone is a sedimentary rock in which neither silt, clay, nor coarser grains is predominant. Rock of this composition that does show laminations or fissility is sometimes described as ''mudshale'' rather than ''mudstone''. The lack of fissility or layering in mudstone may be due to either original texture or the disruption of layering by burrowing organisms in the sediment prior to lithification. Mudstone looks like hardened clay and, depending upon the circumstances under which it was formed, it may show cracks or fissures, like a sun-baked clay deposit. When the mineral composition of mudstones has been determined, using such techniques as scanning electron microscopy,
electron probe microanalysis An electron microprobe (EMP), also known as an electron probe microanalyzer (EPMA) or electron micro probe analyzer (EMPA), is an analytical tool used to non-destructively determine the chemical composition of small volumes of solid materials. It ...
, or
X-ray diffraction analysis X-ray crystallography is the experimental science determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to diffract into many specific directions. By measuring the angles ...
, they have been found to be composed primarily of
clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
, quartz, and feldspars, with a variety of accessory minerals.Boggs 2006, pp.140-143


Carbonate mudstone

In the Dunham classification (Dunham, 1962Dunham, R.J., 1962. Classification of carbonate rocks according to depositional texture. In: W.E. Ham (Ed.), Classification of Carbonate Rocks. American Association of Petroleum Geologists Memoir. American Association of Petroleum Geologists, Tulsa, Oklahoma, pp. 108-121.) system of limestones, a mudstone is defined as a mud-supported carbonate rock that contains less than 10% grains. Most recently, this definition has been clarified as ''a matrix-supported carbonate-dominated rock composed of more than 90% carbonate mud (<63 μm) component''.


The identification of carbonate mudstone

A recent study by Lokier and Al Junaibi (2016) has highlighted that the most common problems encountered when describing a mudstone is to incorrectly estimate the volume of 'grains' in the sample - in consequence, misidentifying mudstone as wackestone and vice versa. The original Dunham classification (1962) defined the matrix as clay and fine-silt size sediment <20 μm in diameter. This definition was redefined by Embry & Klovan (1971) to a grain size of less than or equal to 30 μm. Wright (1992) proposed a further increase to the upper limit for the matrix size in order to bring it into line with the upper limit for silt (63 μm).


Mudstone mineralogy on Mars

On December 13, 2016, NASA reported further evidence supporting habitability on the planet Mars as the ''Curiosity'' rover climbed higher, studying younger layers, on
Mount Sharp Mount Sharp, officially Aeolis Mons (), is a mountain on Mars. It forms the central peak within Gale (crater), Gale crater and is located around , rising high from the valley floor. Its ID in the United States Geological Survey's Gazetteer of ...
. Also reported, the very soluble element
boron Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the ''boron group'' it has th ...
was detected for the first time on Mars. In June 2018, NASA reported that ''Curiosity'' had detected kerogen and other complex organic compounds from mudstone rocks approximately 3.5 billion years old.


See also

* Mudstone on planet Mars ** Aeolis quadrangle ** Composition of Mars ** Timeline of Mars Science Laboratory *


References

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