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Bulat is a type of steel
alloy An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductili ...
known in Russia from medieval times; it was regularly mentioned in Russian legends as the material of choice for cold steel. The name ''булат'' is a Russian transliteration of the Persian word ''fulad'', meaning steel. This type of steel was used by the armies of nomadic peoples. Bulat steel was the main type of steel used for swords in the armies of
Genghis Khan Genghis Khan (born Temüjin; ; xng, Temüjin, script=Latn; ., name=Temujin – August 25, 1227) was the founder and first Great Khan (Emperor) of the Mongol Empire, which became the List of largest empires, largest contiguous empire in history a ...
. Bulat Steel is generally agreed to be a Russian name for
wootz steel Wootz steel, also known as Seric steel, is a crucible steel characterized by a pattern of bands and high carbon content. These bands are formed by sheets of microscopic carbides within a tempered martensite or pearlite matrix in higher carbon ...
, the production method of which has been lost for centuries, and the bulat steel used today makes use of a more recently developed technique.


History

The secret of bulat manufacturing was lost by the beginning of the 19th century. It is known that the process involved dipping the finished weapon into a vat containing a special liquid of which spiny restharrow extract was a part (the plant's name in Russian, ''stalnik'', reflects its historical role), then holding the sword aloft while galloping on a horse, allowing it to dry and harden against the wind. Pavel Anosov eventually managed to duplicate the qualities of that metal in 1838, when he completed ten years of study into the nature of
Damascus steel Damascus steel was the forged steel of the blades of swords smithed in the Near East from ingots of Wootz steel either imported from Southern India or made in production centres in Sri Lanka, or Khorasan, Iran. These swords are characterized by ...
sword A sword is an edged, bladed weapon intended for manual cutting or thrusting. Its blade, longer than a knife or dagger, is attached to a hilt and can be straight or curved. A thrusting sword tends to have a straighter blade with a pointed ti ...
s. Anosov had entered the
Saint Petersburg Saint Petersburg ( rus, links=no, Санкт-Петербург, a=Ru-Sankt Peterburg Leningrad Petrograd Piter.ogg, r=Sankt-Peterburg, p=ˈsankt pʲɪtʲɪrˈburk), formerly known as Petrograd (1914–1924) and later Leningrad (1924–1991), i ...
Mine Cadet School in 1810, where a Damascus steel sword was stored in a display case. He became enchanted with the sword, and was filled with stories of them slashing through their European counterparts. In November 1817, he was sent to the factories of
Zlatoust Zlatoust ( rus, Златоуст, p=zlətɐˈust) is a city in Chelyabinsk Oblast, Russia, located on the Ay River (in the Kama basin), west of Chelyabinsk. Population: 181,000 (1971); 161,000 (1959); 99,000 (1939); 48,000 (1926); 21,000 ( ...
mining region in the southern
Urals The Ural Mountains ( ; rus, Ура́льские го́ры, r=Uralskiye gory, p=ʊˈralʲskʲɪjə ˈɡorɨ; ba, Урал тауҙары) or simply the Urals, are a mountain range that runs approximately from north to south through western ...
, where he was soon promoted to the inspector of the "weapon decoration department". Here he again came into contact with Damascus steel of European origin (which was in fact
pattern welded Pattern welding is the practice in sword and knife making of forming a blade of several metal pieces of differing composition that are forge-welded together and twisted and manipulated to form a pattern. Often mistakenly called Damascus steel, ...
steel, and not at all similar), but quickly found that this steel was quite inferior to the original forged in the Middle East from wootz steel from India. Anosov had been working with various
quenching In materials science, quenching is the rapid cooling of a workpiece in water, oil, polymer, air, or other fluids to obtain certain material properties. A type of heat treating, quenching prevents undesired low-temperature processes, such as ...
techniques, and decided to attempt to duplicate Damascus steel with
quenching In materials science, quenching is the rapid cooling of a workpiece in water, oil, polymer, air, or other fluids to obtain certain material properties. A type of heat treating, quenching prevents undesired low-temperature processes, such as ...
. He eventually developed a methodology that greatly increased the hardness of his steels. Bulat became popular in
cannon A cannon is a large- caliber gun classified as a type of artillery, which usually launches a projectile using explosive chemical propellant. Gunpowder ("black powder") was the primary propellant before the invention of smokeless powder ...
manufacturing, until the
Bessemer process The Bessemer process was the first inexpensive industrial process for the mass production of steel from molten pig iron before the development of the open hearth furnace. The key principle is removal of impurities from the iron by oxidation ...
was able to make the same quality steels for far less money.


Process


Structure

Carbon steel Carbon steel is a steel with carbon content from about 0.05 up to 2.1 percent by weight. The definition of carbon steel from the American Iron and Steel Institute (AISI) states: * no minimum content is specified or required for chromium, coba ...
consists of two components: pure
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
, in the form of ferrite, and
cementite Cementite (or iron carbide) is a compound of iron and carbon, more precisely an intermediate transition metal carbide with the formula Fe3C. By weight, it is 6.67% carbon and 93.3% iron. It has an orthorhombic crystal structure. It is a hard, ...
or iron carbide, a compound of iron and
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon ma ...
. Cementite is very hard and brittle; its
hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...
is about 640 by the Brinell hardness test, whereas ferrite is only 200. The amount of the carbon and the cooling regimen determine the crystalline and chemical composition of the final steel. In bulat, the slow cooling process allowed the cementite to precipitate as micro particles in between ferrite crystals and arrange in random patterns. The color of the carbide is dark while steel is grey. This mixture is what leads to the famous patterning of
Damascus steel Damascus steel was the forged steel of the blades of swords smithed in the Near East from ingots of Wootz steel either imported from Southern India or made in production centres in Sri Lanka, or Khorasan, Iran. These swords are characterized by ...
. Cementite is essentially a ceramic, which accounts for the sharpness of the Damascus (and bulat) steel. Cementite is unstable and breaks down between 600–1100 °C into ferrite and carbon, so working the hot metal must be done very carefully.


See also

* Toledo steel *
Damascus steel Damascus steel was the forged steel of the blades of swords smithed in the Near East from ingots of Wootz steel either imported from Southern India or made in production centres in Sri Lanka, or Khorasan, Iran. These swords are characterized by ...
*
Wootz steel Wootz steel, also known as Seric steel, is a crucible steel characterized by a pattern of bands and high carbon content. These bands are formed by sheets of microscopic carbides within a tempered martensite or pearlite matrix in higher carbon ...
*
Noric steel Noric steel was a steel from Noricum, a Celtic kingdom located in modern Austria and Slovenia. The proverbial hardness of Noric steel is expressed by Ovid: ''"...durior ..ferro quod noricus excoquit ignis..."'' which roughly translates to "...har ...
*
Tamahagane steel ''Tamahagane'' (玉鋼) is a type of steel made in the Japanese tradition. The word ''tama'' means "precious". The word ''hagane'' means "steel". Tamahagane is used to make Japanese swords, knives, and other kinds of tools. The carbon content ...


References


Bibliography

* * * * * {{Use dmy dates, date=June 2013 Steels Steel industry of Russia History of metallurgy pl:Bułat (stal)