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Arsenopyrite ( IMA
Arsenopyrite crystallizes in the
Various transition group metals can substitute for iron in arsenopyrite. The arsenopyrite group includes the following rare minerals:
* Clinosafflorite:
* Gudmundite:
*
symbol
A symbol is a mark, sign, or word that indicates, signifies, or is understood as representing an idea, object, or relationship. Symbols allow people to go beyond what is known or seen by creating linkages between otherwise very different conc ...
: Apy) is an iron arsenic sulfide (FeAsS). It is a hard ( Mohs 5.5-6) metallic, opaque, steel grey to silver white mineral with a relatively high specific gravity
Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...
of 6.1. When dissolved in nitric acid
Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available nitri ...
, it releases elemental sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
. When arsenopyrite is heated, it produces sulfur and arsenic vapor. With 46% arsenic
Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, but ...
content, arsenopyrite, along with orpiment
Orpiment is a deep-colored, orange-yellow arsenic sulfide mineral with formula . It is found in volcanic fumaroles, low-temperature hydrothermal veins, and hot springs and is formed both by sublimation and as a byproduct of the decay of anothe ...
, is a principal ore
Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...
of arsenic. When deposits of arsenopyrite become exposed to the atmosphere, the mineral slowly converts into iron arsenates. Arsenopyrite is generally an acid-consuming sulfide mineral, unlike iron pyrite
The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Pyrite's metallic luster and pale brass-yellow hue giv ...
which can lead to acid mine drainage
Acid mine drainage, acid and metalliferous drainage (AMD), or acid rock drainage (ARD) is the outflow of acidic water from metal mines or coal mines.
Acid rock drainage occurs naturally within some environments as part of the rock weathering ...
.
The crystal habit, hardness, density, and garlic odour when struck are diagnostic. Arsenopyrite in older literature may be referred to as ''mispickel'', a name of German origin.
Arsenopyrite also can be associated with significant amounts of gold
Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile met ...
. Consequently, it serves as an indicator of gold bearing reefs. Many arsenopyrite gold ores are refractory
In materials science, a refractory material or refractory is a material that is resistant to decomposition by heat, pressure, or chemical attack, and retains strength and form at high temperatures. Refractories are polycrystalline, polyphase, ...
, i.e. the gold is not easily cyanide leached from the mineral matrix.
Arsenopyrite is found in high temperature hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
veins, in pegmatite
A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...
s, and in areas of contact metamorphism
Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of ch ...
or metasomatism
Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is the replacement of one rock by another of different mineralogical and chemical co ...
.
Crystallography
Arsenopyrite crystallizes in the monoclinic
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic s ...
crystal system
In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices. Space groups are classified into crystal systems according to their po ...
and often shows prismatic crystal or columnar forms with striation
Striations means a series of ridges, furrows or linear marks, and is used in several ways:
* Glacial striation
* Striation (fatigue), in material
* Striation (geology), a ''striation'' as a result of a geological fault
* Striation Valley, in Ant ...
s and twinning common. Arsenopyrite may be referred to in older references as orthorhombic, but it has been shown to be monoclinic. In terms of its atomic structure, each Fe center is linked to three As atoms and three S atoms. The material can be described as Fe3+ with the diatomic trianion AsS3−. The connectivity of the atoms is more similar to that in marcasite
The mineral marcasite, sometimes called “white iron pyrite”, is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both ...
than pyrite
The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Pyrite's metallic Luster (mineralogy), lust ...
. The ion description is imperfect because the material is semiconducting and the Fe-As and Fe-S bonds are highly covalent
A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atoms ...
.Vaugn, D. J.; Craig, J. R. Mineral Chemistry of Metal Sulfides" Cambridge University Press, Cambridge: 1978. .
Related minerals
Various transition group metals can substitute for iron in arsenopyrite. The arsenopyrite group includes the following rare minerals:
* Clinosafflorite:
* Gudmundite:
*Glaucodot
Glaucodot is a cobalt iron arsenic sulfide mineral with formula . The cobalt:iron(II) ratio is typically 3:1 with minor nickel substituting. It forms a series with arsenopyrite . It is an opaque grey to tin-white typically found as massive forms ...
or alloclasite Alloclasite () is a sulfosalt mineral ( IMA symbol: Acl). It is a member of the arsenopyrite group. Alloclasite crystallizes in the monoclinic system and typically forms as columnar to radiating acicular prismatic clusters. It is an opaque steel-g ...
: or
* Iridarsenite:
* Osarsite or ruarsite: or
See also
* *Classification of minerals The classification of minerals is a process of determining to which of several groups minerals belong based on their chemical characteristics. Since the 1950s, this classification has been carried out by the International Mineralogical Association, ...
* List of minerals
This is a list of minerals for which there are articles on Wikipedia.
Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a m ...
References
External links
* {{Authority control Iron minerals Sulfide minerals Arsenic minerals Monoclinic minerals Minerals in space group 14