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Adams chromatic valence color spaces are a class of
color space A color space is a specific organization of colors. In combination with color profiling supported by various physical devices, it supports reproducible representations of colorwhether such representation entails an analog or a digital represent ...
s suggested by
Elliot Quincy Adams Elliot Quincy Adams (September 13, 1888 – March 12, 1971) was an American scientist. Chemist Gilbert N. Lewis remarked that "the two most profound scientific minds, among the people he had known, were those of E liotQ Adams and Albert Einstein. ...
. Two important Adams chromatic valence spaces are
CIELUV In colorimetry, the CIE 1976 ''L''*, ''u''*, ''v''* color space, commonly known by its abbreviation CIELUV, is a color space adopted by the International Commission on Illumination (CIE) in 1976, as a simple-to-compute transformation of the 1931 CI ...
and Hunter Lab. Chromatic value/valence spaces are notable for incorporating the opponent process model and the empirically-determined 2½ factor in the red/green vs. blue/yellow chromaticity components (such as in
CIELAB The CIELAB color space, also referred to as ''L*a*b*'' , is a color space defined by the International Commission on Illumination (abbreviated CIE) in 1976. (Referring to CIELAB as "Lab" without asterisks should be avoided to prevent confusion ...
).


Chromatic value

In 1942, Adams suggested chromatic ''value'' color spaces. Chromatic value, or ''chromance'', refers to the intensity of the
opponent process The opponent process is a color theory that states that the human visual system interprets information about color by processing signals from photoreceptor cells in an antagonistic manner. The opponent-process theory suggests that there are thr ...
responses and is derived from Adams' theory of color vision. A chromatic value space consists of three components: * V_Y, the Munsell–Sloan–Godlove value function: V_Y^2 = 1.4742Y - 0.004743 Y^2; * V_X - V_Y, the red–green chromaticity dimension, where V_X is the value function applied to (y_n/x_n)X instead of ''Y''; * V_Z - V_Y, the blue–yellow chromaticity dimension, where V_Z is the value function applied to (y_n/z_n)Z instead of ''Y''. A chromatic value diagram is a plot of V_X - V_Y (horizontal axis) against 0.4(V_Z - V_Y) (vertical axis). The 2½ scale factor is intended to make radial distance from the
white point A white point (often referred to as reference white or target white in technical documents) is a set of tristimulus values or chromaticity coordinates that serve to define the color "white" in image capture, encoding, or reproduction. Depending on ...
correlate with the Munsell chroma along any one hue radius (i.e., to make the diagram perceptually uniform). For achromatic surfaces, (y_n/x_n)X = Y = (y_n/z_n)Z, and hence V_X - V_Y = 0, V_Z - V_Y = 0. In other words, the white point is at the origin. Constant differences along the chroma dimension did not ''appear'' different by a corresponding amount, so Adams proposed a new class of spaces, which he termed chromatic ''valence''. These spaces have "nearly equal radial distances for equal changes in Munsell chroma".


Chromance

In chromaticity scales, lightness is factored out, leaving two dimensions. Two lights with the same
spectral power distribution In radiometry, photometry, and color science, a spectral power distribution (SPD) measurement describes the power per unit area per unit wavelength of an illumination (radiant exitance). More generally, the term ''spectral power distribution'' ...
, but different luminance, will have identical
chromaticity Chromaticity is an objective specification of the quality of a color regardless of its luminance. Chromaticity consists of two independent parameters, often specified as hue (h) and colorfulness (s), where the latter is alternatively called ...
coordinates. The familiar CIE (''x'', ''y'')
chromaticity diagram Chromaticity is an objective specification of the quality of a color regardless of its luminance. Chromaticity consists of two independent parameters, often specified as hue (h) and colorfulness (s), where the latter is alternatively called ...
is very perceptually non-uniform: small perceptual changes in chromaticity in greens, for example, translate into large
distances Distance is a numerical or occasionally qualitative measurement of how far apart objects or points are. In physics or everyday usage, distance may refer to a physical length or an estimation based on other criteria (e.g. "two counties over"). ...
, while larger perceptual differences in chromaticity in other colors are usually much smaller. Adams suggested a relatively simple uniform chromaticity scale in his 1942 paper: : \fracX - Y and \fracZ - Y, where x_n, y_n, z_n are the chromaticities of the reference white object (the ''n'' suggests normalized). (Adams had used smoked
magnesium oxide Magnesium oxide ( Mg O), or magnesia, is a white hygroscopic solid mineral that occurs naturally as periclase and is a source of magnesium (see also oxide). It has an empirical formula of MgO and consists of a lattice of Mg2+ ions and O2− ions ...
under CIE Illuminant C, but these would be considered obsolete today. This exposition is generalized from his papers.) Objects which have the same chromaticity coordinates as the white object usually appear neutral, or fairly so, and normalizing in this fashion ensures that their coordinates lie at the origin. Adams plotted the first one the horizontal axis and the latter, multiplied by 0.4, on the vertical axis. The scaling factor is to ensure that the contours of constant chroma (saturation) lie on a circle. Distances along any radius from the origin are proportional to
colorimetric purity Colorimetry is "the science and technology used to quantify and describe physically the human color perception". It is similar to spectrophotometry, but is distinguished by its interest in reducing spectra to the physical correlates of color ...
. The chromance diagram is not invariant to brightness, so Adams normalized each term by the ''Y'' tristimulus value: : \frac \frac = \frac and \frac \frac = \frac. These expressions, he noted, depended only on the chromaticity of the sample. Accordingly, he called their plot a "constant-brightness chromaticity diagram". This diagram does not have the white point at the origin, but at (1, 1) instead.


Chromatic valence

Chromatic valence spaces incorporate two relatively
perceptually uniform In color science, color difference or color distance is the separation between two colors. This metric allows quantified examination of a notion that formerly could only be described with adjectives. Quantification of these properties is of great ...
elements: a
chromaticity Chromaticity is an objective specification of the quality of a color regardless of its luminance. Chromaticity consists of two independent parameters, often specified as hue (h) and colorfulness (s), where the latter is alternatively called ...
scale and a
lightness Lightness is a visual perception of the luminance (L) of an object. It is often judged relative to a similarly lit object. In colorimetry and color appearance models, lightness is a prediction of how an illuminated color will appear to a stan ...
scale. The lightness scale, determined using the Newhall–Nickerson–Judd value function, forms one axis of the color space: : Y = 1.2219V_J - 0.23111V_J^2 + 0.23951V_J^3 - 0.021009V_J^4 + 0.0008404V_J^5. The remaining two axes are formed by multiplying the two uniform chromaticity coordinates by the lightness, ''VJ'': : \frac - 1 = \frac, : \frac - 1 = \frac. This is essentially what Hunter used in his
Lab color space The CIELAB color space, also referred to as ''L*a*b*'' , is a color space defined by the International Commission on Illumination (abbreviated CIE) in 1976. (Referring to CIELAB as "Lab" without asterisks should be avoided to prevent confusion ...
. As with chromatic value, these functions are plotted with a scale factor of 2½ to give nearly equal radial distance for equal changes in Munsell chroma.


Color difference

Adams' color spaces rely on the
Munsell Munsell may refer to: * Albert Henry Munsell (1858–1918), American painter, teacher of art, and the inventor of the Munsell color system * Harvey M. Munsell, American soldier in the Civil War. *Munsell Color Company *Munsell color system In c ...
value Value or values may refer to: Ethics and social * Value (ethics) wherein said concept may be construed as treating actions themselves as abstract objects, associating value to them ** Values (Western philosophy) expands the notion of value beyo ...
for lightness. Defining chromatic valence components W_X=\left(\frac-1\right) V_J and W_Z= \left(\frac-1\right)V_J, we can determine the difference between two colors as: : \Delta E=\sqrt where VJ is the Newhall-Nickerson-Judd value function and the 0.4 factor is incorporated to better make differences in WX and WZ perceptually correspond to one another. In chromatic value color spaces, the chromaticity components are W_X=V_X-V_Y and W_Z=V_Z-V_Y. The difference is: : \Delta E=\sqrt{(0.23 \Delta V_Y)^2+(\Delta W_X)^2 + (0.4 \Delta W_Z)^2} where the Munsell-Sloan-Godlove value function is applied to the tristimulus value indicated in the subscript. (Note that the two spaces use different lightness approximations.)


References

Color space