Black Copper
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Tenorite is a
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
oxide mineral The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. The minerals with complex anion groups such as the si ...
with the chemical formula
CuO Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite. It is ...
.


Occurrence

Tenorite occurs in the weathered or
oxidized Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...
zone associated with deeper primary
copper sulfide Copper sulfides describe a family of chemical compounds and minerals with the formula CuxSy. Both minerals and synthetic materials comprise these compounds. Some copper sulfides are economically important ores. Prominent copper sulfide minerals ...
orebodies. Tenorite commonly occurs with
chrysocolla Chrysocolla ( ) is a hydrated copper phyllosilicate mineral and mineraloid with formula (x<1) or . The structure of the mineral has been questioned, as a 2006 spectrographic study suggest material identified as ...
and the copper carbonates,
azurite Azurite is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the Type locality (geology), type locality at Chessy, Rhône, Chessy-les-Mines near ...
and
malachite Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures ...
. The dull grey-black color of tenorite contrasts sharply with the often intergrown blue
chrysocolla Chrysocolla ( ) is a hydrated copper phyllosilicate mineral and mineraloid with formula (x<1) or . The structure of the mineral has been questioned, as a 2006 spectrographic study suggest material identified as ...
.
Cuprite Cuprite is an oxide mineral composed of copper(I) oxide Cu2O, and is a minor ore of copper. Its dark crystals with red internal reflections are in the isometric system hexoctahedral class, appearing as cubic, octahedral, or dodecahedral forms, o ...
,
native copper Native copper is an uncombined form of copper that occurs as a natural mineral. Copper is one of the few metallic elements to occur in native form, although it most commonly occurs in oxidized states and mixed with other elements. Native coppe ...
and FeMn oxides also occur in this environment. In addition to the hydrothermal, tenorite also occurs as a
volcanic sublimate A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plates are ...
from
Vesuvius Mount Vesuvius ( ; it, Vesuvio ; nap, 'O Vesuvio , also or ; la, Vesuvius , also , or ) is a somma-stratovolcano located on the Gulf of Naples The Gulf of Naples (), also called the Bay of Naples, is a roughly 15-kilometer-wide (9 ...
,
Campania Campania (, also , , , ) is an administrative Regions of Italy, region of Italy; most of it is in the south-western portion of the Italian peninsula (with the Tyrrhenian Sea to its west), but it also includes the small Phlegraean Islands and the i ...
, and Etna,
Sicily (man) it, Siciliana (woman) , population_note = , population_blank1_title = , population_blank1 = , demographics_type1 = Ethnicity , demographics1_footnotes = , demographi ...
,
Italy Italy ( it, Italia ), officially the Italian Republic, ) or the Republic of Italy, is a country in Southern Europe. It is located in the middle of the Mediterranean Sea, and its territory largely coincides with the homonymous geographical re ...
. As a sublimate it occurs with copper chlorides, alkali chlorides and
cotunnite Cotunnite is the natural mineral form of lead(II) chloride with formula PbCl2. It was first described in 1825 from an occurrence on Mount Vesuvius, Naples Province, Campania, Italy. It was named for Domenico Cotugno (Cotunnius) (1736–1822), Ita ...
. The Vesuvian sublimate occurrence was originally named ''melaconise'' or ''melaconite'' by F. S. Beudant in 1832.Chisholm, Hugh, ed. (1911). Encyclopædia Britannica (11th ed.). Cambridge University Press Tenorite was named in 1841 after the Italian botanist
Michele Tenore Michele Tenore (5 May 1780 – 19 July 1861) was an Italian botanist active in Naples, Italy. Tenore studied at the University of Naples, receiving his medical degree in 1800. Then he was a friend of botanists Domenico Maria Leone Cirillo (1739– ...
(1780–1861).


See also

*
Cuprite Cuprite is an oxide mineral composed of copper(I) oxide Cu2O, and is a minor ore of copper. Its dark crystals with red internal reflections are in the isometric system hexoctahedral class, appearing as cubic, octahedral, or dodecahedral forms, o ...
CuO *
List of minerals This is a list of minerals for which there are articles on Wikipedia. Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a m ...
*
List of minerals named after people This is a list of minerals named after people. The chemical composition follows name. A *Abelsonite: C31H32N4Ni – American physicist Philip Hauge Abelson (1913–2004)alfred *Abswurmbachite: Cu2+Mn3+6O8SiO4 – German mineralogist I ...


References

Copper(II) minerals Oxide minerals Monoclinic minerals Minerals in space group 15 {{oxide-mineral-stub