Alison Walker (scientist)

Alison Bridget Walker is a physicist who is a professor at the University of Bath. Her research considers computational modelling of printed electronic devices and the development of perovskite solar cells. She is best known for her work on the Kinetic Monte Carlo method.

Early life and education

Walker was born in Sarawak. She completed her undergraduate and postgraduate studies at the University of Oxford. Her doctoral research considered nuclear quadrupole interactions and fast ionic conductors. After earning her doctorate, Walker moved to the United States, where she joined Michigan State University as a postdoctoral fellow. She moved to the Daresbury Laboratory as a research fellow.

Research and career

Walker started her independent scientific career at the University of East Anglia. She joined the University of Bath in 1998, where she was awarded a Royal Society Industry Fellowship to work at Cambridge Display Technology.

Walker has developed kinetic Monte Carlo (KMC) approaches to better understand the electronic processes of printed electronic devices. In particular, she has considered photovoltaics and light emitting diodes (LEDs). Several different electronic processes take place in these devices, such as charge injection, the formation of excitons (bound electron – hole pairs), charge and exciton migration, and charge recombination/separation (dissociation). The KMCs developed by Walker take into account the complex three-dimensional morphology of the organic active layer and allow for investigations into how device architectures impact device performance. Beyond KMCs, Walker has developed drift-diffusion models to understand the movement of charge and energy in one-dimension.

In her efforts to understand the mechanisms that underpin device operation in OFETs, OLEDs and OPVs, Walker uses optical models that solve Maxwell's equations. These equations can be used to understand the variations in fields associated with photon absorption and generation. Such models can be used to understand the luminance, quantum efficiencies and current-voltage characteristics. A combination of the three models can be used to identify and optimise the positions of the dissociation and recombination zones. In 2013 Walker was made Academic Director of the Centre for Doctoral Training in New and Sustainable Photovoltaics, as well as co-leading the University of Bath SuperSolar network.

Walker has worked with Petra Cameron to investigate perovskite solar cells, hybrid devices that contain organic and inorganic materials. The active layers of these devices contain perovskite crystal structures, which strongly absorb solar radiation. Electrons within the perovskite are excited across the material bandgap, creating mobile charge carriers that migrate to electron and hole transport layers. Walker was made coordinator of the Horizon 2020 programme MAking pErovskiteS TRuly explOitable (Maestro). Walker has created protein simulations to understand the structure and function of biologically-relevant molecules.

Selected publications

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References

{{DEFAULTSORT:Walker, Alison
Living people
Year of birth missing (living people)
Women physicists
Academics of the University of Bath
Alumni of the University of Oxford