Cadmium Acetate
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Cadmium acetate is the
chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...
with the
formula In science, a formula is a concise way of expressing information symbolically, as in a mathematical formula or a ''chemical formula''. The informal use of the term ''formula'' in science refers to the general construct of a relationship betwee ...
. The compound is marketed both as the anhydrous form and as a
dihydrate In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understo ...
, both of which are white or colorless. Only the dihydrate has been verified by
X-ray crystallography X-ray crystallography is the experimental science determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to diffract into many specific directions. By measuring the angles ...
.


Preparation, reactions, and uses

It forms by treating
cadmium oxide Cadmium oxide is an inorganic compound with the formula CdO. It is one of the main precursors to other cadmium compounds. It crystallizes in a cubic rocksalt lattice like sodium chloride, with octahedral cation and anion centers. It occurs na ...
with
acetic acid Acetic acid , systematically named ethanoic acid , is an acidic, colourless liquid and organic compound with the chemical formula (also written as , , or ). Vinegar is at least 4% acetic acid by volume, making acetic acid the main component ...
: : It can also be prepared by treating
cadmium nitrate Cadmium nitrate describes any of the related members of a family of inorganic compounds with the general formula Cd(NO3)2.\mathitH2O, the most commonly encountered form being the tetrahydrate. The anhydrous form is volatile, but the others are ...
with
acetic anhydride Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula (CH3CO)2O. Commonly abbreviated Ac2O, it is the simplest isolable anhydride of a carboxylic acid and is widely used as a reagent in organic synthesis. It is a col ...
. Cadmium acetate has few applications. By reaction with
trioctylphosphine selenide Trioctylphosphine selenide (TOPSe) is an organophosphorus compound with the chemical formula, formula SeP(C8H17)3. It is used as a source of selenium in the preparation of cadmium selenide. TOPSe is a white, air-stable solid that is soluble in or ...
, it has often been used as a precursor to
cadmium selenide Cadmium selenide is an inorganic compound with the formula Cadmium, CdSelenide, Se. It is a black to red-black solid that is classified as a II-VI semiconductor of the n-type semiconductor, n-type. Much of the current research on this compound i ...
and related semiconductors.


Structure of the dihydrate

Unlike the coordination geometry of zinc in
zinc diacetate Zinc acetate is a Salt (chemistry), salt with the chemical formula, formula Zn(CH3CO2)2, which commonly occurs as the Hydrate, dihydrate Zn(CH3CO2)2ยท2H2O. Both the hydrate and the anhydrous forms are colorless solids that are used as dietary supp ...
dihydrate, cadmium is seven coordinate in . It is a
coordination polymer A coordination polymer is an inorganic or organometallic polymer structure containing metal cation centers linked by ligands. More formally a coordination polymer is a coordination compound with repeating coordination entities extending in 1, 2, o ...
, featuring acetate ligands interconnecting cadmium centers.


Safety

Cadmium compounds are considered Group 1 carcinogens by the IARC.


References

{{Acetates Cadmium compounds Acetates Coordination polymers