Carbonate compensation depth (CCD) is the depth in the oceans below which the rate of supply of

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

( calcium carbonate) lags behind the rate of

solvation Solvation (or dissolution) describes the interaction of a solvent with dissolved molecules. Both ionized and uncharged molecules interact strongly with a solvent, and the strength and nature of this interaction influence many properties of the ...

, such that no calcite is preserved. Shells of animals therefore dissolve and carbonate particles may not accumulate in the sediments on the sea floor below this depth. Aragonite compensation depth (hence ACD) describes the same behaviour in reference to

aragonitic Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, (the other forms being the minerals calcite and vaterite). It is formed by biological and physical processes, including pre ...

carbonates. Aragonite is more soluble than calcite, so the aragonite compensation depth is generally shallower than the calcite compensation depth.

Overview

As shown in the diagram, biogenic calcium carbonate (CaCO₃)

tests Test(s), testing, or TEST may refer to: * Test (assessment), an educational assessment intended to measure the respondents' knowledge or other abilities Arts and entertainment * ''Test'' (2013 film), an American film * ''Test'' (2014 film), ...

are produced in the

photic zone The photic zone, euphotic zone, epipelagic zone, or sunlight zone is the uppermost layer of a body of water that receives sunlight, allowing phytoplankton to perform photosynthesis. It undergoes a series of physical, chemical, and biological proc ...

of the oceans (green circles). Upon death, those tests escaping dissolution near the surface, settle along with clays materials. In seawater, a dissolution boundary is formed as a result of temperature, pressure, and depth, and is known as the ''saturation horizon''. Above the saturation horizon, waters are supersaturated and CaCO₃ tests are largely preserved. Below the saturation, waters are undersaturated because of increasing solubility with depth and the release of CO₂ from organic matter decay and CaCO₃ will dissolve. Dissolution occurs primarily at the sediment surface as the sinking velocity of debris is rapid (broad white arrows). At the carbonate compensation depth, the rate of dissolution exactly matches rate of supply of CaCO₃ from above. At steady state this carbonate compensation depth is similar to the snowline (the first depth where carbonate poor sediments occur). The

lysocline The lysocline is the depth in the ocean dependent upon the carbonate compensation depth (CCD), usually around 3.5 km, below which the rate of dissolution of calcite increases dramatically because of a pressure effect. While the lysocline is the u ...

is the depth interval between the saturation and carbonate compensation depth.

Solubility of carbonate

Calcium carbonate is essentially insoluble in sea surface waters today. Shells of dead calcareous

plankton Plankton are the diverse collection of organisms found in Hydrosphere, water (or atmosphere, air) that are unable to propel themselves against a Ocean current, current (or wind). The individual organisms constituting plankton are called plankt ...

sinking to deeper waters are practically unaltered until reaching the

, the point about 3.5 km deep past which the

solubility In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solubil ...

increases dramatically with depth and pressure. By the time the CCD is reached all calcium carbonate has dissolved according to this equation: :CaCO3 + CO2 + H2O <=> Ca^2+ (aq) + 2HCO_3^- (aq) Calcareous plankton and

sediment Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand an ...

particles can be found in the

water column A water column is a conceptual column of water from the surface of a sea, river or lake to the bottom sediment.Munson, B.H., Axler, R., Hagley C., Host G., Merrick G., Richards C. (2004).Glossary. ''Water on the Web''. University of Minnesota-D ...

above the CCD. If the

sea bed The seabed (also known as the seafloor, sea floor, ocean floor, and ocean bottom) is the bottom of the ocean. All floors of the ocean are known as 'seabeds'. The structure of the seabed of the global ocean is governed by plate tectonics. Most of ...

is above the CCD, bottom

s can consist of calcareous sediments called

calcareous ooze Calcareous () is an adjective meaning "mostly or partly composed of calcium carbonate", in other words, containing lime or being chalky. The term is used in a wide variety of scientific disciplines. In zoology ''Calcareous'' is used as an adje ...

, which is essentially a type of

limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...

chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Chalk ...

. If the exposed sea bed is below the CCD tiny

shell Shell may refer to: Architecture and design * Shell (structure), a thin structure ** Concrete shell, a thin shell of concrete, usually with no interior columns or exterior buttresses ** Thin-shell structure Science Biology * Seashell, a hard o ...

s of CaCO₃ will dissolve before reaching this level, preventing deposition of carbonate sediment. As the sea floor spreads,

thermal subsidence In geology and geophysics, thermal subsidence is a mechanism of subsidence in which conductive cooling of the mantle thickens the lithosphere and causes it to decrease in elevation. This is because of thermal contraction: as mantle material cools an ...

of the plate, which has the effect of increasing depth, may bring the carbonate layer below the CCD; the carbonate layer may be prevented from chemically interacting with the sea water by overlying sediments such as a layer of

siliceous ooze Siliceous ooze is a type of biogenic pelagic sediment located on the deep ocean floor. Siliceous oozes are the least common of the deep sea sediments, and make up approximately 15% of the ocean floor. Oozes are defined as sediments which contain a ...

abyssal The abyssal zone or abyssopelagic zone is a layer of the pelagic zone of the ocean. "Abyss" derives from the Greek word , meaning bottomless. At depths of , this zone remains in perpetual darkness. It covers 83% of the total area of the ocean a ...

clay deposited on top of the carbonate layer.

Variations in value of the CCD

The exact value of the CCD depends on the solubility of calcium carbonate which is determined by

temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied o ...

pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and e ...

and the chemical composition of the water – in particular the amount of dissolved in the water. Calcium carbonate is more soluble at lower temperatures and at higher pressures. It is also more soluble if the concentration of dissolved is higher. Adding a reactant to the above chemical equation pushes the equilibrium towards the right producing more products: Ca²⁺ and HCO₃⁻, and consuming more reactants and calcium carbonate according to

Le Chatelier's principle Le Chatelier's principle (pronounced or ), also called Chatelier's principle (or the Equilibrium Law), is a principle of chemistry used to predict the effect of a change in conditions on chemical equilibria. The principle is named after French c ...

. At the present time the CCD in the

Pacific Ocean The Pacific Ocean is the largest and deepest of Earth's five oceanic divisions. It extends from the Arctic Ocean in the north to the Southern Ocean (or, depending on definition, to Antarctica) in the south, and is bounded by the continen ...

is about 4200–4500 metres except beneath the equatorial

upwelling Upwelling is an oceanographic phenomenon that involves wind-driven motion of dense, cooler, and usually nutrient-rich water from deep water towards the ocean surface. It replaces the warmer and usually nutrient-depleted surface water. The nutr ...

zone, where the CCD is about 5000 m. In the

temperate In geography, the temperate climates of Earth occur in the middle latitudes (23.5° to 66.5° N/S of Equator), which span between the tropics and the polar regions of Earth. These zones generally have wider temperature ranges throughout t ...

and

tropical The tropics are the regions of Earth surrounding the Equator. They are defined in latitude by the Tropic of Cancer in the Northern Hemisphere at N and the Tropic of Capricorn in the Southern Hemisphere at S. The tropics are also referred to ...

Atlantic Ocean The Atlantic Ocean is the second-largest of the world's five oceans, with an area of about . It covers approximately 20% of Earth's surface and about 29% of its water surface area. It is known to separate the " Old World" of Africa, Europe ...

the CCD is at approximately 5000 m. In the

Indian Ocean The Indian Ocean is the third-largest of the world's five oceanic divisions, covering or ~19.8% of the water on Earth's surface. It is bounded by Asia to the north, Africa to the west and Australia to the east. To the south it is bounded by th ...

it is intermediate between the Atlantic and the Pacific at approximately 4300 meters. The variation in the depth of the CCD largely results from the length of time since the bottom water has been exposed to the surface; this is called the "age" of the

water mass An oceanographic water mass is an identifiable body of water with a common formation history which has physical properties distinct from surrounding water. Properties include temperature, salinity, chemical - isotopic ratios, and other physical ...

Thermohaline circulation Thermohaline circulation (THC) is a part of the large-scale ocean circulation that is driven by global density gradients created by surface heat and freshwater fluxes. The adjective ''thermohaline'' derives from '' thermo-'' referring to temper ...

determines the relative ages of the water in these basins. Because organic material, such as fecal pellets from

copepods Copepods (; meaning "oar-feet") are a group of small crustaceans found in nearly every freshwater and saltwater habitat. Some species are planktonic (inhabiting sea waters), some are benthic (living on the ocean floor), a number of species have p ...

, sink from the surface waters into deeper water, deep water masses tend to accumulate dissolved carbon dioxide as they age. The oldest water masses have the highest concentrations of and therefore the shallowest CCD. The CCD is relatively shallow in high

latitude In geography, latitude is a coordinate that specifies the north– south position of a point on the surface of the Earth or another celestial body. Latitude is given as an angle that ranges from –90° at the south pole to 90° at the north pol ...

s with the exception of the

North Atlantic The Atlantic Ocean is the second-largest of the world's five oceans, with an area of about . It covers approximately 20% of Earth's surface and about 29% of its water surface area. It is known to separate the "Old World" of Africa, Europe and ...

and regions of

Southern Ocean The Southern Ocean, also known as the Antarctic Ocean, comprises the southernmost waters of the World Ocean, generally taken to be south of 60° S latitude and encircling Antarctica. With a size of , it is regarded as the second-small ...

where

downwelling Downwelling is the process of accumulation and sinking of higher density material beneath lower density material, such as cold or saline water beneath warmer or fresher water or cold air beneath warm air. It is the ''sinking'' limb of a convecti ...

occurs. This downwelling brings young, surface water with relatively low concentrations of carbon dioxide into the deep ocean, depressing the CCD. In the geological past the depth of the CCD has shown significant variation. In the

Cretaceous The Cretaceous ( ) is a geological period that lasted from about 145 to 66 million years ago (Mya). It is the third and final period of the Mesozoic Era, as well as the longest. At around 79 million years, it is the longest geological period of th ...

through to the

Eocene The Eocene ( ) Epoch is a geological epoch (geology), epoch that lasted from about 56 to 33.9 million years ago (mya). It is the second epoch of the Paleogene Period (geology), Period in the modern Cenozoic Era (geology), Era. The name ''Eocene' ...

the CCD was much shallower globally than it is today; due to intense volcanic activity during this period atmospheric concentrations were much higher. Higher concentrations of resulted in a higher

partial pressure In a mixture of gases, each constituent gas has a partial pressure which is the notional pressure of that constituent gas as if it alone occupied the entire volume of the original mixture at the same temperature. The total pressure of an ideal gas ...

of over the ocean. This greater pressure of atmospheric leads to increased dissolved in the ocean mixed surface layer. This effect was somewhat moderated by the deep oceans' elevated temperatures during this period. In the late Eocene the transition from a greenhouse to an icehouse Earth coincided with a deepened CCD. John Murray investigated and experimented on the dissolution of calcium carbonate and was first to identify the carbonate compensation depth in oceans.

Climate change impacts

Increasing atmospheric concentration of from combustion of

fossil fuels A fossil fuel is a hydrocarbon-containing material formed naturally in the Earth's crust from the remains of dead plants and animals that is extracted and burned as a fuel. The main fossil fuels are coal, oil, and natural gas. Fossil fuels ...

are causing the CCD to rise, with zones of

first being affected.

Ocean acidification Ocean acidification is the reduction in the pH value of the Earth’s ocean. Between 1751 and 2021, the average pH value of the ocean surface has decreased from approximately 8.25 to 8.14. The root cause of ocean acidification is carbon dioxid ...

, which is also caused by increasing carbon dioxide concentrations in the atmosphere, will increase such dissolution and shallow the carbonate compensation depth on timescales of tens to hundreds of years.

Sedimentary ooze

On the sea floors above the Carbonate compensation depth, the most commonly found ooze is

; on the sea floors below the Carbonate compensation depth, the most commonly found ooze is

. While calcareous ooze mostly consists of

Rhizaria The Rhizaria are an ill-defined but species-rich supergroup of mostly unicellular eukaryotes. Except for the Chlorarachniophytes and three species in the genus Paulinella in the phylum Cercozoa, they are all non-photosynthethic, but many foramini ...

, siliceous ooze mostly consists of

Radiolaria The Radiolaria, also called Radiozoa, are protozoa of diameter 0.1–0.2 mm that produce intricate mineral skeletons, typically with a central capsule dividing the cell (biology), cell into the inner and outer portions of endoplasm and Ecto ...

and

Diatom A diatom (Neo-Latin ''diatoma''), "a cutting through, a severance", from el, διάτομος, diátomos, "cut in half, divided equally" from el, διατέμνω, diatémno, "to cut in twain". is any member of a large group comprising sev ...

References