Bischofite is a hydrous

magnesium chloride Magnesium chloride is the family of inorganic compounds with the formula , where x can range from 0 to 12. These salts are colorless or white solids that are highly soluble in water. These compounds and their solutions, both of which occur in natu ...

mineral with formula MgCl₂·6H₂O. It belongs to halides and is a sea salt concentrate. It contains many macro- and micro-elements vital for human health, in much higher concentrations than can be found in sea or ocean salt. The main bischofite compound is magnesium chloride (up to 350 g/L), moreover, it contains about 70 other elements as impurities, including

potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...

sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...

bromine Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest element in group 17 of the periodic table ( halogens) and is a volatile red-brown liquid at room temperature that evaporates readily to form a simi ...

, boron,

calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar t ...

silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ta ...

, molybdenum,

silver Silver is a chemical element with the symbol Ag (from the Latin ', derived from the Proto-Indo-European ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical ...

zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...

iron Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...

and

copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...

History

Bischofite is named in honor of German geologist

Gustav Bischof Karl Gustav Bischof (January 18, 1792 – November 30, 1870) was a German chemist, born in Nuremberg. He studied at Erlangen where he became a university lecturer ("Privatdozent") in 1815. In 1819 he was appointed to the position of an extra-O ...

(1792–1870). Its discovery (1877) is attributed to Carl Christian Ochsenius. At its type locality bischofite it an

evaporite An evaporite () is a water- soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as ocean ...

formed in an ancient seabed, which was deposited more than 200 million years ago, during the

Permian The Permian ( ) is a geologic period and System (stratigraphy), stratigraphic system which spans 47 million years from the end of the Carboniferous Period million years ago (Mya), to the beginning of the Triassic Period 251.9 Mya. It is the last ...

Period. Its composotion can be explained by high content of magnesium chloride in the primordial ocean. In 1930–1950, vast bischofite deposits were discovered near the

Volga River The Volga (; russian: Во́лга, a=Ru-Волга.ogg, p=ˈvoɫɡə) is the longest river in Europe. Situated in Russia, it flows through Central Russia to Southern Russia and into the Caspian Sea. The Volga has a length of , and a catchme ...

Russia Russia (, , ), or the Russian Federation, is a transcontinental country spanning Eastern Europe and Northern Asia. It is the largest country in the world, with its internationally recognised territory covering , and encompassing one-eig ...

. The mineral is mined by dissolving an underground dry mineral stratum with artesian water. The resulting brine is pumped out.

Deposits

Bischofite deposits differ by their composition: some of them are salt basins where bischofite is mixed with other minerals such as

carnallite Carnallite (also carnalite) is an evaporite mineral, a hydrated potassium magnesium chloride with formula KMgCl3·6(H2O). It is variably colored yellow to white, reddish, and sometimes colorless or blue. It is usually massive to fibrous with rare ...

halite Halite (), commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride ( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, p ...

kieserite Kieserite, or magnesium sulfate monohydrate, is a hydrous magnesium sulfate mineral with formula (MgSO4·H2O). It has a vitreous luster and it is colorless, grayish-white or yellowish. Its hardness is 3.5 and crystallizes in the monoclinic cry ...

and anhydrite. These are the so-called bischofite containing rocks which have pink-brown-yellow and orange-red colors. They contain 36–58% of bischofite. Carnallite deposits are known in

Staßfurt Staßfurt (Stassfurt) () is a town in the Salzlandkreis district, in Saxony-Anhalt, Germany. It is situated on both sides of the river Bode, approximately northeast of Aschersleben, and south of Magdeburg. Pop. (2005) 23,538. It was one of th ...

Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...

– where bischofite was first discovered, and carnallite is one of the most important minerals in potassium salt deposits (Solykam deposit,

Ural Ural may refer to: *Ural (region), in Russia and Kazakhstan *Ural Mountains, in Russia and Kazakhstan *Ural (river), in Russia and Kazakhstan * Ual (tool), a mortar tool used by the Bodo people of India *Ural Federal District, in Russia *Ural econ ...

, Russia). Sub-surface bischofite layers were also discovered in

Kazakhstan Kazakhstan, officially the Republic of Kazakhstan, is a transcontinental country located mainly in Central Asia and partly in Eastern Europe. It borders Russia to the north and west, China to the east, Kyrgyzstan to the southeast, Uzbeki ...

Turkmenistan Turkmenistan ( or ; tk, Türkmenistan / Түркменистан, ) is a country located in Central Asia, bordered by Kazakhstan to the northwest, Uzbekistan to the north, east and northeast, Afghanistan to the southeast, Iran to the sout ...

, China and the US. There are bischofite-rich deposits with concentrations of 93–96% of the mineral. One of those rare deposits is located in the

Volgograd Volgograd ( rus, Волгогра́д, a=ru-Volgograd.ogg, p=vəɫɡɐˈɡrat), formerly Tsaritsyn (russian: Цари́цын, Tsarítsyn, label=none; ) (1589–1925), and Stalingrad (russian: Сталингра́д, Stalingrád, label=none; ) ...

region of Russia. Another one was found in 1990s in the Poltava region in

Ukraine Ukraine ( uk, Україна, Ukraïna, ) is a country in Eastern Europe. It is the second-largest European country after Russia, which it borders to the east and northeast. Ukraine covers approximately . Prior to the ongoing Russian inv ...

. This is one of the deepest () and oldest bischofite deposits.

Applications

Bischofite has many applications ranging from construction materials (tile, stone) to agriculture (preplant seeds, plant processing during vegetation period), oil extraction (for grouting and solidifying mortars), medical and chemical industry (production of magnesium metal). Bishofite is used in form of compresses to treat joint diseases such as arthritis, rheumatic fever

osteoarthritis Osteoarthritis (OA) is a type of degenerative joint disease that results from breakdown of joint cartilage and underlying bone which affects 1 in 7 adults in the United States. It is believed to be the fourth leading cause of disability in the w ...

rheumatoid arthritis Rheumatoid arthritis (RA) is a long-term autoimmune disorder that primarily affects joints. It typically results in warm, swollen, and painful joints. Pain and stiffness often worsen following rest. Most commonly, the wrist and hands are invol ...

radiculitis Radicular pain, or radiculitis, is pain "radiated" along the dermatome (sensory distribution) of a nerve due to inflammation or other irritation of the nerve root (radiculopathy) at its connection to the spinal column. A common form of radicu ...

calcaneal spur A calcaneal spur (also known as a heel spur) is a bony outgrowth from the calcaneal tuberosity (heel bone). Calcaneal spurs are typically detected by x-ray examination. It is a form of exostosis. When a foot is exposed to constant stress, calci ...

and traumas, especially in rehabilitation centers in Ukraine, Russia, Belarus, and Lithuania. Bischofite is also applied in gel form. Bischofite is used in the production of the industrial Sorel cement and synthetic

. Bischofite solution is applied to deice roads, similar to sodium chloride, but it is less corrosive. It is also used in agriculture, veterinary medicine and cattle breeding to increase the crop yield and treat animals.

References

External links

{{commonscat-inline, Bischofite Halide minerals Magnesium minerals Evaporite Monoclinic minerals Minerals in space group 12