Annealing is a process of slowly cooling hot glass objects after they have been formed, to relieve residual internal stresses introduced during manufacture. Especially for smaller, simpler objects, annealing may be incidental to the process of manufacture, but in larger or more complex products it commonly demands a special process of annealing in a temperature-controlled kiln known as a lehr.E. F. Collins (1921) Electrically heated glass annealing lehr. Journal of the American Ceramic Society 4 (5), pp. 335–349 Annealing of glass is critical to its durability. Glass that has not been properly annealed retains thermal stresses caused by

quenching In materials science, quenching is the rapid cooling of a workpiece in water, oil, polymer, air, or other fluids to obtain certain material properties. A type of heat treating, quenching prevents undesired low-temperature processes, such as ...

, which will indefinitely decrease the strength and reliability of the product. Inadequately annealed glass is likely to crack or shatter when subjected to relatively small temperature changes or to mechanical shock or stress. It even may fail spontaneously. To anneal glass, it is necessary to heat it to its annealing

temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied o ...

, at which its

viscosity The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the int ...

, η, drops to 10¹³ Poise (10¹³ dyne-second/cm²). For most kinds of glass, this annealing temperature is in the range of 454–482 °C (850–900 °F), and is the so-called stress-relief point or annealing point of the glass. At such a viscosity, the glass is still too hard for significant external deformation without breaking, but it is soft enough to relax internal strains by microscopic flow in response to the intense stresses they introduce internally. The piece then heat-soaks until its temperature is even throughout and the stress relaxation is adequate. The time necessary for this step varies depending on the type of glass and its maximum thickness. The glass then is permitted to cool at a predetermined rate until its temperature passes the strain point (η = 10^14.5 Poise), below which even microscopic internal flow effectively stops and annealing stops with it. It then is safe to cool the product to

room temperature Colloquially, "room temperature" is a range of air temperatures that most people prefer for indoor settings. It feels comfortable to a person when they are wearing typical indoor clothing. Human comfort can extend beyond this range depending on ...

at a rate limited by the

heat capacity Heat capacity or thermal capacity is a physical property of matter, defined as the amount of heat to be supplied to an object to produce a unit change in its temperature. The SI unit of heat capacity is joule per kelvin (J/K). Heat cap ...

, thickness,

thermal conductivity The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...

, and

thermal expansion coefficient Thermal expansion is the tendency of matter to change its shape, area, volume, and density in response to a change in temperature, usually not including phase transitions. Temperature is a monotonic function of the average molecular kinetic ...

of the glass. After annealing is complete the material can be cut to size, drilled, or polished without risk of its internal stresses shattering it. At the ''annealing point'' (η = 10¹³ Poise), stresses relax within several minutes, while at the ''strain point'' (η = 10^14.5 Poise) stresses relax within several hours.Werner Vogel: "Glass Chemistry"; Springer-Verlag Berlin and Heidelberg GmbH & Co. K; 2nd revised edition (November 1994), Stresses acquired at temperatures above the strain point, and not relaxed by annealing, remain in the glass indefinitely and may cause either short-term or much delayed failure. Stresses resulting from cooling too rapidly below the strain point largely are considered temporary, although they may be sufficient to cause short-term failure.

References

{{Glass science Glass engineering and science Glass production Warm glass Firing techniques

See also

References