The Bodenstein number (abbreviated ''Bo'', named after
Max Bodenstein
Max Ernst August Bodenstein (July 15, 1871 – September 3, 1942) was a German physical chemist known for his work in chemical kinetics. He was first to postulate a chain reaction mechanism and that explosions are branched chain reactions, lat ...
) is a
dimensionless parameter
A dimensionless quantity (also known as a bare quantity, pure quantity, or scalar quantity as well as quantity of dimension one) is a quantity to which no Dimension (physics), physical dimension is assigned, with a corresponding International Sys ...
in
chemical reaction engineering
Chemical reaction engineering (reaction engineering or reactor engineering) is a specialty in chemical engineering or industrial chemistry dealing with chemical reactors. Frequently the term relates specifically to catalytic reaction systems wh ...
, which describes the ratio of the
amount of substance introduced by
convection
Convection is single or multiphase fluid flow that occurs spontaneously due to the combined effects of material property heterogeneity and body forces on a fluid, most commonly density and gravity (see buoyancy). When the cause of the conve ...
to that introduced by
diffusion
Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemica ...
. Hence, it characterises the
backmixing in a system and allows statements whether and how much volume elements or substances within a
chemical reactor
A chemical reactor is an enclosed volume in which a chemical reaction takes place. In chemical engineering, it is generally understood to be a process vessel used to carry out a chemical reaction, which is one of the classic unit operations in chem ...
mix due to the prevalent currents. It is defined as the ratio of the convection current to the
dispersion
Dispersion may refer to:
Economics and finance
* Dispersion (finance), a measure for the statistical distribution of portfolio returns
* Price dispersion, a variation in prices across sellers of the same item
*Wage dispersion, the amount of variat ...
current. The Bodenstein number is an element of the ''dispersion model of residence times'' and is therefore also called the ''dimensionless dispersion coefficient''.
[Matthias Bohnet (Hrsg.): ''Mechanische Verfahrenstechnik.'' Wiley-VCH, Weinheim 2004, , S. 213–229.]
Mathematically, two idealized extreme cases exist for the Bodenstein number. These, however, cannot be fully reached in practice:
*
corresponds to full backmixing, which is the ideal state to be reached in a
continuous stirred-tank reactor
The continuous stirred-tank reactor (CSTR), also known as vat- or backmix reactor, mixed flow reactor (MFR), or a continuous-''flow'' stirred-tank reactor (C''F''STR), is a common model for a chemical reactor in chemical engineering and environmen ...
.
*
corresponds to no backmixing, but a continuous through flow as in an ideal flow channel.
Control of the
flow velocity
In continuum mechanics the flow velocity in fluid dynamics, also macroscopic velocity in statistical mechanics, or drift velocity in electromagnetism, is a vector field used to mathematically describe the motion of a continuum. The length of the f ...
within a reactor allows to adjust the Bodenstein number to a pre-calculated desired value, so that the desired degree of backmixing of the substances in the reactor can be reached.
Determination of the Bodenstein number
The Bodenstein number is calculated according to
:
where
*
: flow velocity
*
: length of the reactor
*
: axial dispersion coefficient
It can also be determined experimentally from the distribution of the
residence time
The residence time of a fluid parcel is the total time that the parcel has spent inside a control volume (e.g.: a chemical reactor, a lake, a human body). The residence time of a set of parcels is quantified in terms of the frequency distributi ...
s. Assuming an
open system:
:
holds, where
*
: dimensionless variance
*
: variance of the mean residence time
*
: hydrodynamic residence time
References
Dimensionless numbers of chemistry
Dimensionless numbers of fluid mechanics
Chemical engineering