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A black powder rocket motor propels a
model rocket A model rocket are small rockets designed to reach low altitudes (e.g., for model) and be recovered by a variety of means. According to the United States National Association of Rocketry (NAR) Safety Code, model rockets are constructed of ...
using
black powder Gunpowder, also commonly known as black powder to distinguish it from modern smokeless powder, is the earliest known chemical explosive. It consists of a mixture of sulfur, carbon (in the form of charcoal) and potassium nitrate (saltpeter). T ...
. Black powder rocket propellants consist of charcoal,
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formul ...
, and
potassium nitrate Potassium nitrate is a chemical compound with the chemical formula . This alkali metal nitrate salt is also known as Indian saltpetre (large deposits of which were historically mined in India). It is an ionic salt of potassium ions K+ and ...
. Adjustments can be made to the amount of each component to change the rate at which the black powder burns. Black powder rocket motors were created in a primitive form by the Chinese in the early 13th century, and through the years refinements have been made and several uses created. They have been used for weapons and surveillance devices as well as recreation. Black powder rocket motors are only produced in small sizes, to reduce the risk of explosion and a loss of efficiency. Black powder rockets are produced in classes 1/8 A through F. Larger sizes of model rocket motors use
ammonium perchlorate composite propellant Ammonium perchlorate composite propellant (APCP) is a solid-propellant rocket fuel. It differs from many traditional solid rocket propellants such as black powder or zinc-sulfur, not only in chemical composition and overall performance but als ...
, or other composite fuels that contain
ammonium nitrate Ammonium nitrate is a chemical compound with the chemical formula . It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, although it does not form hydrates. It is ...
.


History

Black powder is the oldest composite propellant. Its use in rockets preceded its use in guns.Bedard, Andre. ‘Black Powder Rockets’. Encyclopedia Astronautica. http://www.astronautix.com/ The three main components of black powder are charcoal, sulfur, and saltpeter (or potassium nitrate). It is known that, by 1045, the Chinese were producing black powder, because many references to the subject were found in The Wu-ching Tsung-Yao (Complete Compendium of Military Classics). In the early thirteenth century the Chinese turned black powder propelled objects, formerly only used for entertainment, into weapons of war. The first recorded use of rockets as military weapons was in 1232. The Chinese ‘arrows of fire’ were fired from a sort of catapult launcher. The black powder was packed in a closed tube that had a hole in one end for escaping hot gases, and a long stick as an elementary stability and guidance system. Black powder had a very low specific impulse, however. Refinements in rocket design were made over the next few hundred years. In 1591 a Belgian, Jean Beavie, described and sketched the important idea of multistage rockets. By 1600, rockets were being used in various parts of Europe against cavalry. By 1688, rockets weighing over 120 pounds had been built and fired with success in Germany. These German rockets, carrying 16-pound warheads, used wooden powder cases reinforced with linen. Black powder rockets reached a new level of performance with the introduction of iron hulls and high-pressure combustion, developed in India by the engineers of
Tipu Sultan Tipu Sultan (born Sultan Fateh Ali Sahab Tipu, 1 December 1751 – 4 May 1799), also known as the Tiger of Mysore, was the ruler of the Kingdom of Mysore based in South India. He was a pioneer of rocket artillery.Dalrymple, p. 243 He i ...
. With a range of a kilometer, his rocket-propelled grenades and incendiaries took British invaders by surprise during the
Anglo-Mysore Wars The Anglo-Mysore Wars were a series of four wars fought during the last three decades of the 18th century between the Sultanate of Mysore on the one hand, and the British East India Company (represented chiefly by the neighbouring Madras Pres ...
.Winter, Frank, "The First Golden Age of Rocketry", Smithsonian, 1990 Impressed by these weapons, a London lawyer, Sir
William Congreve William Congreve (24 January 1670 – 19 January 1729) was an English playwright and poet of the Restoration period. He is known for his clever, satirical dialogue and influence on the comedy of manners style of that period. He was also a mi ...
, became fascinated by the challenge of improving rockets. He experimented with propellants and case design. His systematic approach to the problem resulted in improved range, guidance (stabilization), and incendiary capabilities. The British armed forces used Congreve's new rockets to great advantage during the Napoleonic and 1812 Wars. In 1939, researchers at the
California Institute of Technology The California Institute of Technology (branded as Caltech or CIT)The university itself only spells its short form as "Caltech"; the institution considers other spellings such a"Cal Tech" and "CalTech" incorrect. The institute is also occasional ...
seeking to develop a high-performance solid rocket motor to assist aircraft take-off, combined black powder with common road
asphalt Asphalt, also known as bitumen (, ), is a sticky, black, highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term ...
to produce the first true composite motor. This was the birth of the true composite motor and marked the end of the use of black powder in major rocketry applications. This was also the beginning of the
Jet Propulsion Laboratory The Jet Propulsion Laboratory (JPL) is a Federally funded research and development centers, federally funded research and development center and NASA field center in the City of La Cañada Flintridge, California, La Cañada Flintridge, California ...
, and the source of its name.


Formulations

Black powder rocket propellant is very similar in makeup to old-fashioned gunpowder. The main difference is the presence of a binder, usually
dextrin Dextrins are a group of low-molecular-weight carbohydrates produced by the hydrolysis of starch and glycogen. Dextrins are mixtures of polymers of D-glucose units linked by α-(1→4) or α-(1→6) glycosidic bonds. Dextrins can be produced from ...
. The commonly used
Estes Estes is an English-language surname said to derive from Old English and have the meaning "of the East" (literally, "East's"). As a surname, it has been traced to southern Kent, as early as the mid-15th century, Nicholas Estes (Ewstas, Esteuzi) b. ...
model rocket engines are made with black powder propellant. Black powder propellant must be pressed very tightly in order to function well. Motors designed with black powder are most often end-burners, due to the fast burn rate of this propellant. A simple dextrin-free version (the most commonly used formulation) incorporates 75% potassium nitrate, 10% sulphur, and 15% charcoal. Dextrin may be added as desired (usually between 0 and 5%). Additional (coarse) charcoal or metal powders (5 - 10%) may be added to obtain an interesting spark trail. However, this may alter slightly the burn rate of the mixture.


Performance

The impulse (area under the thrust-time curve) of a black powder motor is used to determine its class. Motors are divided into classes from 1/4A to E, which covers an impulse range of 0 to 40 N·s (
newton-second The newton-second (also newton second; symbol: N⋅s or N s) is the unit of impulse in the International System of Units (SI). It is dimensionally equivalent to the momentum unit kilogram-metre per second (kg⋅m/s). One newton-secon ...
s). Other types of model rocket motors can be classified up to an ‘H’, which is up to 320 N·s, and even further in some cases. Each class's upper limit is double the upper limit of the previous class. Figures from tests of Estes rocket motors are used in the following examples of rocket motor performance. For miniature black powder rocket motors (13 mm diameter), the maximum
thrust Thrust is a reaction force described quantitatively by Newton's third law. When a system expels or accelerates mass in one direction, the accelerated mass will cause a force of equal magnitude but opposite direction to be applied to that ...
is between 5 and 12 N, the total impulse is between 0.5 and 2.2 N·s, and the burn time is between 0.25 and 1 second. For Estes ‘regular size’ rocket motors (18 mm diameter), there are three classes: A, B, and C. The A class 18 mm motors have a maximum thrust between 9.5 and 9.75 N, a total impulse between 2.1 and 2.3 N·s, and a burn time between 0.5 and 0.75 seconds. The B class 18 mm motors have a maximum thrust between 12.15 and 12.75 N, a total impulse between 4.2 and 4.35 N·s, and a burn time between 0.85 and 1 second. The C class 18mm motors have a maximum thrust from 14 – 14.15 N, a total impulse between 8.8 and 9 N·s, and a burn time between 1.85 and 2 seconds. There are also 3 classes included in Estes large (24 mm diameter) rocket motors: C, D, and E. The C class 24 mm motors have a maximum thrust between 21.6 and 21.75 N, a total impulse of between 8.8 and 9 N·s, and a burn time between 0.8 and 0.85 seconds. The D class 24 mm motors have a maximum thrust between 29.7 and 29.8 N, a total impulse between 16.7 and 16.85 N·s, and a burn time between 1.6 and 1.7 seconds. The E class 24 mm motors have a maximum thrust between 19.4 and 19.5 N, a total impulse between 28.45 and 28.6 N·s, and a burn time between 3 and 3.1 seconds.


See also

* Rocket candy


References

{{Reflist Model rocketry Rocket propellants Rocket engines Solid-fuel rockets Solid fuels