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A carbon dioxide sensor or CO2 sensor is an instrument for the measurement of
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
gas. The most common principles for CO2 sensors are infrared gas sensors ( NDIR) and chemical gas sensors. Measuring carbon dioxide is important in monitoring
indoor air quality Indoor air quality (IAQ) is the air quality within and around buildings and structures. IAQ is known to affect the health, comfort, and well-being of building occupants. Poor indoor air quality has been linked to sick building syndrome, reduce ...
, the function of the lungs in the form of a capnograph device, and many industrial processes.


Nondispersive infrared (NDIR) CO2 sensors

NDIR sensors are
spectroscopic Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. Matter wa ...
sensors to detect CO2 in a gaseous environment by its characteristic absorption. The key components are an
infrared Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around ...
source, a
light Light or visible light is electromagnetic radiation that can be perceived by the human eye. Visible light is usually defined as having wavelengths in the range of 400–700 nanometres (nm), corresponding to frequencies of 750–420 te ...
tube, an interference (wavelength) filter, and an infrared detector. The gas is pumped or diffuses into the light tube, and the electronics measure the absorption of the characteristic
wavelength In physics, the wavelength is the spatial period of a periodic wave—the distance over which the wave's shape repeats. It is the distance between consecutive corresponding points of the same phase on the wave, such as two adjacent crests, t ...
of light. NDIR sensors are most often used for measuring carbon dioxide.Carbonate Based CO2 Sensors with High Performance, Th. Lang, H.-D. Wiemhöfer and W. Göpel, Conf.Proc.Eurosensors IX, Stockholm (S) (1995); Sensors and Actuators B, 34, 1996, 383–387. The best of these have sensitivities of 20–50 PPM. Typical NDIR sensors cost in the (US) $100 to $1000 range. NDIR CO2 sensors are also used for dissolved CO2 for applications such as beverage carbonation, pharmaceutical fermentation and CO2 sequestration applications. In this case they are mated to an ATR (attenuated total reflection) optic and measure the gas ''in situ''. New developments include using microelectromechanical systems (MEMS) IR sources to bring down the costs of this sensor and to create smaller devices (for example for use in
air conditioning Air conditioning, often abbreviated as A/C or AC, is the process of removing heat from an enclosed space to achieve a more comfortable interior environment (sometimes referred to as 'comfort cooling') and in some cases also strictly controlling ...
applications). Another method (
Henry's Law In physical chemistry, Henry's law is a gas law that states that the amount of dissolved gas in a liquid is directly proportional to its partial pressure above the liquid. The proportionality factor is called Henry's law constant. It was formulate ...
) also can be used to measure the amount of dissolved CO2 in a liquid, if the amount of foreign gases is insignificant.


Photoacoustic sensors

CO2 can be measured using
photoacoustic spectroscopy Photoacoustic spectroscopy is the measurement of the effect of absorbed electromagnetic energy (particularly of light) on matter by means of acoustic detection. The discovery of the photoacoustic effect dates to 1880 when Alexander Graham Bell sh ...
. Concentration of CO2 can be measured by subjecting a sample to pulses of electromagnetic energy (such as from a distributed feedback laser) that is tuned specifically to the absorption wavelength of CO2. With each pulse of energy, the CO2 molecules within the sample will absorb and generate pressure waves via the
photoacoustic effect The photoacoustic effect or optoacoustic effect is the formation of sound waves following light absorption in a material sample. In order to obtain this effect the light intensity must vary, either periodically (''modulated light'') or as a single ...
. These pressure waves are then detected with an acoustic detector and converted to a usable CO2 reading through a computer or microprocessor.


Chemical CO2 sensors

Chemical CO2 gas sensors with sensitive layers based on polymer- or hetero
polysiloxane A silicone or polysiloxane is a polymer made up of siloxane (−R2Si−O−SiR2−, where R = organic group). They are typically colorless oils or rubber-like substances. Silicones are used in sealants, adhesives, lubricants, medicine, cooking ...
have the principal advantage of very low energy consumption, and that they can be reduced in size to fit into microelectronic-based systems. On the downside, short and long term drift effects, as well as a rather low overall lifetime, are major obstacles when compared with the NDIR measurement principle.Reliable CO2 Sensors Based with Silicon-based Polymers on Quartz Microbalance Transducers, R. Zhou, S. Vaihinger, K.E. Geckeler, and W. Göpel, Conf.Proc.Eurosensors VII, Budapest (H) (1993); Sensors and Actuators B, 18–19, 1994, 415–420. Most CO2 sensors are fully calibrated prior to shipping from the factory. Over time, the zero point of the sensor needs to be calibrated to maintain the long term stability of the sensor.


Estimated CO2 sensor

For indoor environments such as offices or gyms where the principal source of CO2 is human
respiration Respiration may refer to: Biology * Cellular respiration, the process in which nutrients are converted into useful energy in a cell ** Anaerobic respiration, cellular respiration without oxygen ** Maintenance respiration, the amount of cellul ...
, rescaling some easier-to-measure quantities such as
volatile organic compound Volatile organic compounds (VOCs) are organic compounds that have a high vapour pressure at room temperature. High vapor pressure correlates with a low boiling point, which relates to the number of the sample's molecules in the surrounding air, a ...
(VOC) and
hydrogen gas Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, a ...
(H2) concentrations provides a good-enough estimator of the real CO2 concentration for ventilation and occupancy purposes. Furthermore, inasmuch as ventilation is a factor in the spread of respiratory
virus A virus is a submicroscopic infectious agent that replicates only inside the living cells of an organism. Viruses infect all life forms, from animals and plants to microorganisms, including bacteria and archaea. Since Dmitri Ivanovsk ...
es, CO2 levels are a rough metric for
COVID-19 Coronavirus disease 2019 (COVID-19) is a contagious disease caused by a virus, the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2). The first known case was identified in Wuhan, China, in December 2019. The disease quickly ...
risk; the worse the ventilation, the better for viruses and ''vice versa''. Sensors for these substances can be made using cheap (~$20) Microelectromechanical systems (MEMS)
metal oxide semiconductor The metal–oxide–semiconductor field-effect transistor (MOSFET, MOS-FET, or MOS FET) is a type of field-effect transistor (FET), most commonly fabricated by the thermal oxidation, controlled oxidation of silicon. It has an insulated gate, the ...
(MOS) technology. The reading they generate is called estimated CO2 (eCO2) or CO2 equivalent (CO2eq). Although the readings tend to be good enough in the long run, introducing non-respiration sources of VOC or CO2, such as peeling fruits or using
perfume Perfume (, ; french: parfum) is a mixture of fragrant essential oils or aroma compounds (fragrances), fixatives and solvents, usually in liquid form, used to give the human body, animals, food, objects, and living-spaces an agreeable scent. Th ...
, will undermine their reliability. H2-based sensors are less susceptible as they are more specific to human breathing, although the very health conditions the
hydrogen breath test A hydrogen breath test (or HBT) is used as a diagnostic tool for small intestine bacterial overgrowth and carbohydrate malabsorption, such as lactose, fructose, and sorbitol malabsorption. The test is simple, non-invasive, and is performed after ...
is set to diagnose will also disrupt them.


Applications

* Examples: **
Modified atmosphere Modified atmosphere packaging (MAP) is the practice of modifying the composition of the internal atmosphere of a package (commonly food packages, drugs, etc.) in order to improve the shelf life. The need for this technology for food arises from t ...
s **
Indoor air quality Indoor air quality (IAQ) is the air quality within and around buildings and structures. IAQ is known to affect the health, comfort, and well-being of building occupants. Poor indoor air quality has been linked to sick building syndrome, reduce ...
** Stowaway detection ** Cellar and gas stores ** Marine vessels ** Greenhouses ** Landfill gas **
Confined space A confined space is a space with limited entry and egress and not suitable for human inhabitants. An example is the interior of a storage tank, occasionally entered by maintenance workers but not intended for human occupancy. Hazards in a confined ...
s **
Aerospace Aerospace is a term used to collectively refer to the atmosphere and outer space. Aerospace activity is very diverse, with a multitude of commercial, industrial and military applications. Aerospace engineering consists of aeronautics and astr ...
** Healthcare **
Horticulture Horticulture is the branch of agriculture that deals with the art, science, technology, and business of plant cultivation. It includes the cultivation of fruits, vegetables, nuts, seeds, herbs, sprouts, mushrooms, algae, flowers, seaweeds and no ...
**
Transportation Transport (in British English), or transportation (in American English), is the intentional movement of humans, animals, and goods from one location to another. Modes of transport include air, land (rail and road), water, cable, pipeline, ...
**
Cryogenics In physics, cryogenics is the production and behaviour of materials at very low temperatures. The 13th IIR International Congress of Refrigeration (held in Washington DC in 1971) endorsed a universal definition of “cryogenics” and “cr ...
**
Ventilation Ventilation may refer to: * Ventilation (physiology), the movement of air between the environment and the lungs via inhalation and exhalation ** Mechanical ventilation, in medicine, using artificial methods to assist breathing *** Ventilator, a m ...
management **
Mining Mining is the extraction of valuable minerals or other geological materials from the Earth, usually from an ore body, lode, vein, seam, reef, or placer deposit. The exploitation of these deposits for raw material is based on the economic ...
**
Rebreather A rebreather is a breathing apparatus that absorbs the carbon dioxide of a user's breathing, exhaled breath to permit the rebreathing (recycling) of the substantially unused oxygen content, and unused inert content when present, of each breath. ...
s (SCUBA) **
Decaffeination Decaffeination is the removal of caffeine from coffee beans, cocoa, tea leaves, and other caffeine-containing materials. Decaffeinated drinks contain typically 1–2% of the original caffeine content, and sometimes as much as 20%. Decaffeinate ...
* For indoor human occupancy counting * For HVAC applications, CO2 sensors can be used to monitor the quality of air and the tailored need for fresh air, respectively. Measuring CO2 levels indirectly determines how many people are in a room, and ventilation can be adjusted accordingly. See demand controlled ventilation (DCV).KMC Controls. (2013). Demand Control Ventilation Benefits for Your Building. Retrieved 25 March 2013, from http://www.kmccontrols.com/docs/DCV_Benefits_White_Paper_KMC_RevB.pdf


See also

* Exhaust gas analyzer * Oxygen sensor *
Gas detector A gas detector is a device that detects the presence of gases in an area, often as part of a safety system. A gas detector can sound an alarm to operators in the area where the leak is occurring, giving them the opportunity to leave. This type of ...
* Colorimetric capnography


References

{{DEFAULTSORT:Carbon Dioxide Sensor Sensors Gas sensors