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The term bulk material analyzer is the generic noun for that device which fits around a conveyor belt and conducts real-time elemental analysis of the material on the belt. Other names often found for such a device include ''belt analyzer'', ''crossbelt analyzer'' and ''elemental analyzer''. This product first found popularity in the
cement A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel (aggregate) together. Cement m ...
industry during the 1990s, and today most new cement plants include at least one analyzer, if not two.


Cement industry

A couple of applications predominate for the bulk material analyzer in
cement A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel (aggregate) together. Cement m ...
production.


Stockpile management

One is known as "stockpile management," whereby an analyzer located upstream of the pile is able to track the cumulative chemistry of the pile. This allows the operator to direct haul
truck A truck or lorry is a motor vehicle designed to transport cargo, carry specialized payloads, or perform other utilitarian work. Trucks vary greatly in size, power, and configuration, but the vast majority feature body-on-frame constructi ...
s to different sections of the
quarry A quarry is a type of open-pit mining, open-pit mine in which dimension stone, rock (geology), rock, construction aggregate, riprap, sand, gravel, or slate is excavated from the ground. The operation of quarries is regulated in some juri ...
in a way that will result in the final elemental composition of the pile close to target.


Raw mix proportioning

A second application in cement for the bulk material analyzer is raw mix proportioning. An analyzer placed just upstream of the raw mill can monitor the chemistry of the raw mix and automatically trigger an adjustment in the proportions of the reclaimed stockpile and the correctives. By doing so, the plant is able to reduce the variability in the raw mix, and later on the
kiln A kiln is a thermally insulated chamber, a type of oven, that produces temperatures sufficient to complete some process, such as hardening, drying, or chemical changes. Kilns have been used for millennia to turn objects made from clay int ...
feed. Consistent kiln feed chemistry in turn leads to lower fuel consumption per ton of clinker produced.


Other applications

In the 2000s the application of the bulk material analyzer was extended to include
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ...
s. Today, analyzers are found in
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish ...
,
iron ore Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the ...
, and
phosphate In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid . The phosphate or orthophosphate ion is derived from phosph ...
s, to name a few. One of the advantages of these analyzers is the timeliness of information for the user. Another is the avoidance of physical sampling.


Technology

The technology most frequently found in bulk material analysis and
coal analysis Coal analysis techniques are specific analytical methods designed to measure the particular physical and chemical properties of coals. These methods are used primarily to determine the suitability of coal for coke (fuel), coking, power generation o ...
are PFTNA (Pulsed Fast Thermal Neutron Activation), the
prompt gamma neutron activation analysis Prompt-gamma neutron activation analysis (PGAA) is a very widely applicable technique for determining the presence and amount of many elements simultaneously in samples ranging in size from micrograms to many grams. It is a non-destructive method, ...
(PGNAA) and Laser-induced breakdown spectroscopy ( LIBS). PFTNA and PGNAA technology rely on activation of the material on the conveyor belt by
neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behav ...
s, and the instantaneous emission of
gamma ray A gamma ray, also known as gamma radiation (symbol γ or \gamma), is a penetrating form of electromagnetic radiation arising from the radioactive decay of atomic nucleus, atomic nuclei. It consists of the shortest wavelength electromagnetic wav ...
s from nuclei which have absorbed neutrons. Capitalizing on the unique gamma ray spectrum associated with each element, the instrument can perform an analysis each minute on the composite spectrum to determine the overall elemental composition of the material. LIBS operate by focusing the laser onto a small area at the surface of the material forming a plasma plume. When plasma quickly cools down the atomic emission lines of the elements can be observed using
optical spectrometer An optical spectrometer (spectrophotometer, spectrograph or spectroscope) is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify mate ...
. Based on obtained spectra quantitative chemical analysis of the sample is performed.


References

* Alsop, Philip A.; Chen, Hung, Tseng, Herman. “Prompt gamma neutron activation analysis (PGNAA).” ''The Cement Plant Operations Handbook.'' Fifth ed. October 2007. * Berg, Joel L. “High Frequency Blend Control.” ''World Cement.'' March 1999. * Bond, J.E.; Coursaux, R.; Worthington, R.L. "Blending systems and control technologies for cement raw materials " Industry Applications Magazine, IEEE Nov/Dec 2000 Volume: 6 Issue:6 page: 49 - 59 * Bond, J.E.; Wintz, S. "Blending and control systems technologies for cement raw materials revisited - PGNA analyzer application review - An example from Lafarge's Davenport plant in Buffalo, Iowa USA" 53rd Cement Industry Technical Conference, 2011. Conference Record IEEE-IAS/PCA, May 2011, 18 pp. * Hook, Jeff and Darrell Leetham; “CrossBelt at Union Bridge.” ''International Cement Review.'' November 2008. * Foster, S.; Bond, J. "The history and future of nuclear elemental analyzers for product optimization in the cement industry", Cement Industry Technical Conference, 2006. Conference Record. IEEE, 9–14 April 2006, 18 pp. * Proctor, R. J. On-line Prompt Gamma Neutron Activation Analyzers”, ... Handbook, Editor-Gregory K. McMillan, Fifth Edition, McGraw Hill, 1999 * Woodward, Richard. “Transforming Pre-Blending Strategy.” ''World Cement.'' April 1997. * “On-line Analysers.” ''The World Cement Plant & Equipment Handbook.'' Volume 1. 1996. * Michael Gaft, M.; Nagli L. "Industrial Online Raw Materials Analyzer Based on Laser-Induced Breakdown Spectroscopy", Applied Spectroscopy, September 2014 Analytical chemistry