Archaeometallurgy is the study of the past use and production of metals by humans. It is a sub-discipline of
archaeology
Archaeology or archeology is the scientific study of human activity through the recovery and analysis of material culture. The archaeological record consists of artifacts, architecture, biofacts or ecofacts, sites, and cultural landscap ...
and
archaeological science.
Uses
Archaeometallurgical study has many uses in both the
chemical
A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., wi ...
and
anthropological
Anthropology is the scientific study of humanity, concerned with human behavior, human biology, cultures, societies, and linguistics, in both the present and past, including past human species. Social anthropology studies patterns of behavi ...
fields. Analysis contributes valuable insights into many archaeological questions, from technological choice to social organisation. Any project concerned with the relationship that the human species has had to the metals known to us is an example of archaeometallurgical study.
Methods
There are various methodological approaches to archaeometallurgical studies. The same methods used in
analytical chemistry
Analytical chemistry studies and uses instruments and methods to separate, identify, and quantify matter. In practice, separation, identification or quantification may constitute the entire analysis or be combined with another method. Separati ...
may be used to analyze artifacts. Chemical analysis methods may include the analysis of
mass
Mass is an intrinsic property of a body. It was traditionally believed to be related to the quantity of matter in a physical body, until the discovery of the atom and particle physics. It was found that different atoms and different elementar ...
,
density
Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematical ...
or
chemical composition
A chemical composition specifies the identity, arrangement, and ratio of the elements making up a compound.
Chemical formulas can be used to describe the relative amounts of elements present in a compound. For example, the chemical formula for ...
. Most methods are non-destructive in nature, such as
X-ray spectroscopy
X-ray spectroscopy is a general term for several spectroscopic techniques for characterization of materials by using x-ray radiation.
Characteristic X-ray spectroscopy
When an electron from the inner shell of an atom is excited by the energy o ...
, or micro-destructive (requiring removal of only a tiny portion of the sample). Non-destructive methods can be used on more artefacts than destructive ones, but because they operate at the surface of the metal, corrosion and other surface effects may interfere with the results. Options that include sampling include various forms of
mass spectrometry
Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is use ...
and a variety of chemical tests.
Modern to ancient
One of the methods of archaeometallurgy is the study of modern metals and
alloys
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, ...
to explain and understand the use of metals in the past. A study conducted by the department of Particle Physics and Astrophysics at Weizmann Institute of Science and the department of Archaeology at the University of Haifia analyzed the chemical composition and the mass of different denominations of
Euro
The euro ( symbol: €; code: EUR) is the official currency of 19 out of the member states of the European Union (EU). This group of states is known as the eurozone or, officially, the euro area, and includes about 340 million citizens . ...
coinage. They concluded that even with modern standards and technology, there is a considerable variation within the "same" denomination of coin.
[.] This simple conclusion can be used to further analyze discoveries of ancient currency.
Non-ferrous archaeometallurgy
The specific study of the
non-ferrous metals
In metallurgy, non-ferrous metals are metals or alloys that do not contain iron (allotropes of iron, ferrite, and so on) in appreciable amounts.
Generally more costly than ferrous metals, non-ferrous metals are used because of desirable proper ...
used in past. Gold, silver and copper were the first to be used by ancient humans. Gold and copper are both found in their '
native
Native may refer to:
People
* Jus soli, citizenship by right of birth
* Indigenous peoples, peoples with a set of specific rights based on their historical ties to a particular territory
** Native Americans (disambiguation)
In arts and entert ...
' state in nature, and were thus the first to be exploited as they did not need to be smelted from their ores. They could be hammered into sheets or decorative shapes. The
extraction of copper from its ores may have developed due to the attractive colouring and value of ores such as
malachite
Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures ...
.
Ferrous archaeometallurgy
The specific study of the
ferrous
In chemistry, the adjective Ferrous indicates a compound that contains iron(II), meaning iron in its +2 oxidation state, possibly as the divalent cation Fe2+. It is opposed to "ferric" or iron(III), meaning iron in its +3 oxidation state, such a ...
compounds (those including
iron, Fe) used in the past. Iron metal was first encountered in
meteorites
A meteorite is a solid piece of debris from an object, such as a comet, asteroid, or meteoroid, that originates in outer space and survives its passage through the atmosphere to reach the surface of a planet or moon. When the original object en ...
, and was later extracted from
iron ores
Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the for ...
to create
wrought iron
Wrought iron is an iron alloy with a very low carbon content (less than 0.08%) in contrast to that of cast iron (2.1% to 4%). It is a semi-fused mass of iron with fibrous slag Inclusion (mineral), inclusions (up to 2% by weight), which give it a ...
which was never fully molten, and later,
cast iron
Cast iron is a class of iron–carbon alloys with a carbon content more than 2%. Its usefulness derives from its relatively low melting temperature. The alloy constituents affect its color when fractured: white cast iron has carbide impuriti ...
. Iron combined with carbon formed
steel
Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant ty ...
, allowing people to develop superior tools and weapons from the
Iron Age
The Iron Age is the final epoch of the three-age division of the prehistory and protohistory of humanity. It was preceded by the Stone Age (Paleolithic, Mesolithic, Neolithic) and the Bronze Age (Chalcolithic). The concept has been mostly appl ...
to the
industrial revolution
The Industrial Revolution was the transition to new manufacturing processes in Great Britain, continental Europe, and the United States, that occurred during the period from around 1760 to about 1820–1840. This transition included going f ...
.
History
After initial sporadic work, archaeometallurgy was more widely institutionalised in the 1960s and 70s, with research groups in Britain (
The British Museum
The British Museum is a public museum dedicated to human history, art and culture located in the Bloomsbury area of London. Its permanent collection of eight million works is among the largest and most comprehensive in existence. It documen ...
, the UCL Institute of Archaeology, the Institute for Archeo-Metallurgical Studies (iams)), Germany (
Deutsches Bergbau Museum) and the US (
MIT
The Massachusetts Institute of Technology (MIT) is a private land-grant research university in Cambridge, Massachusetts. Established in 1861, MIT has played a key role in the development of modern technology and science, and is one of the m ...
and
Harvard
Harvard University is a private Ivy League research university in Cambridge, Massachusetts. Founded in 1636 as Harvard College and named for its first benefactor, the Puritan clergyman John Harvard, it is the oldest institution of higher le ...
).
Specialisations within metallurgical focus on
metallography
Metallography is the study of the physical structure and components of metals, by using microscopy.
Ceramic and polymeric materials may also be prepared using metallographic techniques, hence the terms ceramography, plastography and, collectiv ...
of finished objects,
mineralogy
Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical) properties of minerals and mineralized artifacts. Specific studies within mineralogy include the proces ...
of waste products such as
slag
Slag is a by-product of smelting (pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-prod ...
and
manufacturing studies.
See also
*
Ancient iron production
Archaeometallurgical slag is slag discovered and studied in the context of archaeology. Slag, the byproduct of iron-working processes such as smelting or smithing, is left at the iron-working site rather than being moved away with the product. As ...
*
Cupellation
Cupellation is a refining process in metallurgy where ores or alloyed metals are treated under very high temperatures and have controlled operations to separate noble metals, like gold and silver, from base metals, like lead, copper, zinc, arsen ...
*
Liquation
Liquation is a metallurgical method for separating metals from an ore or alloy. A mixture of metals is melted together with a third, after which the mixture is separated by liquid extraction. This method was largely used to separate silver from co ...
*
Roman metallurgy
*
Metallurgy during the Copper Age in Europe
The Copper Age, also called the Eneolithic or the Chalcolithic Age, has been traditionally understood as a transitional period between the Neolithic and the Bronze Age, in which a gradual introduction of the metal (native copper) took place, w ...
*
Metallurgy in Pre-Columbian America
Metallurgy in pre-Columbian America is the extraction, purification and alloying of metals and metal crafting by Indigenous peoples of the Americas prior to European contact in the late 15th century. Indigenous Americans have been using nativ ...
*
History of ferrous metallurgy
Ferrous metallurgy is the metallurgy of iron and its alloys. The earliest surviving prehistoric iron artifacts, from the 4th millennium BC in Egypt, were made from meteoritic iron-nickel. It is not known when or where the smelting of iron from o ...
*
Native copper
Native copper is an uncombined form of copper that occurs as a natural mineral. Copper is one of the few metallic elements to occur in native form, although it most commonly occurs in oxidized states and mixed with other elements. Native coppe ...
*
Tin sources and trade in ancient times
Tin is an essential metal in the creation of tin- bronzes, and its acquisition was an important part of ancient cultures from the Bronze Age onward. Its use began in the Middle East and the Balkans around 3000 BC. Tin is a relatively rare element ...
*
Experimental Archaeometallurgy Experimental archaeometallurgy is a subset of experimental archaeology that specifically involves past metallurgical processes most commonly involving the replication of copper and iron objects as well as testing the methodology behind the productio ...
*
Nonferrous Archaeometallurgy in the Southern Levant
Nonferrous archaeometallurgy in the southern Levant is the archaeological study of non-iron-related metal technology in the region of the Southern Levant during the Chalcolithic period and Bronze Age from approximately 4500BC to 1000BC.
Chalcoli ...
*
Metallurgy#History
References
Further reading
*
R. F. Tylecote (1992) ''A History of Metallurgy'', 2nd edn, Institute of Materials
*S. Kalyanaraman (2011) "Indian Hieroglyphs", Sarasvati Research Center, Herndon, V
Indian Hieroglyphshttp://bharatkalyan97.blogspot.in/2012/02/dr-s-kalyanaramans-recent-contribution.html]
*TH. Rehren and E. Pernicka (2008) "Coins, Artefacts and Isotopes- Archaeometallurgy and Archaeometry", UCL Institute of Archaeology
*Bayley, Crossley, and Ponting (2008) "Metals and Metalworking", Historical Metallurgy Society Occasional Publication no. 6,
*Killick, David, and Thomas Fenn (2012) "Archaeometallurgy: The Study of Preindustrial Mining and Metallurgy", Annual Review of Anthropology, Vol. 41:559-575, DOI: 10.1146/annurev-anthro-092611-145719
External links
The Historical Metallurgy SocietyIAMSoffered two courses in 2012:
*
Prehistoric Metallurgyby Simon Timberlake and Fergus Milton at
Butser Ancient Farm
Butser Ancient Farm is an archaeological open-air museum and experimental archaeology site located near Petersfield, Hampshire, Petersfield in Hampshire, southern England. Butser features experimental reconstructions of prehistoric, Romano-Britis ...
.
Yale University Archaeometallurgy Laboratory
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