![Volcanic Tuff of Green River Formation in Wyoming](https://upload.wikimedia.org/wikipedia/commons/3/39/Volcanic_Tuff_of_Green_River_Formation_in_Wyoming.jpg)
Bentonite () is an
absorbent swelling
clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4).
Clays develop plasticity when wet, due to a molecular film of water surrounding the clay par ...
consisting mostly of
montmorillonite
Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite group, ...
(a type of
smectite
A smectite (from ancient Greek ''σμηκτός'' smektos 'lubricated'; ''σμηκτρίς'' smektris 'walker's earth', 'fuller's earth'; rubbing earth; earth that has the property of cleaning) is a mineral mixtures of various swelling sheet sil ...
) which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelling capacity than Ca-montmorillonite.
Bentonite usually forms from the weathering of
volcanic ash
Volcanic ash consists of fragments of rock, mineral crystals, and volcanic glass, created during volcano, volcanic eruptions and measuring less than 2 mm (0.079 inches) in diameter. The term volcanic ash is also often loosely used t ...
in
seawater
Seawater, or salt water, is water from a sea or ocean. On average, seawater in the world's oceans has a salinity of about 3.5% (35 g/L, 35 ppt, 600 mM). This means that every kilogram (roughly one liter by volume) of seawater has appro ...
, or by
hydrothermal circulation
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
through the
porosity
Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
of volcanic ash beds,
which converts (
devitrification
Devitrification is the process of crystallization in a formerly crystal-free (amorphous) glass. The term is derived from the Latin ''vitreus'', meaning '' glassy'' and ''transparent''.
Devitrification in glass art
Devitrification occurs in glass a ...
) the
volcanic glass
Volcanic glass is the amorphous (uncrystallized) product of rapidly cooling magma. Like all types of glass, it is a state of matter intermediate between the closely packed, highly ordered array of a crystal and the highly disordered array of liqu ...
(
obsidian
Obsidian () is a naturally occurring volcanic glass formed when lava extrusive rock, extruded from a volcano cools rapidly with minimal crystal growth. It is an igneous rock.
Obsidian is produced from felsic lava, rich in the lighter elements s ...
,
rhyolite
Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral ...
,
dacite
Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained (aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyolite. ...
) present in the ash into clay minerals. In the mineral alteration process, a large fraction (up to 40-50 wt.%) of
amorphous
In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid, glassy solid) is a solid that lacks the long-range order that is characteristic of a crystal.
Etymology
The term comes from the Greek ''a'' ("wi ...
silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
is
dissolved and
leached away, leaving the bentonite deposit in place. Bentonite beds are white or pale blue or green (traces of
reduced ) in fresh exposures, turning to a cream color and then yellow, red, or brown (traces of
oxidized
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...
) as the exposure is weathered further.
As a swelling clay, bentonite has the ability to absorb large quantities of water, which increases its volume by up to a factor of eight.
This makes bentonite beds unsuitable for building and road construction. However, the swelling property is used to advantage in
drilling mud
In geotechnical engineering, drilling fluid, also called drilling mud, is used to aid the drilling of boreholes into the earth. Often used while drilling oil and natural gas wells and on exploration drilling rigs, drilling fluids are also us ...
and groundwater sealants. The montmorillonite / smectite making up bentonite is an
aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
phyllosilicate
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.
In mineralogy, silica (silicon dioxide, ) is usually consid ...
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
, which takes the form of microscopic platy grains. These give the clay a very large total surface area, making bentonite a valuable
adsorbent
Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a ...
. The plates also adhere to each other when wet. This gives the clay a cohesiveness that makes it useful as a
binder and as an additive to improve the plasticity of
kaolinite
Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
clay used for
pottery
Pottery is the process and the products of forming vessels and other objects with clay and other ceramic materials, which are fired at high temperatures to give them a hard and durable form. Major types include earthenware, stoneware and por ...
.
One of the first findings of bentonite was in the
Cretaceous
The Cretaceous ( ) is a geological period that lasted from about 145 to 66 million years ago (Mya). It is the third and final period of the Mesozoic Era, as well as the longest. At around 79 million years, it is the longest geological period of th ...
Benton Shale
The Benton Shale (also Benton Formation or Benton Group) is a geologic formation name historically used in Montana, Wyoming, North Dakota, South Dakota, Colorado, Kansas, and Nebraska. In the "mile high" plains in the center of the continent, th ...
near
Rock River, Wyoming
Rock River is a town in Albany County, Wyoming, United States. As of the 2010 census, the town population was 245.
Geography
Rock River is located at (41.740770, –105.974602).
According to the United States Census Bureau, the town has a tota ...
. The
Fort Benton Group, along with others in stratigraphic succession, was named after
Fort Benton, Montana
Fort Benton is a city in and the county seat of Chouteau County, Montana, United States. Established in 1846, Fort Benton is the oldest continuously occupied settlement in Montana. The city's waterfront area, the most important aspect of its 1 ...
, in the mid-19th century by
Fielding Bradford Meek
Fielding Bradford Meek (December 10, 1817 – December 22, 1876) was an American geologist and a paleontologist who specialized in the invertebrates.
Biography
The son of a lawyer, he was born in Madison, Indiana. In early life he was in bu ...
and
F. V. Hayden of the U.S. Geological Survey.
Bentonite has since been found in many other locations, including China and Greece (bentonite deposit of the
Milos
Milos or Melos (; el, label=Modern Greek, Μήλος, Mílos, ; grc, Μῆλος, Mêlos) is a volcanic Greek island in the Aegean Sea, just north of the Sea of Crete. Milos is the southwesternmost island in the Cyclades group.
The ''Venus d ...
volcanic island in the
Aegean Sea
The Aegean Sea ; tr, Ege Denizi (Greek language, Greek: Αιγαίο Πέλαγος: "Egéo Pélagos", Turkish language, Turkish: "Ege Denizi" or "Adalar Denizi") is an elongated embayment of the Mediterranean Sea between Europe and Asia. It ...
). The total worldwide production of bentonite in 2018 was 20,400,000 metric tons.
[T. Brown ''et al.'' 2020. ]
World Mineral Production 2014–18
'. British Geological Survey, Nottingham, England.
Types
![Montmorillonite-en](https://upload.wikimedia.org/wikipedia/commons/0/0c/Montmorillonite-en.svg)
In geology, the term ''bentonite'' is applied to a type of
claystone
Mudrocks are a class of fine-grained siliciclastic sedimentary rocks. The varying types of mudrocks include siltstone, claystone, mudstone, slate, and shale. Most of the particles of which the stone is composed are less than and are too sm ...
(a clay rock, not a clay mineral) composed mostly of
montmorillonite
Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite group, ...
(a clay mineral from the
smectite
A smectite (from ancient Greek ''σμηκτός'' smektos 'lubricated'; ''σμηκτρίς'' smektris 'walker's earth', 'fuller's earth'; rubbing earth; earth that has the property of cleaning) is a mineral mixtures of various swelling sheet sil ...
group). It forms by devitrification of
volcanic ash
Volcanic ash consists of fragments of rock, mineral crystals, and volcanic glass, created during volcano, volcanic eruptions and measuring less than 2 mm (0.079 inches) in diameter. The term volcanic ash is also often loosely used t ...
or
tuff
Tuff is a type of rock made of volcanic ash ejected from a vent during a volcanic eruption. Following ejection and deposition, the ash is lithified into a solid rock. Rock that contains greater than 75% ash is considered tuff, while rock cont ...
,
typically in a marine environment.
This results in a very soft, porous rock that may contain residual crystals of more resistant minerals, and which feels soapy or greasy to the touch. However, in commercial and industrial applications, the term ''bentonite'' is used more generally to refer to any swelling clay composed mostly of
smectite
A smectite (from ancient Greek ''σμηκτός'' smektos 'lubricated'; ''σμηκτρίς'' smektris 'walker's earth', 'fuller's earth'; rubbing earth; earth that has the property of cleaning) is a mineral mixtures of various swelling sheet sil ...
clay minerals, which includes montmorillonite.
The undifferentiated reference to the weathered volcanic rock for the geologist or to the industrial mixture of swelling clays can be a source of confusion.
The montmorillonite making up bentonite is an
aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
phyllosilicate
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.
In mineralogy, silica (silicon dioxide, ) is usually consid ...
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
whose crystal structure is described as low-charge ''TOT''. This means that a crystal of montmorillonite consists of layers, each of which is made up of two ''T'' sheets bonded to either side of an ''O'' sheet. The ''T'' sheets are so called because each aluminium or silicon ion in the sheet is surrounded by four oxygen ions arranged as a tetrahedron. The ''O'' sheets are so called because each aluminium ion is surrounded by six oxygen or hydroxyl ions arranged as an octahedron. The complete ''TOT'' layer has a weak negative electrical charge, and this is neutralized by calcium or sodium
cation
An ion () is an atom or molecule with a net electrical charge.
The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
s that bind adjacent layers together, with a distance between layers of about 1
nanometer
330px, Different lengths as in respect to the molecular scale.
The nanometre (international spelling as used by the International Bureau of Weights and Measures; SI symbol: nm) or nanometer (American and British English spelling differences#-re ...
. Because the negative charge is weak, only a fraction of the possible cation sites on the surface of a ''TOT'' layer actually contain calcium or sodium. Water molecules can easily infiltrate between sheets and fill the remaining sites. This accounts for the swelling property of montmorillonite and other smectite clay minerals.
The different types of bentonite are each named after the respective dominant cation. For industrial purposes, two main classes of bentonite are recognized: sodium and calcium bentonite. Sodium bentonite is the more valuable but calcium bentonite is more common.
In
stratigraphy
Stratigraphy is a branch of geology concerned with the study of rock (geology), rock layers (Stratum, strata) and layering (stratification). It is primarily used in the study of sedimentary rock, sedimentary and layered volcanic rocks.
Stratigrap ...
and
tephrochronology
250px, Tephra horizons in south-central Iceland. The thick and light coloured layer at the height of the volcanologist's hands is rhyolitic tephra from Hekla.
Tephrochronology is a Geochronology, geochronological technique that uses discrete la ...
, completely
devitrified (weathered volcanic glass) ash-fall beds are sometimes also referred to as "K-bentonites" (the illitized clay rock) when the dominant clay species is
illite
Illite is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina ...
(a non-swelling clay).
However, in pure clay mineralogy, the term illite is more appropriate than "K-bentonite" (the "altered K-rock") because it is a distinct type of non-swelling clay while the commercial term bentonite implicitly refers to a swelling clay, a
smectite
A smectite (from ancient Greek ''σμηκτός'' smektos 'lubricated'; ''σμηκτρίς'' smektris 'walker's earth', 'fuller's earth'; rubbing earth; earth that has the property of cleaning) is a mineral mixtures of various swelling sheet sil ...
(in the European and UK terminology), or a
montmorillonite
Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite group, ...
(in the US terminology).
Sodium bentonite
Sodium bentonite expands when wet, absorbing as much as several times its dry
mass
Mass is an intrinsic property of a body. It was traditionally believed to be related to the quantity of matter in a physical body, until the discovery of the atom and particle physics. It was found that different atoms and different elementar ...
in water. Because of its excellent
colloid
A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others extend ...
al properties,
[ it is often used in ]drilling mud
In geotechnical engineering, drilling fluid, also called drilling mud, is used to aid the drilling of boreholes into the earth. Often used while drilling oil and natural gas wells and on exploration drilling rigs, drilling fluids are also us ...
for oil
An oil is any nonpolar chemical substance that is composed primarily of hydrocarbons and is hydrophobic (does not mix with water) & lipophilic (mixes with other oils). Oils are usually flammable and surface active. Most oils are unsaturated ...
and gas wells and boreholes for geotechnical and environmental investigations. The property of swelling also makes sodium bentonite useful as a sealant, since it provides a self-sealing, low permeability barrier. It is used to line the base of landfills
A landfill site, also known as a tip, dump, rubbish dump, garbage dump, or dumping ground, is a site for the disposal of waste materials. Landfill is the oldest and most common form of waste disposal, although the systematic burial of the waste ...
, for example. Bentonite is also part of the backfill material used at the Waste Isolation Pilot Project
The Waste Isolation Pilot Plant, or WIPP, is the world's third deep geological repository (after Germany's Repository for radioactive waste Morsleben and the Schacht Asse II salt mine) licensed to store transuranic radioactive waste for 10,000 ...
. Various surface modifications to sodium bentonite improve some rheological
Rheology (; ) is the study of the flow of matter, primarily in a fluid (liquid or gas) state, but also as "soft solids" or solids under conditions in which they respond with plastic flow rather than deforming elastically in response to an applie ...
or sealing performance in geoenvironmental applications, for example, the addition of polymers.
Sodium bentonite can be combined with elemental sulfur as fertilizer prill
A prill is a small aggregate or globule of a material, most often a dry sphere, formed from a melted liquid through spray crystallization. Prilled is a term used in mining and manufacturing to refer to a product that has been Pelletizing, pelleti ...
s. These permit slow oxidation of the sulfur to sulfate
The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ar ...
, a plant nutrient needed for some crops like onion
An onion (''Allium cepa'' L., from Latin ''cepa'' meaning "onion"), also known as the bulb onion or common onion, is a vegetable that is the most widely cultivated species of the genus ''Allium''. The shallot is a botanical variety of the onion ...
s or garlic
Garlic (''Allium sativum'') is a species of bulbous flowering plant in the genus ''Allium''. Its close relatives include the onion, shallot, leek, chive, Allium fistulosum, Welsh onion and Allium chinense, Chinese onion. It is native to South A ...
synthesizing a lot of organo-sulfur compounds, and maintain sulfate levels in rainfall-leached soil longer than either pure powdered sulfur or gypsum
Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywall. ...
. Sulfur/bentonite pads with added organic fertilizers have been used for organic farming.
Calcium bentonite
Calcium bentonite is a useful adsorbent
Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a ...
of ions in solution, as well as fats and oils. It is the main active ingredient of fuller's earth
Fuller's earth is any clay material that has the capability to decolorize oil or other liquids without the use of harsh chemical treatment. Fuller's earth typically consists of palygorskite (attapulgite) or bentonite.
Modern uses of fuller's ea ...
, probably one of the earliest industrial cleaning agents. It has significantly less swelling capacity than sodium bentonite.
Calcium bentonite may be converted to sodium bentonite (termed sodium beneficiation or sodium activation) to exhibit many of sodium bentonite's properties by an ion exchange
Ion exchange is a reversible interchange of one kind of ion present in an insoluble solid with another of like charge present in a solution surrounding the solid with the reaction being used especially for softening or making water demineralised, ...
process. As commonly practiced, this means adding 5–10% of a soluble sodium salt such as sodium carbonate
Sodium carbonate, , (also known as washing soda, soda ash and soda crystals) is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield moderately alkaline solutions ...
to wet bentonite, mixing well, and allowing time for the ion exchange to take place and water to remove the exchanged calcium. Some properties, such as viscosity and fluid loss of suspensions, of sodium-beneficiated calcium bentonite (or sodium-activated bentonite) may not be fully equivalent to those of natural sodium bentonite. For example, residual calcium carbonates (formed if exchanged cations are insufficiently removed) may result in inferior performance of the bentonite in geosynthetic liners.
Illitisation of smectite clays by potassium ions and K-bentonite rock
Illite
Illite is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina ...
is the main clay constituent of potash bentonite (a rock type also known as K-bentonite or potassium bentonite). K-bentonite is a term reserved to volcanic stratigraphy and tephrochronology and is related to the weathered clay rock type only. Illite, the clay mineral, is a potassium
Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosphe ...
-rich phylosilicate formed from the alteration of smectic clay in contact with groundwater rich in ions. Illite is a high-charge ''TOT'' clay mineral, in which sheets are bound relatively strongly by more numerous potassium ions, and so it is no longer a swelling clay and has few industrial uses. In contrast to the highly hydrated ions which act as "swellers" or "expanders" ions, poorly hydrated ions behave as "collapsers" when exchanging with ions accessible in the interlayers space present between two ''TOT'' layers. Dehydrated ions are preferentially located in between two face-to-face hexagonal cavities formed by six joined silica tetrahedra present at the surface of the basal plane of a ''TOT'' layer (see the corresponding figure showing an elementary ''TOT'' layer). Because dehydrated, these ions are sometimes said to form inner-sphere bonds with the surrounding oxygen atoms present in the hexagonal cavity hosting them. It means there is no water molecule in between the ion and the oxygen atoms attached to the silica tetrahedra (T).
Uses
The main uses of bentonite are in drilling mud
In geotechnical engineering, drilling fluid, also called drilling mud, is used to aid the drilling of boreholes into the earth. Often used while drilling oil and natural gas wells and on exploration drilling rigs, drilling fluids are also us ...
and as a binder, purifier, absorbent, and carrier for fertilizer
A fertilizer (American English) or fertiliser (British English; see spelling differences) is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from ...
s or pesticide
Pesticides are substances that are meant to control pests. This includes herbicide, insecticide, nematicide, molluscicide, piscicide, avicide, rodenticide, bactericide, insect repellent, animal repellent, microbicide, fungicide, and lampri ...
s. As of around 1990, almost half of the US production of bentonite was used as drilling mud. Minor uses include filler, sealant
Sealant is a substance used to block the passage of fluids through openings in materials, a type of mechanical seal. In building construction ''sealant'' is sometimes synonymous with ''caulking'' and also serve the purposes of blocking dust, s ...
, and catalyst
Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...
in petroleum refining
An oil refinery or petroleum refinery is an industrial processes, industrial process Factory, plant where petroleum (crude oil) is transformed and refining, refined into useful products such as gasoline (petrol), diesel fuel, asphalt, asphalt ...
. Calcium bentonite is sometimes marketed as fuller's earth
Fuller's earth is any clay material that has the capability to decolorize oil or other liquids without the use of harsh chemical treatment. Fuller's earth typically consists of palygorskite (attapulgite) or bentonite.
Modern uses of fuller's ea ...
, whose uses overlap with those of other forms of bentonite.
Drilling mud
Bentonite is used in drilling mud
In geotechnical engineering, drilling fluid, also called drilling mud, is used to aid the drilling of boreholes into the earth. Often used while drilling oil and natural gas wells and on exploration drilling rigs, drilling fluids are also us ...
to lubricate
Lubrication is the process or technique of using a lubricant to reduce friction and wear and tear in a contact between two surfaces. The study of lubrication is a discipline in the field of tribology.
Lubrication mechanisms such as fluid-lubrica ...
and cool
Cool commonly refers to:
* Cool, a moderately low temperature
* Cool (aesthetic), an aesthetic of attitude, behavior, and style
Cool or COOL may also refer to:
Economics
* Country of origin labelling
* mCOOL - US consumer legislation to enforc ...
the cutting tools (drill bit
Drill bits are cutting tools used in a drill to remove material to create holes, almost always of circular cross-section. Drill bits come in many sizes and shapes and can create different kinds of holes in many different materials. In order ...
), to remove cuttings, to stabilize the borehole
A borehole is a narrow shaft bored in the ground, either vertically or horizontally. A borehole may be constructed for many different purposes, including the extraction of water ( drilled water well and tube well), other liquids (such as petro ...
walls, and to help prevent blowout
Blowout or Blow out may refer to:
Film and television
*''Blow Out'', a 1981 film by Brian De Palma
* ''The Blow Out'', a 1936 short film
* ''Blow Out'' (TV series), a TV series on Bravo
* "Blow Out" (''Prison Break''), an episode of ''Prison ...
s (by maintaining a sufficient hydraulic pressure
Hydraulics (from Greek: Υδραυλική) is a technology and applied science using engineering, chemistry, and other sciences involving the mechanical properties and use of liquids. At a very basic level, hydraulics is the liquid coun ...
in the well). Bentonite also curtails drilling fluid invasion by its propensity for aiding in the formation of mud cake. Much of bentonite's usefulness in the drilling and geotechnical engineering
Geotechnical engineering is the branch of civil engineering concerned with the engineering behavior of earth materials. It uses the principles of soil mechanics and rock mechanics for the solution of its respective engineering problems. It als ...
industry comes from its unique rheological
Rheology (; ) is the study of the flow of matter, primarily in a fluid (liquid or gas) state, but also as "soft solids" or solids under conditions in which they respond with plastic flow rather than deforming elastically in response to an applie ...
properties. Relatively small quantities of bentonite suspended in water form a viscous
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water.
Viscosity quantifies the inter ...
, shear-thinning material. Most often, bentonite suspensions are also thixotropic
Thixotropy is a time-dependent shear thinning property. Certain gels or fluids that are thick or viscous under static conditions will flow (become thinner, less viscous) over time when shaken, agitated, shear-stressed, or otherwise stressed (ti ...
, although rare cases of rheopectic
In continuum mechanics, rheopecty or rheopexy is the rare property of some non-Newtonian fluids to show a time-dependent increase in viscosity ( time-dependent viscosity); the longer the fluid undergoes shearing force, the higher its viscosity. ...
behavior have also been reported. At high enough concentrations (about 60 grams of bentonite per litre of suspension
Suspension or suspended may refer to:
Science and engineering
* Suspension (topology), in mathematics
* Suspension (dynamical systems), in mathematics
* Suspension of a ring, in mathematics
* Suspension (chemistry), small solid particles suspend ...
, ~6wt.%), bentonite suspensions begin to take on the characteristics of a gel
A gel is a semi-solid that can have properties ranging from soft and weak to hard and tough. Gels are defined as a substantially dilute cross-linked system, which exhibits no flow when in the steady-state, although the liquid phase may still di ...
(a fluid with a minimum yield strength
In materials science and engineering, the yield point is the point on a stress-strain curve that indicates the limit of elastic behavior and the beginning of plastic behavior. Below the yield point, a material will deform elastically and wi ...
required to make it move).
Binder
Bentonite has been widely used as a foundry-sand bond in iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
and steel
Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant ty ...
foundries
A foundry is a factory that produces metal castings. Metals are cast into shapes by melting them into a liquid, pouring the metal into a mold, and removing the mold material after the metal has solidified as it cools. The most common metals pr ...
. Sodium bentonite is most commonly used for large castings that use dry molds, while calcium bentonite is more commonly used for smaller castings that use "green" or wet molds. Bentonite is also used as a binding agent in the manufacture of iron ore
Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the fo ...
(taconite
Taconite () is a variety of iron formation, an iron-bearing (over 15% iron) sedimentary rock, in which the iron minerals are interlayered with quartz, chert, or carbonate. The name "taconyte" was coined by Horace Vaughn Winchell (1865–1923) ...
) pellets as used in the steelmaking industry. Bentonite, in small percentages, is used as an ingredient in commercial and homemade clay bodies and ceramic glazes. It greatly increases the plasticity
Plasticity may refer to:
Science
* Plasticity (physics), in engineering and physics, the propensity of a solid material to undergo permanent deformation under load
* Neuroplasticity, in neuroscience, how entire brain structures, and the brain it ...
of clay bodies and decreases settling in glazes, making both easier to work with for most applications.
The ionic surface of bentonite has a useful property in making a sticky coating on sand grains. When a small proportion of finely ground bentonite clay is added to hard sand and wetted, the clay binds the sand particles into a moldable aggregate known as green sand used for making molds in sand casting
Sand casting, also known as sand molded casting, is a metal casting process characterized by using sand as the mold material. The term "sand casting" can also refer to an object produced via the sand casting process. Sand castings are produced i ...
.
Purification
Bentonites are used for decolorizing various mineral, vegetable, and animal oils. They are also used for clarifying wine, liquor, cider, beer, mead, and vinegar.
Bentonite has the property of adsorbing relatively large amounts of protein
Proteins are large biomolecules and macromolecules that comprise one or more long chains of amino acid residues. Proteins perform a vast array of functions within organisms, including catalysing metabolic reactions, DNA replication, respo ...
molecules from aqueous solutions. Consequently, bentonite is uniquely useful in the process of winemaking
Winemaking or vinification is the production of wine, starting with the selection of the fruit, its fermentation into alcohol, and the bottling of the finished liquid. The history of wine-making stretches over millennia. The science of wine and ...
, where it is used to remove excessive amounts of protein
Proteins are large biomolecules and macromolecules that comprise one or more long chains of amino acid residues. Proteins perform a vast array of functions within organisms, including catalysing metabolic reactions, DNA replication, respo ...
from white wine
White wine is a wine that is Fermentation in winemaking, fermented without skin contact. The wine color, colour can be straw-yellow, yellow-green, or yellow-gold. It is produced by the alcoholic fermentation of the non-coloured Juice vesicles, ...
s. Were it not for this use of bentonite, many or most white wines would precipitate undesirable flocculent
Flocculation, in the field of chemistry, is a process by which colloidal particles come out of suspension to sediment under the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The action differs from pre ...
clouds or hazes upon exposure to warm temperatures, as these proteins denature. It also has the incidental use of inducing more rapid clarification of both red and white wines.
Bentonite is also considered an effective low-cost adsorbent for the removal of chromium(VI)
Hexavalent chromium (chromium(VI), Cr(VI), chromium 6) is chromium in any chemical compound that contains the element in the +6 oxidation state (thus hexavalent). Virtually all chromium ore is processed via hexavalent chromium, specifically the ...
ions from aqueous solutions (contaminated wastewater).
Absorbent
Bentonite is used in a variety of pet care items such as cat litter
A litter box, also known as a sandbox, cat box, litter tray, cat pan, potty, pot or litter pan, is an indoor feces and urine collection box for cats, as well as rabbits, ferrets, miniature pigs, small dogs, and other pets that instinctively or ...
to absorb pet waste. It is also used to absorb oils and grease.
Carrier
Bentonite is used as an inert carrier for pesticide
Pesticides are substances that are meant to control pests. This includes herbicide, insecticide, nematicide, molluscicide, piscicide, avicide, rodenticide, bactericide, insect repellent, animal repellent, microbicide, fungicide, and lampri ...
s, fertilizer
A fertilizer (American English) or fertiliser (British English; see spelling differences) is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from ...
s, and fire retardant
A fire retardant is a substance that is used to slow down or stop the spread of fire or reduce its intensity. This is commonly accomplished by chemical reactions that reduce the flammability of fuels or delay their combustion. Fire retardants m ...
s. It helps ensure that the active agent is uniformly dispersed and that pesticides and fertilizers are retained on the plants.
Filler
Bentonite is used as a filler in a wide variety of products, including adhesive
Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation.
The use of adhesives offers certain advant ...
s, cosmetics
Cosmetics are constituted mixtures of chemical compounds derived from either natural sources, or synthetically created ones. Cosmetics have various purposes. Those designed for personal care and skin care can be used to cleanse or protect ...
, paint
Paint is any pigmented liquid, liquefiable, or solid mastic composition that, after application to a substrate in a thin layer, converts to a solid film. It is most commonly used to protect, color, or provide texture. Paint can be made in many ...
, rubber
Rubber, also called India rubber, latex, Amazonian rubber, ''caucho'', or ''caoutchouc'', as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds. Thailand, Malaysia, and ...
, and soap
Soap is a salt of a fatty acid used in a variety of cleansing and lubricating products. In a domestic setting, soaps are surfactants usually used for washing, bathing, and other types of housekeeping. In industrial settings, soaps are use ...
s. It also acts as a stabilizer and extender in these products.
Sealant
The property of swelling on contact with water makes sodium bentonite useful as a sealant since it provides a self-sealing, low- permeability barrier. It is used to line the base of landfills
A landfill site, also known as a tip, dump, rubbish dump, garbage dump, or dumping ground, is a site for the disposal of waste materials. Landfill is the oldest and most common form of waste disposal, although the systematic burial of the waste ...
to prevent migration of leachate
A leachate is any liquid that, in the course of passing through matter, extracts soluble or suspended solids, or any other component of the material through which it has passed.
Leachate is a widely used term in the environmental sciences wher ...
, for confining metal pollutants of groundwater
Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit of rock or an unconsolidate ...
, and for the sealing of subsurface disposal systems for spent nuclear fuel
Spent nuclear fuel, occasionally called used nuclear fuel, is nuclear fuel that has been irradiated in a nuclear reactor (usually at a nuclear power plant). It is no longer useful in sustaining a nuclear reaction in an ordinary thermal reactor an ...
. Similar uses include making slurry wall
A slurry wall is a civil engineering technique used to build reinforced concrete walls in areas of soft earth close to open water, or with a high groundwater table.
This technique is typically used to build diaphragm (water-blocking) walls surro ...
s, waterproofing of below-grade walls, and forming other impermeable barriers, e.g., to seal off the annulus
Annulus (or anulus) or annular indicates a ring- or donut-shaped area or structure. It may refer to:
Human anatomy
* ''Anulus fibrosus disci intervertebralis'', spinal structure
* Annulus of Zinn, a.k.a. annular tendon or ''anulus tendineus com ...
of a water well
A well is an excavation or structure created in the ground by digging, driving, or drilling to access liquid resources, usually water. The oldest and most common kind of well is a water well, to access groundwater in underground aquifers. Th ...
, to plug old wells.
Bentonite can also be "sandwiched" between synthetic materials to create geosynthetic clay liner
Different types of fabric used for geosynthetic clay liners.
Geosynthetic clay liners (GCLs) are factory manufactured hydraulic barriers consisting of a layer of bentonite or other very low-permeability material supported bgeotextilesand/or geom ...
s (GCLs) for the aforementioned purposes. This technique allows for more convenient transport and installation, and it greatly reduces the volume of bentonite required. It is also used to form a barrier around newly planted trees to constrain root growth so as to prevent damage to nearby pipes, footpaths, and other infrastructure. Farmers use bentonite to seal retention ponds and line canals.
Catalyst
High-purity calcium bentonite is treated with acid for use as a catalyst in cracking heavy petroleum
Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...
fractions.
Medicine
Bentonite has been prescribed as a bulk laxative
Laxatives, purgatives, or aperients are substances that loosen stools and increase bowel movements. They are used to treat and prevent constipation.
Laxatives vary as to how they work and the side effects they may have. Certain stimulant, lubri ...
, and it is also used as a base for many dermatologic formulas. Granular bentonite is being studied for use in battlefield wound dressings. Bentonite is also sold online and in retail outlets for a variety of indications.
Bentoquatam is a bentonate-based topical medication intended to act as a shield against exposure to urushiol
Urushiol is an oily mixture of organic compounds with allergenic properties found in plants of the family Anacardiaceae, especially ''Toxicodendron'' ''spp.'' (e.g., poison oak, Chinese lacquer tree, poison ivy, poison sumac), ''Comocladia sp ...
, the oil found in plants such as poison ivy or poison oak Poison oak refers to two plant species in the genus ''Toxicodendron,'' both of which can cause skin irritation:
*''Toxicodendron diversilobum'' or Western poison oak, found in western North America
*''Toxicodendron pubescens
''Toxicodendron pub ...
.
Bentonite can also be used as a desiccant
A desiccant is a hygroscopic substance that is used to induce or sustain a state of dryness (desiccation) in its vicinity; it is the opposite of a humectant. Commonly encountered pre-packaged desiccants are solids that absorb water. Desiccant ...
due to its adsorption properties. Bentonite desiccants have been successfully used to protect pharmaceutical, nutraceutical, and diagnostic products from moisture degradation and extend shelf life
Shelf life is the length of time that a commodity may be stored without becoming unfit for use, consumption, or sale. In other words, it might refer to whether a commodity should no longer be on a pantry shelf (unfit for use), or no longer on a ...
. In most common package environments, bentonite desiccants offer a higher water adsorption capacity than silica gel
Silica gel is an amorphous and porous form of silicon dioxide (silica), consisting of an irregular tridimensional framework of alternating silicon and oxygen atoms with nanometer-scale voids and pores. The voids may contain water or some other l ...
desiccants. Bentonite complies with the FDA
The United States Food and Drug Administration (FDA or US FDA) is a federal agency of the Department of Health and Human Services. The FDA is responsible for protecting and promoting public health through the control and supervision of food s ...
for contact with food and drugs.
Farming in Thailand
The application of clay technology by farmers in northeast Thailand, using bentonite clay, has dramatically reversed soil degradation
Soil retrogression and degradation are two regressive evolution processes associated with the loss of equilibrium of a stable soil. Retrogression is primarily due to soil erosion and corresponds to a phenomenon where succession reverts the land t ...
and resulted in greater economic returns, with higher yields and higher output prices. Studies carried out by The International Water Management Institute
The International Water Management Institute (IWMI) is a non-profit international water management research organisation under the CGIAR with its headquarters in Colombo, Sri Lanka, and offices across Africa and Asia. Research at the Institute foc ...
and partners in 2002–2003 focused on the application of locally sourced bentonite clays to degraded soils in the region. These applications were carried out in structured field trials. Applying bentonite clays effectively improved yields of forage sorghum
''Sorghum'' () is a genus of about 25 species of flowering plants in the grass family (Poaceae). Some of these species are grown as cereals for human consumption and some in pastures for animals. One species is grown for grain, while many othe ...
grown under rain-fed conditions.
Bentonite application also influenced the prices that farmers received for their crops. Production costs are higher, but due to higher production and the quality of the food, clay farmers could afford to invest and grow more and better food, compared to nonclay-using farmers.
Bentonite slurry walls in modern construction
Bentonite slurry wall
A slurry wall is a civil engineering technique used to build reinforced concrete walls in areas of soft earth close to open water, or with a high groundwater table.
This technique is typically used to build diaphragm (water-blocking) walls surro ...
s (also known as diaphragm walls
) are used in construction, where the slurry wall is a trench filled with a thick colloidal
A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others extend ...
mixture of bentonite and water.[
]
A trench that would collapse due to the hydraulic pressure in the surrounding soil does not collapse as the slurry balances the hydraulic pressure. Forms for concrete, and rebar, can be assembled in a slurry-filled trench, and then have concrete poured into the form. The liquid concrete being denser displaces the less-dense bentonite slurry and causes the latter to overflow from the trench. This displaced bentonite slurry is then channeled to a recycling unit from which it can subsequently be reused in a new trench elsewhere on the construction site.
In addition, because the colloid is relatively impervious to water, a slurry wall can prevent the seepage of groundwater, which is useful in preventing the further spread of groundwater that has been contaminated by toxic material such as industrial waste.[
]
Pottery
The clay from which pottery is made is described as "plastic
Plastics are a wide range of synthetic or semi-synthetic materials that use polymers as a main ingredient. Their plasticity makes it possible for plastics to be moulded, extruded or pressed into solid objects of various shapes. This adaptab ...
" if it can be stretched without cracking, or "short" or non-plastic if it tends to break up when formed. A small amount of bentonite is often added to make a clay mixture more plastic. This makes the clay more easily formed, by methods such as throwing on a potter's wheel
In pottery, a potter's wheel is a machine used in the shaping (known as throwing) of clay into round ceramic ware. The wheel may also be used during the process of trimming excess clay from leather-hard dried ware that is stiff but malleable, a ...
and various hand-building techniques. Short clay, such as a porcelain
Porcelain () is a ceramic material made by heating substances, generally including materials such as kaolinite, in a kiln to temperatures between . The strength and translucence of porcelain, relative to other types of pottery, arises mainl ...
mixture consisting only of kaolinite
Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
and feldspar
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldsp ...
, can be formed only by a limited set of methods such as pressing and molding, that do not put the clay under tension. However, bentonite typically contains minerals that affect the color of the mix, and its swelling absorbent properties can make such a mix prone to significant shrinkage and potential cracking as it dries.
Ceramic glaze
Ceramic glaze is an impervious layer or coating of a vitreous substance which has been fused to a pottery body through firing. Glaze can serve to color, decorate or waterproof an item. Glazing renders earthenware vessels suitable for holding ...
s often contain bentonite. The bentonite is added to slow or prevent the settling of the glazes. It can also improve the consistency of application of glazes on porous biscuit-fired ware. Once a certain amount of glaze water has been absorbed by the biscuit the bentonite effectively clogs the pores and resists the absorption of further water resulting in a more evenly thick coat.
Emergency use
Bentonite is used in industry and emergency response as a chemical absorbent and container sealant.
History and natural occurrence
In 2018, China was the top producer of bentonite, with almost a one-quarter share of the world's production, followed by the United States and India. Total worldwide production was 24,400,000 metric tons of bentonite and 3,400,000 metric tons of fuller's earth.[T. Brown et al. 2013. ]
World Mineral Production 2007–11
'. British Geological Survey, Nottingham, England.
Most high-grade natural sodium bentonite is produced from the western United States in an area between the Black Hills
The Black Hills ( lkt, Ȟe Sápa; chy, Moʼȯhta-voʼhonáaeva; hid, awaxaawi shiibisha) is an isolated mountain range rising from the Great Plains of North America in western South Dakota and extending into Wyoming, United States. Black Elk P ...
of South Dakota
South Dakota (; Sioux language, Sioux: , ) is a U.S. state in the West North Central states, North Central region of the United States. It is also part of the Great Plains. South Dakota is named after the Lakota people, Lakota and Dakota peo ...
and the Bighorn Basin
The Bighorn Basin is a plateau region and intermontane basin, approximately 100 miles (160 km) wide, in north-central Wyoming in the United States. It is bounded by the Absaroka Range on the west, the Pryor Mountains on the north, the Bighor ...
of Wyoming, and the Tokat Resadiye region of Turkey. Mixed sodium/calcium bentonite is mined in Greece
Greece,, or , romanized: ', officially the Hellenic Republic, is a country in Southeast Europe. It is situated on the southern tip of the Balkans, and is located at the crossroads of Europe, Asia, and Africa. Greece shares land borders with ...
, Australia
Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
, India
India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...
, Russia
Russia (, , ), or the Russian Federation, is a List of transcontinental countries, transcontinental country spanning Eastern Europe and North Asia, Northern Asia. It is the List of countries and dependencies by area, largest country in the ...
, and Ukraine
Ukraine ( uk, Україна, Ukraïna, ) is a country in Eastern Europe. It is the second-largest European country after Russia, which it borders to the east and northeast. Ukraine covers approximately . Prior to the ongoing Russian inv ...
.
In the United States, calcium bentonite is mined primarily in Mississippi
Mississippi () is a state in the Southeastern region of the United States, bordered to the north by Tennessee; to the east by Alabama; to the south by the Gulf of Mexico; to the southwest by Louisiana; and to the northwest by Arkansas. Miss ...
and Alabama
(We dare defend our rights)
, anthem = "Alabama (state song), Alabama"
, image_map = Alabama in United States.svg
, seat = Montgomery, Alabama, Montgomery
, LargestCity = Huntsville, Alabama, Huntsville
, LargestCounty = Baldwin County, Al ...
. Other major locations producing calcium bentonite include New Zealand, Germany, Greece, Turkey, India, and China.
See also
*
References
External links
*
{{Authority control
Aluminium minerals
Calcium minerals
Sodium minerals
Industrial minerals
Medicinal clay
Phyllosilicates