Acanthite is a form of silver sulfide with the chemical formula Ag₂S. It crystallizes in the

monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic s ...

system and is the stable form of silver sulfide below .

Argentite In mineralogy, argentite (from the Latin ''argentum'', silver) is cubic silver sulfide (Ag2S), which can only exist at temperatures above 173 °C, 177 °C or 179 °C. When it cools to ordinary temperatures it turns into its mono ...

is the stable form above that temperature. As argentite cools below that temperature its cubic form is distorted to the monoclinic form of acanthite. Below 173 °C acanthite forms directly. Acanthite is the only stable form in normal air temperature.

Occurrence

Acanthite is a common silver mineral in moderately low-temperature

hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...

veins Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated b ...

and in zones of supergene enrichment. It occurs in association with native silver,

pyrargyrite Pyrargyrite is a sulfosalt mineral consisting of silver sulfantimonite, Ag3SbS3. Known also as dark red silver ore or ruby silver, it is an important source of the metal. It is closely allied to, and isomorphous with, the corresponding sulfarse ...

proustite Proustite is a sulfosalt mineral consisting of silver sulfarsenide, Ag3 As S3, known also as light red silver or ruby silver ore, and an important source of the metal. It is closely allied to the corresponding sulfantimonide, pyrargyrite, from whi ...

polybasite Polybasite is a sulfosalt mineral of silver, copper, antimony and arsenic. Its chemical formula is . It forms black monoclinic crystals (thin, tabular, with six corners) which can show dark red internal reflections. It has a Mohs hardness o ...

stephanite Stephanite is a silver antimony sulfosalt mineral with formula: Ag5 Sb S4. It is composed of 68.8% silver, and sometimes is of importance as an ore of this metal. History Under the name Schwarzerz it was mentioned by Georgius Agricola in 1546, an ...

aguilarite Aguilarite is an uncommon sulfosalt mineral with formula Ag4 Se S. It was described in 1891 and named for discoverer Ponciano Aguilar. Description Aguilarite is bright lead-gray on fresh surfaces but becomes dull iron black when exposed to air. T ...

galena Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It cryst ...

chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mo ...

sphalerite Sphalerite (sometimes spelled sphaelerite) is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimen ...

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

and

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...

. Acanthite was first described in 1855 for an occurrence in the Jáchymov (St Joachimsthal) District, Krušné Hory Mts ( Erzgebirge), Karlovy Vary Region,

Bohemia Bohemia ( ; cs, Čechy ; ; hsb, Čěska; szl, Czechy) is the westernmost and largest historical region of the Czech Republic. Bohemia can also refer to a wider area consisting of the historical Lands of the Bohemian Crown ruled by the Bohem ...

Czech Republic The Czech Republic, or simply Czechia, is a landlocked country in Central Europe. Historically known as Bohemia, it is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the southeast. The ...

. The name is from the Greek "akantha" meaning thorn or arrow, in reference to its crystal shape.

Gallery

File:Acanthite - Chispas Mine, Arizpe, Sonora, Mexico.jpg, Acanthite - Locality: Chispas Mine,

Arizpe Arizpe (or Arispe) is a small town and the municipal seat of the Arizpe Municipality in the north of the Mexican state of Sonora. It is located at 30°20'"N 110°09'"W. The area of the municipality is 2,806.78 sq.km. The population in 2005 was ...

Sonora Sonora (), officially Estado Libre y Soberano de Sonora ( en, Free and Sovereign State of Sonora), is one of the 31 states which, along with Mexico City, comprise the Administrative divisions of Mexico, Federal Entities of Mexico. The state is d ...

, Mexico. Scale is one inch with a ruled line at one cm. File:Acanthite-180757.jpg, Classic acanthite specimen from the Rayas Mine at

Guanajuato Guanajuato (), officially the Free and Sovereign State of Guanajuato ( es, Estado Libre y Soberano de Guanajuato), is one of the 32 states that make up the Federal Entities of Mexico. It is divided into 46 municipalities and its capital city i ...

, Mexico.Size: 2.4 x 1.1 x 1.1 cm.

References

{{ores Sulfide minerals Silver minerals Monoclinic minerals Minerals in space group 14