Blau Gas
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Blau gas (german: Blaugas) is an artificial
illuminating gas The history of gaseous fuel, important for lighting, heating, and cooking purposes throughout most of the 19th century and the first half of the 20th century, began with the development of analytical and pneumatic chemistry in the 18th century. ...
, similar to
propane Propane () is a three-carbon alkane with the molecular formula . It is a gas at standard temperature and pressure, but compressible to a transportable liquid. A by-product of natural gas processing and petroleum refining, it is commonly used a ...
, named after its inventor, Hermann Blau of
Augsburg Augsburg (; bar , Augschburg , links=https://en.wikipedia.org/wiki/Swabian_German , label=Swabian German, , ) is a city in Swabia, Bavaria, Germany, around west of Bavarian capital Munich. It is a university town and regional seat of the ' ...
, Germany. Not or rarely used or produced today, it was manufactured by decomposing
mineral oil Mineral oil is any of various colorless, odorless, light mixtures of higher alkanes from a mineral source, particularly a distillate of petroleum, as distinct from usually edible vegetable oils. The name 'mineral oil' by itself is imprecise, ...
s in
retort In a chemistry laboratory, a retort is a device used for distillation or dry distillation of substances. It consists of a spherical vessel with a long downward-pointing neck. The liquid to be distilled is placed in the vessel and heated. The ...
s by heat, and compressing the resulting
naphtha Naphtha ( or ) is a flammable liquid hydrocarbon mixture. Mixtures labelled ''naphtha'' have been produced from natural gas condensates, petroleum distillates, and the distillation of coal tar and peat. In different industries and regions ''n ...
until it liquefied. It was transported in liquid condition, and, like LPG, when released returns to a gaseous state. Blau gas has a rather water-like color. It was historically stored in steel cylinders for shipment, and, around the turn of the century, had the advantage of possessing the highest
specific energy Specific energy or massic energy is energy per unit mass. It is also sometimes called gravimetric energy density, which is not to be confused with energy density, which is defined as energy per unit volume. It is used to quantify, for example, sto ...
of all artificially produced gases. Chemically, Blau gas is similar to coal gas, but, unlike coal gas, is free from
carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simple ...
. Furthermore, Blau gas is difficult to bring to explosion. Blau gas was burned for lighting and heating; a less-pure form known as
Pintsch gas Carl Friedrich Julius Pintsch (6 January 1815 – 20 January 1884) was a German tinsmith, manufacturer and inventor who is primarily known for the invention of Pintsch gas. The gas, distilled from naphtha or other petroleum products, was wi ...
fuelled illuminated buoys and beacons (for navigation),
railroad car A railroad car, railcar (American and Canadian English), railway wagon, railway carriage, railway truck, railwagon, railcarriage or railtruck (British English and UIC), also called a train car, train wagon, train carriage or train truck, is a ...
lights and stoves in the late 19th and early 20th centuries. Blau gas is most famous, however, as the buoyancy compensating fuel for the
LZ 127 Graf Zeppelin LZ 127 ''Graf Zeppelin'' () was a German passenger-carrying, hydrogen-filled rigid airship that flew from 1928 to 1937. It offered the first commercial transatlantic passenger flight service. Named after the German airship pioneer Ferdinan ...
. Because it weighs approximately the same as
air The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing f ...
, burning Blau gas and thereby replacing its volume with air does not lighten the gas cells of an
airship An airship or dirigible balloon is a type of aerostat or lighter-than-air aircraft that can navigate through the air under its own power. Aerostats gain their lift from a lifting gas that is less dense than the surrounding air. In early ...
, thereby eliminating the need to adjust buoyancy or ballast in-flight."Blue Gas & Hydrogen". ''
Time Time is the continued sequence of existence and events that occurs in an apparently irreversible succession from the past, through the present, into the future. It is a component quantity of various measurements used to sequence events, to ...
'', 15 October 1928
Blau gas contains about 50% olefins (alkenes), 37%
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Eart ...
and other
alkane In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which ...
s, 6%
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, an ...
, while the rest is air. The heat of combustion is 122 MJ/m3.


See also

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August Riedinger August Riedinger (9 October 1845 – 15 January 1919) Augsburg city archive was a German businessman who operated gas companies in Germany and Europe and also participated in balloon manufacturing. Life Riedinger was born in 1845 as the son o ...
*
History of manufactured gas The history of gaseous fuel, important for lighting, heating, and cooking purposes throughout most of the 19th century and the first half of the 20th century, began with the development of analytical and pneumatic chemistry in the 18th century. ...
*
K-1 (airship) The K-1 was an experimental blimp designed by the United States Navy in 1929. Due to the inability to get Congressional approval for the construction of an airship the navy used the ploy of ordering a "universal" control car (type J/K) which coul ...


References


External links


Use of Blau gas on airship LZ-127 Graf Zeppelin
{{Fuel gas Fuel gas Lighting Aviation fuels Synthetic fuels Synthetic fuel technologies Airship technology