Alum-(K) is a hydrous
potassium
Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosphe ...
aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
sulfate mineral
The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal veins and as secondary mine ...
with formula KAl(SO
4)
2·12(H
2O). It is the mineral form of
potassium alum
Potassium alum, potash alum, or potassium aluminium sulfate is a chemical compound: the double sulfate of potassium and aluminium, with chemical formula KAl(SO4)2. It is commonly encountered as the dodecahydrate, KAl(SO4)2·12H2O. It crystalli ...
and is referred to as potassium alum in older sources. It is a member of the alum group.
[Alum-(K) on Mindat]
/ref>
It occurs as colorless to white, soft isometric crystals and efflorescence coatings.[Potassium alum on Handbook of Mineralogy]
/ref> Rare crystals are octahedral in form if occurring as precipitates from neutral water solution, but cubic in form if the solution is alkaline.[
It occurs as a precipitate around volcanic ]fumarole
A fumarole (or fumerole) is a vent in the surface of the Earth or other rocky planet from which hot volcanic gases and vapors are emitted, without any accompanying liquids or solids. Fumaroles are characteristic of the late stages of volcani ...
s and solfatara
A fumarole (or fumerole) is a vent in the surface of the Earth or other rocky planet from which hot volcanic gases and vapors are emitted, without any accompanying liquids or solids. Fumaroles are characteristic of the late stages of volcani ...
s. It also occurs as an alteration in argillaceous sediments or coal beds which contain oxidizing
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...
sulfide mineral
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the ...
s (pyrite
The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Pyrite's metallic Luster (mineralogy), lust ...
or marcasite
The mineral marcasite, sometimes called “white iron pyrite”, is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both ...
). Occurs associated with alunogen
Alunogen (from French ''alun'', “ alum”), also called feather alum and hair salt is a colourless to white (although often coloured by impurities, such as iron substituting for aluminium) fibrous to needle-like aluminium sulfate mineral. It has ...
, pickeringite
Pickeringite is a magnesium aluminium sulfate mineral with formula MgAl2(SO4)4·22(H2O). It forms a series with halotrichite.
It forms as an alteration product of pyrite in aluminium rich rocks and in coal seams.
It also occurs in pyrite rich hyd ...
, epsomite
Epsomite, Epsom salt, or magnesium sulfate heptahydrate, is a hydrous magnesium sulfate mineral with formula MgSO4·7H2O.
Epsomite crystallizes in the orthorhombic system as rarely found acicular or fibrous crystals, the normal form is as massi ...
, melanterite
Melanterite is a mineral form of hydrous iron(II) sulfate: FeSO4·7H2O. It is the iron analogue of the copper sulfate chalcanthite. It alters to siderotil by loss of water. It is a secondary sulfate mineral which forms from the oxidation of pri ...
, gypsum
Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywall. ...
and native sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
.[
Occurrences include ]Mount Vesuvius
Mount Vesuvius ( ; it, Vesuvio ; nap, 'O Vesuvio , also or ; la, Vesuvius , also , or ) is a somma-stratovolcano located on the Gulf of Naples in Campania, Italy, about east of Naples and a short distance from the shore. It is one of s ...
, Italy and Alum Cave, Sevier County, Tennessee
Sevier County ( ) is a county of the U.S. state of Tennessee. As of the 2020 census, the population was 98,380. Its county seat and largest city is Sevierville. Sevier County comprises the Sevierville, TN Micropolitan Statistical Area, which i ...
.[
]
References
Sulfate minerals
Cubic minerals
Minerals in space group 205
Potassium minerals
{{sulfate-mineral-stub