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An asphalt volcano is a rare type of
submarine volcano Submarine volcanoes are underwater vents or fissures in the Earth's surface from which magma can erupt. Many submarine volcanoes are located near areas of tectonic plate formation, known as mid-ocean ridges. The volcanoes at mid-ocean ridges ...
(
seamount A seamount is a large geologic landform that rises from the ocean floor that does not reach to the water's surface (sea level), and thus is not an island, islet or cliff-rock. Seamounts are typically formed from extinct volcanoes that rise abru ...
) first discovered in 2003. Several examples have been found: first, along the coasts of the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territorie ...
and
Mexico Mexico (Spanish: México), officially the United Mexican States, is a country in the southern portion of North America. It is bordered to the north by the United States; to the south and west by the Pacific Ocean; to the southeast by Guatema ...
, and then in other regions of the world; a few are still active. Resembling seamounts in structure, they are made entirely of
asphalt Asphalt, also known as bitumen (, ), is a sticky, black, highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term a ...
, and form when natural oil seeps up from the Earth's crust underwater.


Formation and distribution

Asphalt volcanoes are ocean floor vents that erupt asphalt instead of lava. They were discovered in the
Gulf of Mexico The Gulf of Mexico ( es, Golfo de México) is an oceanic basin, ocean basin and a marginal sea of the Atlantic Ocean, largely surrounded by the North American continent. It is bounded on the northeast, north and northwest by the Gulf Coast of ...
during an expedition of the research vessel SONNE, led by Gerhard Bohrmann of the DFG Research Center Ocean Margins. On these volcanoes a previously unknown highly diverse ecosystem at a water depth of 3,000 meters was discovered.Asphalt volcanoes discovered
Press Release 13. University of Bremen center for marine environmental sciences. May, 2004. Retrieved 5 July 2010.
The first asphalt volcanoes were discovered in 2003 by a research expedition to the
Gulf of Mexico The Gulf of Mexico ( es, Golfo de México) is an oceanic basin, ocean basin and a marginal sea of the Atlantic Ocean, largely surrounded by the North American continent. It is bounded on the northeast, north and northwest by the Gulf Coast of ...
. They are located on a seafloor hill named "Chapopote,"
Nahuatl Nahuatl (; ), Aztec, or Mexicano is a language or, by some definitions, a group of languages of the Uto-Aztecan language family. Varieties of Nahuatl are spoken by about Nahua peoples, most of whom live mainly in Central Mexico and have smaller ...
for "tar." The site is located in a field of
salt dome A salt dome is a type of structural dome formed when salt (or other evaporite minerals) intrudes into overlying rocks in a process known as diapirism. Salt domes can have unique surface and subsurface structures, and they can be discovered using ...
s known as the Campeche Knolls, a series of steep hills formed from salt bodies that rise from underlying rock, a common feature in the gulf. The research team documented tar flows as wide as across. Also discovered alongside the asphalt were areas soaked with
petroleum Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...
and
methane hydrate Methane clathrate (CH4·5.75H2O) or (8CH4·46H2O), also called methane hydrate, hydromethane, methane ice, fire ice, natural gas hydrate, or gas hydrate, is a solid clathrate compound (more specifically, a clathrate hydrate) in which a large amo ...
, also spewed from the volcano. This kind of an environment proves attractive to chemical-loving bacteria and tubeworms, although the exact biogeochemical relationship is not yet known. The tar is relatively hot when it comes out of the seafloor, but just like undersea
lava Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or un ...
flows, it is quickly cooled by the much colder seawater around it. This produces forms similar to the distinctive
A'a Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or un ...
and
pahoehoe Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or und ...
types of
basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
lava flow seen in places like
Hawaii Hawaii ( ; haw, Hawaii or ) is a state in the Western United States, located in the Pacific Ocean about from the U.S. mainland. It is the only U.S. state outside North America, the only state that is an archipelago, and the only stat ...
. Another similarity is that the tar heats methane hydrate and causes it to explode into a free gas, similar to the action hot lava has on
groundwater Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit of rock or an unconsolidate ...
in
phreatomagmatic eruption Phreatomagmatic eruptions are volcanic eruptions resulting from interaction between magma and water. They differ from exclusively magmatic eruptions and phreatic eruptions. Unlike phreatic eruptions, the products of phreatomagmatic eruptions conta ...
s. The team proposed an asphalt volcano formation theory in a paper published in ''
Eos In ancient Greek mythology and religion, Eos (; Ionic and Homeric Greek ''Ēṓs'', Attic ''Héōs'', "dawn", or ; Aeolic ''Aúōs'', Doric ''Āṓs'') is the goddess and personification of the dawn, who rose each morning from her home ...
''. The article suggested that water heated past the critical point underneath the seafloor found a passageway to the surface, most likely a
salt dome A salt dome is a type of structural dome formed when salt (or other evaporite minerals) intrudes into overlying rocks in a process known as diapirism. Salt domes can have unique surface and subsurface structures, and they can be discovered using ...
, and carried with it a heavy load of
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ex ...
s and dissolved minerals. A special property of such critically heated water is that it can mix with oils, whereas normal water cannot. The same process is attributed to the formation of
black smoker A hydrothermal vent is a fissure on the seabed from which geothermally heated water discharges. They are commonly found near volcanically active places, areas where tectonic plates are moving apart at mid-ocean ridges, ocean basins, and hotspot ...
s. Once the water reaches the surface, it cools, and its carrying capacity drops. The lighter compounds in the mixture escape to the surface, while the tar and other heavier materials remain on the seafloor, eventually building up the asphalt volcano's structure. In 2007, seven more such structures were discovered off the coast of
Santa Barbara, California Santa Barbara ( es, Santa Bárbara, meaning "Saint Barbara") is a coastal city in Santa Barbara County, California, of which it is also the county seat. Situated on a south-facing section of coastline, the longest such section on the West Coas ...
. The largest of these domes lies at a depth of . The structures were larger than a football field and about as tall as a six-story building, all made completely out of asphalt. The unusual features were first noted by Ed Keller on bathymetric surveys conducted in the 1990s, and first viewed by a team led by David Valentine in 2007, utilizing ''
DSV Alvin ''Alvin'' (DSV-2) is a crewed deep-ocean research submersible owned by the United States Navy and operated by the Woods Hole Oceanographic Institution (WHOI) in Woods Hole, Massachusetts. The vehicle was built by General Mills' Electronics Grou ...
''. Samples were brought up for testing at the university campus and the
Woods Hole Oceanographic Institution The Woods Hole Oceanographic Institution (WHOI, acronym pronounced ) is a private, nonprofit research and higher education facility dedicated to the study of marine science and engineering. Established in 1930 in Woods Hole, Massachusetts, it i ...
. Two further dives with DSV ''Alvin'' in 2009 and a detailed photographic survey of the area by the autonomous underwater vehicle ''Sentry'' showed many similarities to volcanic flows, including flow texture and cracking of the asphalt layers.
Carbon dating Radiocarbon dating (also referred to as carbon dating or carbon-14 dating) is a method for determining the age of an object containing organic material by using the properties of radiocarbon, a radioactive isotope of carbon. The method was dev ...
puts the structures at between 30 and 40 thousand years old. They had at one time been a prolific source of
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Eart ...
. The two largest structures, less than apart, are pocked by pits and depressions, a sign of methane gas bubbling up long ago. Although the structures are still emitting residual gas, at present the amounts are too small to have any effect. The amount of crude oil in the largest of the structures alone is "enough to fuel my Honda Civic for about half a billion miles. oweverthe quality of the material is very poor...It's not worth something like light sweet crude," said Valentine. The petroleum in the structure is more viscous than that which is usually found in underground wells. This is because it has had less time to "bake" under the Earth's heat before being released. In addition, as much as 20% of its mass is made of "junk"—microscopic organisms, sand, and miscellaneous materials that gradually accumulated in the oil. Analysis of the samples collected from the mounds suggest that they required several decades, even centuries, to build up their current bulk, and that the volcanoes last erupted around 35,000 years ago. In addition they may account for a mysterious spike in oceanic
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Eart ...
concentrations around 35,000 years ago. Methane forms naturally alongside the petroleum underneath the structure, and while petroleum flows have long abated, some residual methane continues to bubble up. This burst of methane would have caused a rapid increase in the population of methane-eating bacteria, which in turn caused a decrease in oxygen in the water, possibly causing a dead zone, in addition to the large amounts of crude oil released into the environment. The presence of these structures provides a hard surface on which life can grow, as the surrounding ocean floor is generally muddy. This is similar to what happens on
seamount A seamount is a large geologic landform that rises from the ocean floor that does not reach to the water's surface (sea level), and thus is not an island, islet or cliff-rock. Seamounts are typically formed from extinct volcanoes that rise abru ...
s, resulting in their place as an ecological "hub."


Onshore "tar volcanoes"

Onshore "tar volcanoes" have also been observed, for instance in
Carpinteria, California Carpinteria (; es, Carpintería, meaning "Carpentry") is a small seaside city in southeastern Santa Barbara County, California. Located on the Central Coast (California), Central Coast of California, it had a population of 13,264 at the 2020 U ...
, in an asphalt mine. Asphalt exuded from joint cracks in the upturned
Monterey shale The Monterey Formation is an extensive Miocene oil-rich geological sedimentary formation in California, with outcrops of the formation in parts of the California Coast Ranges, Peninsular Ranges, and on some of California's off-shore island ...
forming the floor of the mine.Plate 3-A in U.S. Geological Survey. Bulletin 321. 1907 Similar structures, the
Carpinteria Tar Pits The Carpinteria Tar Pits (also Carpinteria Oil Seeps) are a series of natural asphalt lakes situated in the southern part of Santa Barbara County in southern California, USA. The Carpinteria Tar Pits are a natural asphalt lake areas similar ...
, still form on the beach below Carpinteria.


See also

*
Petroleum seep A petroleum seep is a place where natural liquid or gaseous hydrocarbons escape to the earth's atmosphere and surface, normally under low pressure or flow. Seeps generally occur above either terrestrial or offshore petroleum accumulation stru ...
*
Pockmark (geology) Pockmarks are concave, crater-like depressions on seabeds that are caused by fluids (liquids and gasses) escaping and erupting through the seafloor. They can vary in size and have been found worldwide. Pockmarks were discovered off the coasts of N ...
*
Mud volcano A mud volcano or mud dome is a landform created by the eruption of mud or slurries, water and gases. Several geological processes may cause the formation of mud volcanoes. Mud volcanoes are not true igneous volcanoes as they do not produce lava ...
*
Pitch Lake The Pitch Lake is the largest natural deposit of asphalt in the world, estimated to contain 10 million tons. It is located in La Brea in southwest Trinidad, within the Siparia Regional Corporation. The lake covers about 100 acres (0.405 squa ...


References

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External links


What is an asphalt volcano?
Mother Nature Network, 2014. Good photos.

NOAA Ocean Explorer, April 24, 2014 Seamounts Petroleum geology