Californium(III) Fluoride
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Californium(III) fluoride is a binary
inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...
of
californium Californium is a radioactive chemical element with the symbol Cf and atomic number 98. The element was first synthesized in 1950 at Lawrence Berkeley National Laboratory (then the University of California Radiation Laboratory), by bombarding ...
and
fluorine Fluorine is a chemical element with the symbol F and atomic number 9. It is the lightest halogen and exists at standard conditions as a highly toxic, pale yellow diatomic gas. As the most electronegative reactive element, it is extremely reacti ...
with the formula


Physical properties

Californium(III) fluoride is a yellow-green solid and has two crystalline structures that are temperature dependent. At low temperatures the orthorhombic structure ( type) is found with
lattice constant A lattice constant or lattice parameter is one of the physical dimensions and angles that determine the geometry of the unit cells in a crystal lattice, and is proportional to the distance between atoms in the crystal. A simple cubic crystal has o ...
s ''a'' = 665.3(3) pm, ''b'' = 703.9(1) pm and ''c'' = 439.3(3) pm. At higher temperatures it forms a trigonal system ( type) with: ''a'' = 694.5(3) pm and ''c'' = 710.1(2) pm. Here, each californium atom is surrounded by nine fluorine atoms in a distorted triply-capped trigonal-prismatic structure.


References

Californium compounds Fluorides {{inorganic-compound-stub