Babefphite
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Babefphite is a rare
phosphate mineral Phosphate minerals contain the tetrahedrally coordinated phosphate (PO43−) anion along sometimes with arsenate (AsO43−) and vanadate (VO43−) substitutions, and chloride (Cl−), fluoride (F−), and hydroxide (OH−) anions that also fit i ...
with the general formula BaBe(PO4)(F,OH). The name is given for its composition (Ba meaning
barium Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...
, Be meaning
beryllium Beryllium is a chemical element with the symbol Be and atomic number 4. It is a steel-gray, strong, lightweight and brittle alkaline earth metal. It is a divalent element that occurs naturally only in combination with other elements to form mi ...
, F meaning
fluorine Fluorine is a chemical element with the symbol F and atomic number 9. It is the lightest halogen and exists at standard conditions as a highly toxic, pale yellow diatomic gas. As the most electronegative reactive element, it is extremely reacti ...
, and P for
phosphorus Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ear ...
).


Crystallography

Babefphite is
tetragonal In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the cube becomes a rectangular prism with a square ...
, which means crystallographically, it contains two horizontal and interchangeable equal axes (a1 and 2) and a longitudinal axis (c). It belongs to the 4/m 2/m 2/m point group; meaning it has four horizontal axes of twofold
symmetry Symmetry (from grc, συμμετρία "agreement in dimensions, due proportion, arrangement") in everyday language refers to a sense of harmonious and beautiful proportion and balance. In mathematics, "symmetry" has a more precise definit ...
, two of which coincide with the crystallographic axes (a1) and (a2) and the remaining two at 45° to the (a1) and (a2).Wintringham, J.P. (1917) An Elementary Introduction to Crystallography. American Mineralogist, 2, 109-110.


Optical properties

Babefphite is an
anisotropic Anisotropy () is the property of a material which allows it to change or assume different properties in different directions, as opposed to isotropy. It can be defined as a difference, when measured along different axes, in a material's physic ...
mineral meaning that the velocity of light passing through it will vary depending on the direction of travel. When measured against Canada Balsam it will display moderate positive relief. Relief is an optical property that relates the index of refraction of a mineral versus the index of refraction of another material. Positive relief denotes light being bent toward the mineral. Negative relief means the light is bent toward the mounting material. In the case of optical mineralogy, this other material is most often whatever material is used to mount the mineral in question in thin section. Based on the white color of babefphite in hand sample it is likely that it appears clear in thin section under plane polarized light. Due to its anisotropic nature, it has the possibility of displaying very weak pleochroism under the same conditions.
Pleochroism Pleochroism (from Greek πλέων, ''pléōn'', "more" and χρῶμα, ''khrôma'', "color") is an optical phenomenon in which a substance has different colors when observed at different angles, especially with polarized light. Backgroun ...
is defined as a change of color, on rotation, of plane light. It occurs when the extraordinary and ordinary rays of light are absorbed differently, thereby displaying different colors. The wider the difference in the rays the more dramatic the color change. Babefphite is also weakly birefringent.
Birefringence Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent (or birefractive). The birefring ...
is an optical property that is determined by the direction that light passes through a mineral.Neese, C., and Dutrow, B. (2007) 3rd edition Optical Mineralogy, 370p. Oxford University Press, Oxford, England


Occurrence

Babefphite was first described in 1966 for an occurrence at the Aunik fluorite-rare metals deposit,
Buryatia Buryatia, officially the Republic of Buryatia (russian: Республика Бурятия, r=Respublika Buryatiya, p=rʲɪsˈpublʲɪkə bʊˈrʲætʲɪjə; bua, Буряад Улас, Buryaad Ulas, , mn, Буриад Улс, Buriad Uls), is ...
, Eastern-Siberian Region, Russia. It has also been reported from the Rožná pegmatite in the Vysočina Region,
Moravia Moravia ( , also , ; cs, Morava ; german: link=yes, Mähren ; pl, Morawy ; szl, Morawa; la, Moravia) is a historical region in the east of the Czech Republic and one of three historical Czech lands, with Bohemia and Czech Silesia. The me ...
,
Czech Republic The Czech Republic, or simply Czechia, is a landlocked country in Central Europe. Historically known as Bohemia, it is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the southeast. The ...
. In the Siberian occurrence it occurs in residual material above
rare-earth metal The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides (yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous silve ...
bearing
skarn Skarns or tactites are hard, coarse-grained metamorphic rocks that form by a process called metasomatism. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals ...
s associated with alkaline intrusive bodies. It occurs with
zircon Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of the r ...
, ilmenorutile,
fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs sca ...
,
phenakite Phenakite or phenacite is a fairly rare nesosilicate mineral consisting of beryllium orthosilicate, Be2 Si O4. Occasionally used as a gemstone, phenakite occurs as isolated crystals, which are rhombohedral with parallel-faced hemihedrism, and are ...
,
scheelite Scheelite is a calcium tungstate mineral with the chemical formula Ca W O4. It is an important ore of tungsten (wolfram). Scheelite is originally named after Swedish chemist K. Scheele (1742-1786). Well-formed crystals are sought by collectors a ...
,
bertrandite Bertrandite is a beryllium sorosilicate hydroxide mineral with composition: Be4Si2O7(OH)2. Bertrandite is a colorless to pale yellow orthorhombic mineral with a hardness of 6-7. It is commonly found in beryllium rich pegmatites and is in part an ...
,
albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate. I ...
,
microcline Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. Microcline typically contains minor amounts of sodium. It is common in granite and pegmatites. Microcline forms during slow ...
and
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
.


References

{{reflist Barium minerals Beryllium minerals Phosphate minerals Triclinic minerals Minerals in space group 1 Minerals described in 1966