chemistry Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions ...

, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the

saltwort Saltwort is a common name for various genera of flowering plants that thrive in salty environments, typically in coastal salt marshes and seashores, including: :*''Salsola'' and related genera within subfamily ''Salsoloideae'' :*''Salicornia'' :*'' ...

) is a

basic BASIC (Beginners' All-purpose Symbolic Instruction Code) is a family of general-purpose, high-level programming languages designed for ease of use. The original version was created by John G. Kemeny and Thomas E. Kurtz at Dartmouth College ...

, ionic

salt Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quantitie ...

of an

alkali metal The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K),The symbols Na and K for sodium and potassium are derived from their Latin names, ''natrium'' and ''kalium''; these are still the origins of the names ...

or an

alkaline earth metal The alkaline earth metals are six chemical elements in group 2 of the periodic table. They are beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra).. The elements have very similar properties: they are al ...

. An alkali can also be defined as a base that dissolves in

water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a ...

. A solution of a soluble base has a pH greater than 7.0. The

adjective In linguistics, an adjective (list of glossing abbreviations, abbreviated ) is a word that generally grammatical modifier, modifies a noun or noun phrase or describes its referent. Its semantic role is to change information given by the noun. Tra ...

alkaline, and less often, alkalescent, is commonly used in

English English usually refers to: * English language * English people English may also refer to: Peoples, culture, and language * ''English'', an adjective for something of, from, or related to England ** English national ide ...

as a

synonym A synonym is a word, morpheme, or phrase that means exactly or nearly the same as another word, morpheme, or phrase in a given language. For example, in the English language, the words ''begin'', ''start'', ''commence'', and ''initiate'' are all ...

for basic, especially for bases soluble in water. This broad use of the term is likely to have come about because alkalis were the first bases known to obey the Arrhenius definition of a base, and they are still among the most common bases.

Etymology

The word "alkali" is derived from Arabic ''al qalīy'' (or ''alkali''), meaning ''the calcined ashes'' (see

calcination Calcination refers to thermal treatment of a solid chemical compound (e.g. mixed carbonate ores) whereby the compound is raised to high temperature without melting under restricted supply of ambient oxygen (i.e. gaseous O2 fraction of air), genera ...

), referring to the original source of alkaline substances. A water-extract of burned plant ashes, called

potash Potash () includes various mined and manufactured salts that contain potassium in water-soluble form.

and composed mostly of

potassium carbonate Potassium carbonate is the inorganic compound with the formula K2 CO3. It is a white salt, which is soluble in water. It is deliquescent, often appearing as a damp or wet solid. Potassium carbonate is mainly used in the production of soap and gl ...

, was mildly basic. After heating this substance with

calcium hydroxide Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca( OH)2. It is a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed or slaked with water. It has m ...

(''slaked lime''), a far more strongly basic substance known as ''caustic potash'' (

potassium hydroxide Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which exp ...

) was produced. Caustic potash was traditionally used in conjunction with animal fats to produce soft

soap Soap is a salt of a fatty acid used in a variety of cleansing and lubricating products. In a domestic setting, soaps are surfactants usually used for washing, bathing, and other types of housekeeping. In industrial settings, soaps are use ...

s, one of the caustic processes that rendered soaps from fats in the process of

saponification Saponification is a process of converting esters into soaps and alcohols by the action of aqueous alkali (for example, aqueous sodium hydroxide solutions). Soaps are salts of fatty acids, which in turn are carboxylic acids with long carbon chains. ...

, one known since antiquity. Plant potash lent the name to the element

potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosphe ...

, which was first derived from caustic potash, and also gave potassium its chemical symbol K (from the German name ''Kalium''), which ultimately derived from alkali.

Common properties of alkalis and bases

Alkalis are all Arrhenius bases, ones which form

hydroxide Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. I ...

ions (OH⁻) when dissolved in water. Common properties of alkaline

aqueous solution An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would be re ...

s include: * Moderately concentrated solutions (over 10⁻³ M) have a pH of 10 or greater. This means that they will turn

phenolphthalein Phenolphthalein ( ) is a chemical compound with the chemical formula, formula carbon, C20hydrogen, H14oxygen, O4 and is often written as "HIn", "HPh", "phph" or simply "Ph" in shorthand notation. Phenolphthalein is often used as an indicator in ...

from colorless to pink. * Concentrated solutions are

caustic Caustic most commonly refers to: * Causticity, a property of various corrosive substances ** Sodium hydroxide, sometimes called ''caustic soda'' ** Potassium hydroxide, sometimes called ''caustic potash'' ** Calcium oxide, sometimes called ''caus ...

(causing

chemical burns A chemical burn occurs when living tissue is exposed to a corrosive substance (such as a strong acid, base or oxidizer) or a cytotoxic agent (such as mustard gas, lewisite or arsine). Chemical burns follow standard burn classification and may cau ...

). * Alkaline solutions are slippery or soapy to the touch, due to the

of the fatty substances on the surface of the skin. * Alkalis are normally

water-soluble In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solub ...

, although some like

barium carbonate Barium carbonate is the inorganic compound with the formula BaCO3. Like most alkaline earth metal carbonates, it is a white salt that is poorly soluble in water. It occurs as the mineral known as witherite. In a commercial sense, it is one of t ...

are only soluble when reacting with an acidic aqueous solution.

Difference between alkali and base

The terms "base" and "alkali" are often used interchangeably, particularly outside the context of

and

chemical engineering Chemical engineering is an engineering field which deals with the study of operation and design of chemical plants as well as methods of improving production. Chemical engineers develop economical commercial processes to convert raw materials int ...

. There are various, more specific definitions for the concept of an alkali. Alkalis are usually defined as a subset of the bases. One of two subsets is commonly chosen. * A basic salt of an alkali metal or alkaline earth metal (this includes Mg(OH)₂ (

magnesium hydroxide Magnesium hydroxide is the inorganic compound with the chemical formula Mg(OH)2. It occurs in nature as the mineral brucite. It is a white solid with low solubility in water (). Magnesium hydroxide is a common component of antacids, such as milk ...

) but excludes NH₃ (

ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous was ...

)). * Any base that is soluble in water and forms hydroxide ions or the solution of a base in water. (This includes both Mg(OH)₂ and NH₃, which forms NH₄OH.) The second subset of bases is also called an "

Arrhenius base Arrhenius may refer to * Birgit Arrhenius (born 1932), Swedish archaeologist * Carl Axel Arrhenius (1757–1824), Swedish army lieutenant and amateur mineralogist who discovered ytterbite, a mineral that led to the discovery of yttrium by Johan Gad ...

Alkali salts

Alkali salts are soluble hydroxides of

alkali metals The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K),The symbols Na and K for sodium and potassium are derived from their Latin names, ''natrium'' and ''kalium''; these are still the origins of the names ...

and

alkaline earth metals The alkaline earth metals are six chemical elements in group 2 of the periodic table. They are beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra).. The elements have very similar properties: they are all ...

, of which common examples are: *

Sodium hydroxide Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations and hydroxide anions . Sodium hydroxide is a highly caustic base and alkali ...

(NaOH) – often called "caustic soda" *

Potassium hydroxide Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which exp ...

(KOH) – commonly called "caustic potash" *

Lye A lye is a metal hydroxide traditionally obtained by leaching wood ashes, or a strong alkali which is highly soluble in water producing caustic basic solutions. "Lye" most commonly refers to sodium hydroxide (NaOH), but historically has been u ...

– generic term for either of two previous salts or their mixture *

Calcium hydroxide Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca( OH)2. It is a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed or slaked with water. It has m ...

(Ca(OH)₂) – saturated solution known as "

limewater Limewater is the common name for a saturated aqueous solution of calcium hydroxide. Calcium hydroxide, Ca(OH)2, is sparsely soluble at room temperature in water (1.5 g/L at 25 °C). "Pure" (i.e. less than or fully saturated) limewater i ...

" *

Magnesium hydroxide Magnesium hydroxide is the inorganic compound with the chemical formula Mg(OH)2. It occurs in nature as the mineral brucite. It is a white solid with low solubility in water (). Magnesium hydroxide is a common component of antacids, such as milk ...

(Mg(OH)₂) – an atypical alkali since it has low solubility in water (although the dissolved portion is considered a strong base due to complete dissociation of its ions)

Alkaline soil

Soils with pH values that are higher than 7.3 are usually defined as being alkaline. These soils can occur naturally, due to the presence of alkali salts. Although many plants do prefer slightly basic soil (including vegetables like

cabbage Cabbage, comprising several cultivars of ''Brassica oleracea'', is a leafy green, red (purple), or white (pale green) biennial plant grown as an annual vegetable crop for its dense-leaved heads. It is descended from the wild cabbage ( ''B.&nb ...

and fodder like

buffalo grass Buffalo grass may refer to * Buffalo grass, sweet vernal grass or vanilla grass ('' Anthoxanthum odoratum'') * Buffalo grass ('' Bouteloua dactyloides'') * Buffalo grass ('' Brachiaria mutica'') * Buffalo grass or sweet grass (''Hierochloe odorata' ...

), most plants prefer a mildly acidic soil (with pHs between 6.0 and 6.8), and

alkaline soil Alkali, or Alkaline, soils are clay soils with high pH (greater than 8.5), a poor soil structure and a low infiltration capacity. Often they have a hard calcareous layer at 0.5 to 1 metre depth. Alkali soils owe their unfavorable physico- ...

s can cause problems.

Alkali lakes

In alkali lakes (also called ''soda lakes''), evaporation concentrates the naturally occurring carbonate salts, giving rise to an alkalic and often saline lake. Examples of alkali lakes: * Alkali Lake,

Lake County, Oregon Lake County is one of the 36 counties in the U.S. state of Oregon. As of the 2020 census, the population was 8,160. Its county seat is Lakeview. The county is named after the many lakes found within its boundaries, including Lake Abert, Summe ...

* Baldwin Lake,

San Bernardino County, California San Bernardino County (), officially the County of San Bernardino, is a County (United States), county located in the Southern California, southern portion of the U.S. state of California, and is located within the Inland Empire area. As of the ...

* Bear LakeDavis, Jim and Milligan, Mark (2011)
Why is Bear Lake so blue?
Public Information Series 96.

Utah Geological Survey The Utah Geological Survey is based in Salt Lake City, Utah, United States. It also has an office in Cedar City, Utah. It is a division of the

, Department of Natural Resources on the Utah–Idaho border *

Lake Magadi Lake Magadi is the southernmost lake in the Kenyan Rift Valley, lying in a catchment of faulted volcanic rocks, north of Tanzania's Lake Natron. During the dry season, it is 80% covered by soda and is well known for its wading birds, including f ...

in Kenya *

Lake Turkana Lake Turkana (), formerly known as Lake Rudolf, is a lake in the Kenyan Rift Valley, in northern Kenya, with its far northern end crossing into Ethiopia. It is the world's largest permanent desert lake and the world's largest alkaline lake. B ...

Kenya ) , national_anthem = "Ee Mungu Nguvu Yetu"() , image_map = , map_caption = , image_map2 = , capital = Nairobi , coordinates = , largest_city = Nairobi , ...

Mono Lake Mono Lake ( ) is a saline soda lake in Mono County, California, formed at least 760,000 years ago as a terminal lake in an endorheic basin. The lack of an outlet causes high levels of salts to accumulate in the lake which make its water alk ...

, near

Owens Valley Owens Valley (Numic Numic is a branch of the Uto-Aztecan language family. It includes seven languages spoken by Native American peoples traditionally living in the Great Basin, Colorado River basin, Snake River basin, and southern Great Pl ...

California California is a U.S. state, state in the Western United States, located along the West Coast of the United States, Pacific Coast. With nearly 39.2million residents across a total area of approximately , it is the List of states and territori ...

Redberry Lake, Saskatchewan Redberry Lake is a lake near Hafford in the Canadian province of Saskatchewan. It is a medium-sized saline lake within an area characterized by mostly freshwater aquatic environments. The lake makes up the core protected area of the Redberry ...

* Summer Lake,

Tramping Lake, Saskatchewan Tramping Lake (Canada 2016 Census, 2016 population: ) is a village in the Provinces and territories of Canada, Canadian province of Saskatchewan within the Rural Municipality of Tramping Lake No. 380 and Division No. 13, Saskatchewan, Census Di ...

References

{{Authority control Inorganic chemistry