Allam Cycle
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The Allam Cycle or Allam-Fetvedt Cycle is a process for converting carbonaceous fuels into thermal energy, while capturing the generated 
carbon dioxide Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transpar ...
 and water. This zero emissions cycle was validated at a 50 MWth natural gas fed test facility in La Porte, Texas in May 2018. This industrial plant is owned and operated by NET Power LLC, a privately held technology licensing company. NET Power is owned by Constellation Energy Corporation,
Occidental Petroleum Corporation Occidental Petroleum Corporation (often abbreviated Oxy in reference to its ticker symbol and logo) is an American company engaged in hydrocarbon exploration in the United States, and the Middle East as well as petrochemical manufacturing in the ...
(Oxy) Low Carbon Ventures,
Baker Hughes Baker Hughes Company, organized in Delaware and headquartered in Houston, is one of the world's largest oil field services companies. The company provides products and services for oil well drilling, formation evaluation, completion, productio ...
Company and 8 Rivers Capital, the company holding the patents for the technology. The key inventors behind the process are English engineer
Rodney John Allam Rodney John Allam, MBE (born 1940 in St Helens, Lancashire) is an English chemical engineer and fellow of the Institution of Chemical Engineers who is credited with inventions related to power generation, notably the Allam power cycle, which ...
, American engineer Jeremy Eron Fetvedt, American scientist Dr. Miles R Palmer, and American businessperson and innovator G. William Brown, Jr. The Allam-Fetvedt Cycle was recognized by
MIT Technology Review ''MIT Technology Review'' is a bimonthly magazine wholly owned by the Massachusetts Institute of Technology, and editorially independent of the university. It was founded in 1899 as ''The Technology Review'', and was re-launched without "The" in ...
on the 2018 list of 10 Breakthrough Technologies.


Description

The Allam-Fetvedt Cycle that operates as a recuperated, high-pressure,
Brayton cycle The Brayton cycle is a thermodynamic cycle that describes the operation of certain heat engines that have air or some other gas as their working fluid. The original Brayton engines used a piston compressor and piston expander, but modern gas tur ...
employing a transcritical working fluid with an
oxy-fuel combustion Oxy-fuel combustion is the process of burning a fuel using pure oxygen, or a mixture of oxygen and recirculated flue gas, instead of air. Since the nitrogen component of air is not heated, fuel consumption is reduced, and higher flame temperatures ...
regime. This cycle begins by burning a gaseous fuel with oxygen and a hot, high-pressure, recycled supercritical working fluid in a combustor. The recycled stream serves the dual purpose of lowering the combustion flame temperature to a manageable level and diluting the combustion products such that the cycle working fluid is predominantly . The pressure in the combustor can be as high as approximately 30 MPa and the combustion feedstock consists of approximately 95% recycled by mass.  The combustor provides a high-pressure exhaust that can be supplied to a turbine expander operating at a pressure ratio between 6 and 12. The expander discharge leaves as a subcritical mixture predominantly comingled with combustion derived water. This fluid enters an economizer heat exchanger, which cools the expander discharge down to below 65 °C against the stream of that is being recycled to the combustor. Upon exiting the economizer heat exchanger, the expander exhaust is further cooled to near ambient temperature by a central cooling system, enabling liquid water to be removed from the working fluid and recycled for beneficial use.   The remaining working fluid of nearly pure then enters a compression and pumping stage. The compression system consists of a conventional inter-cooled centrifugal compressor with an inlet pressure below the critical pressure. The working fluid is compressed and then cooled to near ambient temperature in the compressor after-cooler. At this point, the combination of compressing and cooling the working fluid permits it to achieve a density in excess of 500 kg/m3. In this condition, the stream can be pumped to the high combustion pressure required using a multi-stage centrifugal pump.  Finally, the high-pressure working fluid is sent back through the economizer heat exchanger to be reheated and returned to the combustor. The net product derived from the addition of fuel and oxygen in the combustor is removed from the high-pressure stream; at this point, the product is high-pressure and high purity, ready for sequestration or utilization without requiring further compression. In order for the system to reach a high
thermal efficiency In thermodynamics, the thermal efficiency (\eta_) is a dimensionless performance measure of a device that uses thermal energy, such as an internal combustion engine, steam turbine, steam engine, boiler, furnace, refrigerator, ACs etc. For a he ...
, a close temperature approach is needed on the high-temperature side of the primary heat exchanger. Due to the cooling process employed at the compression and pumping stage of the Allam-Fetvedt Cycle, a large energy imbalance would typically exist in the cycle between the cooling expander exhaust flow and the reheating recycle flow. The Allam-Fetvedt Cycle corrects this imbalance through the incorporation of low-grade heat at the low-temperature end of the recuperative heat exchanger.  Due to the low temperatures at the cool end of the cycle, this low-grade heat only needs to be in the range of 100 °C to 400 °C.  A convenient source of this heat is the Air Separation Unit (ASU) required for the oxy-fuel combustion regime. This basic configuration, when burning natural gas as a fuel, has been modeled to achieve an efficiency up to 60% (LHV) as a power cycle net of all parasitic loads, including the energy-intensive ASU. Despite its novelty, the components required by this cycle are all currently commercially available, with the exception of the combustion turbine package. The turbine relies on well-proven technologies and approaches used by existing gas and steam turbine design tools.


Applications

Construction began in March 2016 in
La Porte, Texas La Porte ( ) is a city in Harris County, Texas, United States, within the Bay Area of the Houston–Sugar Land–Baytown metropolitan area. As of the 2020 census, the city population was 35,124. La Porte is the fourth-largest incorporated c ...
on a 50 MWth industrial test facility that would showcase the Allam-Fetvedt Cycle, with construction completed in 2017. In 2018, the Allam-Fetvedt Cycle and supporting technologies were validated at this demonstration plant, which now serves as a test facility, allowing OEMs to certify components for use with future Allam-Fetvedt Cycle plants. On November 15, 2021, at approximately 7:40 pm EST the test facility successfully synchronized to the ERCOT grid proving that the Allam Fetvedt Cycle was capable of generating power at 60 Hz. This test facility is owned and operated by NET Power, which is owned by Constellation Energy Corporation,
Occidental Petroleum Occidental Petroleum Corporation (often abbreviated Oxy in reference to its ticker symbol and logo) is an American company engaged in hydrocarbon exploration in the United States, and the Middle East as well as petrochemical manufacturing in the ...
(Oxy) Low Carbon Ventures,
Baker Hughes Baker Hughes Company, organized in Delaware and headquartered in Houston, is one of the world's largest oil field services companies. The company provides products and services for oil well drilling, formation evaluation, completion, productio ...
and 8 Rivers Capital (the inventor of the technology).  In recognition of the Allam-Fetvedt Cycle test facility in La Porte, Texas, NET Power was awarded the 2018 International Excellence in Energy Breakthrough Technological Project of the Year at the Abu Dhabi International Petroleum Exhibition and Conference (ADIPEC).


Patent history


See also

*
Oxy-fuel combustion process Oxy-fuel combustion is the process of burning a fuel using pure oxygen, or a mixture of oxygen and recirculated flue gas, instead of air. Since the nitrogen component of air is not heated, fuel consumption is reduced, and higher flame temperatures ...


References

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External links


Process diagram for natural gas






Energy conversion Thermodynamic cycles English inventions Power station technology Carbon capture and storage