Arsenical copper contains up to 0.5%

arsenic Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, but ...

which, at elevated temperatures, imparts higher

tensile strength Ultimate tensile strength (UTS), often shortened to tensile strength (TS), ultimate strength, or F_\text within equations, is the maximum stress that a material can withstand while being stretched or pulled before breaking. In brittle materials t ...

and a reduced tendency to scaling. It is typically specified in

boiler A boiler is a closed vessel in which fluid (generally water) is heated. The fluid does not necessarily boil. The heated or vaporized fluid exits the boiler for use in various processes or heating applications, including water heating, central h ...

work, especially locomotive

firebox Firebox may refer to: *Firebox (steam engine), the area where the fuel is burned in a steam engine *Firebox (architecture), the part of a fireplace where fuel is combusted *Firebox Records Firebox Records was a Finnish record label based in S ...

es. It also helps prevent embrittlement of oxygen free copper by

bismuth Bismuth is a chemical element with the Symbol (chemistry), symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental ...

antimony Antimony is a chemical element with the symbol Sb (from la, stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient time ...

and

lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...

by the formation of complex oxides. Copper with a larger percentage of arsenic is called arsenical bronze, which can be work-hardened much harder than copper.

References

Copper alloys Steam boilers Coinage metals and alloys Arsenic {{alloy-stub

See also

References