Binary Chemical Munition
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__NOTOC__ Binary chemical weapons or munitions are
chemical weapon A chemical weapon (CW) is a specialized munition that uses chemicals formulated to inflict death or harm on humans. According to the Organisation for the Prohibition of Chemical Weapons (OPCW), this can be any chemical compound intended as a ...
s which contain the
toxic Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacterium, or plant, as well as the effect on a subst ...
agent in its active state as chemical
precursor Precursor or Precursors may refer to: *Precursor (religion), a forerunner, predecessor ** The Precursor, John the Baptist Science and technology * Precursor (bird), a hypothesized genus of fossil birds that was composed of fossilized parts of unr ...
s that are significantly less toxic than the agent. This improves the safety of storing, transporting, and disposing of the weapon. Commonly, firing the munition removes a barrier between two precursors. These react to form the intended agent which is then
aerosol An aerosol is a suspension (chemistry), suspension of fine solid particles or liquid Drop (liquid), droplets in air or another gas. Aerosols can be natural or Human impact on the environment, anthropogenic. Examples of natural aerosols are fog o ...
ized and distributed by a bursting charge. Binary chemical weapons are chemical weapons within the scope of the
Chemical Weapons Convention The Chemical Weapons Convention (CWC), officially the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction, is an arms control treaty administered by the Organisation for ...
and therefore their production, use and stockpiling is forbidden in most countries, as at least one of the individual chemicals is likely to be a
Schedule 1 Schedule 1 may refer to: * Schedule I Controlled Substances within the US Controlled Substances Act * Schedule I Controlled Drugs and Substances within the Canadian Controlled Drugs and Substances Act * Schedule I Psychotropic Substances within t ...
chemical for which large scale production is forbidden.


Examples

One example of a binary chemical weapon is the
United States Army The United States Army (USA) is the land service branch of the United States Armed Forces. It is one of the eight U.S. uniformed services, and is designated as the Army of the United States in the U.S. Constitution.Article II, section 2, cla ...
M687 The M687 was an American 155 mm binary sarin chemical artillery shell. The design was standardized in 1976 and production began on December 16, 1987 at Pine Bluff Arsenal, Pine Bluff, Arkansas. Production was halted three years later, following th ...
. In the M687,
methylphosphonyl difluoride Methylphosphonyl difluoride (DF), also known as EA-1251 or difluoro, is a chemical weapon precursor. Its chemical formula is CH3POF2. It is a List of Schedule 1 substances (CWC), Schedule 1 substance under the Chemical Weapons Convention. It is ...
(military name: DF, a
Schedule 1 Schedule 1 may refer to: * Schedule I Controlled Substances within the US Controlled Substances Act * Schedule I Controlled Drugs and Substances within the Canadian Controlled Drugs and Substances Act * Schedule I Psychotropic Substances within t ...
chemical) and a mixture of two agents held in chambers within the munition, separated by a partition. When the weapon is fired,
acceleration In mechanics, acceleration is the rate of change of the velocity of an object with respect to time. Accelerations are vector quantities (in that they have magnitude and direction). The orientation of an object's acceleration is given by the ...
causes the partition to break, and the precursors are mixed by the rotation of the munition in flight, producing
sarin Sarin (NATO designation GB G-series, "B"">Nerve_agent#G-series.html" ;"title="hort for Nerve agent#G-series">G-series, "B" is an extremely toxic synthetic organophosphorus compound.Soviet Union The Soviet Union,. officially the Union of Soviet Socialist Republics. (USSR),. was a transcontinental country that spanned much of Eurasia from 1922 to 1991. A flagship communist state, it was nominally a federal union of fifteen national ...
and later
Russian Federation Russia (, , ), or the Russian Federation, is a List of transcontinental countries, transcontinental country spanning Eastern Europe and North Asia, Northern Asia. It is the List of countries and dependencies by area, largest country in the ...
experimented with binary munitions capable of mixing and distributing two agents that would work together in worsening the weapon's effects, an example of which would be the combination of
nerve agents Nerve agents, sometimes also called nerve gases, are a class of organic chemicals that disrupt the mechanisms by which nerves transfer messages to organs. The disruption is caused by the blocking of acetylcholinesterase (AChE), an enzyme that ...
with
blister agents A blister agent (or vesicant), is a chemical compound that causes severe skin, eye and mucosal pain and irritation. They are named for their ability to cause severe chemical burns, resulting in painful water blisters on the bodies of those affec ...
. The director of a non- proliferation research program of the
Middlebury Institute of International Studies at Monterey The Middlebury Institute of International Studies at Monterey (MIIS), formerly known as the Monterey Institute of International Studies, is an American graduate school of Middlebury College, a private college in Middlebury, Vermont. Established ...
has stated that the
death of Kim Jong-nam Death is the irreversible cessation of all biological functions that sustain an organism. For organisms with a brain, death can also be defined as the irreversible cessation of functioning of the whole brain, including brainstem, and brain ...
due to poisoning with VX was likely carried out with a binary version of the agent, since VX fumes would otherwise have killed the suspected attackers.


In popular culture

* A miniature binary weapon is used in an
assassination Assassination is the murder of a prominent or important person, such as a head of state, head of government, politician, world leader, member of a royal family or CEO. The murder of a celebrity, activist, or artist, though they may not have ...
in the
Frederick Forsyth Frederick McCarthy Forsyth (born 25 August 1938) is an English novelist and journalist. He is best known for thrillers such as ''The Day of the Jackal'', ''The Odessa File'', '' The Fourth Protocol'', '' The Dogs of War'', ''The Devil's Alter ...
novel ''
The Devil's Alternative ''The Devil's Alternative'' is a novel by British writer Frederick Forsyth first published in 1979. It was his fourth full-length novel and marked a new direction in his work, setting the story in the near-future (in 1982) rather than in the rec ...
''. It consists of two half- capsules, a non-resistant one containing
potassium cyanide Potassium cyanide is a compound with the formula KCN. This colorless crystalline salt, similar in appearance to sugar, is highly soluble in water. Most KCN is used in gold mining, organic synthesis, and electroplating. Smaller applications includ ...
and an acid-resistant one containing
hydrochloric acid Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid Acid strength is the tendency of an acid, symbol ...
. The substances mix after the halves are assembled and the seal between them is broken, and form
hydrogen cyanide Hydrogen cyanide, sometimes called prussic acid, is a chemical compound with the formula HCN and structure . It is a colorless, extremely poisonous, and flammable liquid that boils slightly above room temperature, at . HCN is produced on an ...
. The surplus acid eats through the capsule walls of the non-resistant half, and after a delay of several hours, the lethal content is released into the
intestinal tract The gastrointestinal tract (GI tract, digestive tract, alimentary canal) is the tract or passageway of the digestive system that leads from the mouth to the anus. The GI tract contains all the major organs of the digestive system, in humans and ...
of whoever ingested it. While technically possible, the assassination tool as discussed in the novel is presumably fictional. However, there are claims that in September 2003, the SVR (Russian Foreign Intelligence Service) prepared to assassinate Boris Berezovsky with a similar device.Goldfarb & Litvinenko (2007) * In the 10th and 11th episodes of the 6th season of TV-series ''
Dexter Dexter may refer to: Arts and entertainment * Dexter, the main character of the American animated series ''Dexter's Laboratory'' that aired from 1996 to 2003 * Dexter, a fictional character in the British Diary of a Bad Man#Main, web series ''Diar ...
'' are shown preparation and application of binary weapon consisting of two containers filled with DF and
isopropyl alcohol Isopropyl alcohol (IUPAC name propan-2-ol and also called isopropanol or 2-propanol) is a colorless, flammable organic compound with a pungent alcoholic odor. As an isopropyl group linked to a hydroxyl group (chemical formula ) it is the simple ...
. When mixed, the two substances form
sarin Sarin (NATO designation GB G-series, "B"">Nerve_agent#G-series.html" ;"title="hort for Nerve agent#G-series">G-series, "B" is an extremely toxic synthetic organophosphorus compound.xXx XXX may refer to: Codes and symbols * 30 (number), Roman numeral XXX * XXX, designating pornography ** XXX, an X rating#United_States, X rating ** .xxx, an internet top-level domain intended for pornographic sites * XXX, a symbol of the straight ...
'' features a Soviet-made binary chemical weapon codenamed "Silent Night", after its supposed ability to render an area silent by killing its inhabitants. In the movie, the chemical was acquired by the terrorist group Anarchy-99, and their leader, Yorgi, plans to launch missiles containing Silent Night from an autonomous solar-powered submarine called Ahab, with the intent to sow chaos among civilized nations as they all blame each other for the attacks. *
Michael Crichton John Michael Crichton (; October 23, 1942 – November 4, 2008) was an American author and filmmaker. His books have sold over 200 million copies worldwide, and over a dozen have been adapted into films. His literary works heavily feature tech ...
's 1972 novel ''
Binary Binary may refer to: Science and technology Mathematics * Binary number, a representation of numbers using only two digits (0 and 1) * Binary function, a function that takes two arguments * Binary operation, a mathematical operation that t ...
'' uses a binary nerve agent "VZ" as the main plot device intended to kill the President of the United States, and indirectly most of the inhabitants of San Diego.


See also

*
Binary explosive A binary explosive or two-component explosive is an explosive consisting of two components, neither of which is explosive by itself, which have to be mixed in order to become explosive. Examples of common binary explosives include Oxyliquit (liquid ...
*
Binary liquid Binary liquid is a type of chemical combination, which creates a special reaction or feature as a result of mixing two liquid chemicals, that are normally inert or have no function by themselves. A number of chemical products are produced as a resu ...
* Mubtakkar *
QL (chemical) Isopropyl aminoethylmethyl phosphonite (NATO designation QL), also known as ''O''-(2-diisopropylaminoethyl) '-ethyl methylphosphonite, is a precursor chemical to the nerve agent VX and VR-56. It is a colorless liquid with a strong fishy odor, a ...
(isopropyl aminoethylmethyl phosphonite)


Citations


General and cited references

* (2007): '' Death of a dissident: The Poisoning of Alexander Litvinenko and the Return of the KGB''. The Free Press. {{DEFAULTSORT:Binary Chemical Weapon 2 (number) Chemical weapons