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A botryoidal ( ) texture or
mineral habit In mineralogy, crystal habit is the characteristic external shape of an individual crystal or crystal group. The habit of a crystal is dependent on its crystallographic form and growth conditions, which generally creates irregularities due to ...
, is one in which the
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
has an external form composed of many rounded segments, named for the Ancient Greek (), meaning "a bunch of
grape A grape is a fruit, botanically a berry, of the deciduous woody vines of the flowering plant genus ''Vitis''. Grapes are a non- climacteric type of fruit, generally occurring in clusters. The cultivation of grapes began perhaps 8,000 years ago, ...
s".Adjective form: ''botruoeidēs''
This is a common form for many minerals, particularly
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
and
malachite Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures ...
, which are known for frequently forming botryoidal masses. It is also a common form of
goethite Goethite (, ) is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the "α" polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient t ...
,
smithsonite Smithsonite, also known as zinc spar, is the mineral form of zinc carbonate ( Zn CO3). Historically, smithsonite was identified with hemimorphite before it was realized that they were two different minerals. The two minerals are very similar in app ...
,
fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs sca ...
, and
chrysocolla Chrysocolla ( ) is a hydrated copper phyllosilicate mineral and mineraloid with formula (x<1) or . The structure of the mineral has been questioned, as a 2006 spectrographic study suggest material identified as ...
. Similar habits are ''reniform'' (kidney-shaped) and ''mammillary'' (breast-shaped or partial spheres).


Formation

Minerals take on a botryoidal habit when they form in an environment containing many nuclei, specks of sand, dust, or other particulate matter to serve as sources of crystal nucleation. Acicular or fibrous crystals grow outward from these "seeds" at the same or very similar rate, resulting in radial
crystal growth A crystal is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions. Crystal growth is a major stage of a crystallization process, and consists of the a ...
. As these spheres grow, they can run into or overlap with others that are nearby, fusing together to form a botryoidal cluster. Since botryoidal growths are formed from many smaller crystals, botryoidal habit is usually independent of the specific
crystal structure In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystal, crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric pat ...
associated with any given mineral. This is how the habit can be observed in a variety of minerals that otherwise display distinct
euhedral Euhedral crystals (also known as idiomorphic or automorphic crystals) are those that are well-formed, with sharp, easily recognised faces. The opposite is anhedral (also known as '' xenomorphic'' or ''allotriomorphic''): a rock with an anhedra ...
forms.


References

* Klein, Cornelis and Cornelius S. Hurlbut, Jr.; 1985; ''Manual of Mineralogy''; Wiley; 20th ed.; p 199; {{ISBN, 0-471-80580-7 * http://www.minerals.net/mineral_glossary/botryoidal.aspx * http://www.britannica.com/EBchecked/topic/75161/botryoidal-texture Mineral habits