The hydrogen line, 21 centimeter line, or H I line is the
electromagnetic radiation
In physics, electromagnetic radiation (EMR) consists of waves of the electromagnetic field, electromagnetic (EM) field, which propagate through space and carry momentum and electromagnetic radiant energy. It includes radio waves, microwaves, inf ...
spectral line
A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to iden ...
that is created by a change in the energy state of neutral
hydrogen atom
A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral atom contains a single positively charged proton and a single negatively charged electron bound to the nucleus by the Coulomb force. Atomic hydrogen consti ...
s. This electromagnetic radiation has a precise frequency of , which is equivalent to the
vacuum wavelength
In physics, the wavelength is the spatial period of a periodic wave—the distance over which the wave's shape repeats.
It is the distance between consecutive corresponding points of the same phase on the wave, such as two adjacent crests, tro ...
of in
free space
A vacuum is a space devoid of matter. The word is derived from the Latin adjective ''vacuus'' for "vacant" or "void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressure. Physicists often dis ...
. This frequency falls below the
microwave
Microwave is a form of electromagnetic radiation with wavelengths ranging from about one meter to one millimeter corresponding to frequencies between 300 MHz and 300 GHz respectively. Different sources define different frequency ran ...
region of the
electromagnetic spectrum
The electromagnetic spectrum is the range of frequencies (the spectrum) of electromagnetic radiation and their respective wavelengths and photon energies.
The electromagnetic spectrum covers electromagnetic waves with frequencies ranging from ...
, which begins at 3.0 GHz (10 cm wavelength), and it is observed frequently in
radio astronomy
Radio astronomy is a subfield of astronomy that studies celestial objects at radio frequencies. The first detection of radio waves from an astronomical object was in 1933, when Karl Jansky at Bell Telephone Laboratories reported radiation coming f ...
because those
radio wave
Radio waves are a type of electromagnetic radiation with the longest wavelengths in the electromagnetic spectrum, typically with frequencies of 300 gigahertz (GHz) and below. At 300 GHz, the corresponding wavelength is 1 mm (short ...
s can penetrate the large clouds of interstellar
cosmic dust
Cosmic dust, also called extraterrestrial dust, star dust or space dust, is dust which exists in outer space, or has fallen on Earth. Most cosmic dust particles measure between a few molecules and 0.1 mm (100 micrometers). Larger particles are c ...
that are
opaque
Opacity or opaque may refer to:
* Impediments to (especially, visible) light:
** Opacities, absorption coefficients
** Opacity (optics), property or degree of blocking the transmission of light
* Metaphors derived from literal optics:
** In lingu ...
to
visible light
Light or visible light is electromagnetic radiation that can be perceived by the human eye. Visible light is usually defined as having wavelengths in the range of 400–700 nanometres (nm), corresponding to frequencies of 750–420 te ...
. This line is also the theoretical basis of the
hydrogen maser
A hydrogen maser, also known as hydrogen frequency standard, is a specific type of maser that uses the intrinsic properties of the hydrogen atom to serve as a precision frequency reference.
Both the proton and electron of a hydrogen atom have sp ...
.
The microwaves of the hydrogen line come from the atomic transition of an electron between the two
hyperfine levels
In atomic physics, hyperfine structure is defined by small shifts in otherwise degenerate energy levels and the resulting splittings in those energy levels of atoms, molecules, and ions, due to electromagnetic multipole interaction between the nuc ...
of the hydrogen
1 s ground state
The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. ...
that have an energy difference of []. It is called the ''spin-flip transition''. The frequency, , of the quantum, quanta that are emitted by this transition between two different energy levels is given by the Planck–Einstein relation . According to that relation, the
photon energy
Photon energy is the energy carried by a single photon. The amount of energy is directly proportional to the photon's electromagnetic frequency and thus, equivalently, is inversely proportional to the wavelength. The higher the photon's frequency, ...
of a
photon
A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they always ...
with a frequency of is []. The constant of proportionality, , is known as the Planck constant.
Cause
The ground state of neutral hydrogen consists of an electron bound to a proton. Both the electron and the proton have intrinsic magnetic dipole moments ascribed to their
spin
Spin or spinning most often refers to:
* Spinning (textiles), the creation of yarn or thread by twisting fibers together, traditionally by hand spinning
* Spin, the rotation of an object around a central axis
* Spin (propaganda), an intentionally b ...
, whose interaction results in a slight increase in energy when the spins are parallel, and a decrease when antiparallel. The fact that only parallel and antiparallel states are allowed is a result of the quantum mechanical discretization of the total
angular momentum
In physics, angular momentum (rarely, moment of momentum or rotational momentum) is the rotational analog of linear momentum. It is an important physical quantity because it is a conserved quantity—the total angular momentum of a closed syst ...
of the system. When the spins are parallel, the magnetic dipole moments are antiparallel (because the electron and proton have opposite charge), thus one would expect this configuration to actually have ''lower energy'' just as two magnets will align so that the north pole of one is closest to the south pole of the other. This logic fails here because the wave functions of the electron and the proton overlap; that is, the electron is not spatially displaced from the proton, but encompasses it. The magnetic dipole moments are therefore best thought of as tiny current loops. As parallel currents attract, the parallel magnetic dipole moments (i.e., antiparallel spins) have lower energy. The transition has an energy difference of that when applied in the Planck equation gives:
:
where is the Planck constant and is the speed of light.
This transition is highly
forbidden with an extremely small transition rate of , and a mean lifetime of the excited state of around 10 million years. A spontaneous occurrence of the transition is unlikely to be seen in a laboratory on Earth, but it can be artificially induced using a
hydrogen maser
A hydrogen maser, also known as hydrogen frequency standard, is a specific type of maser that uses the intrinsic properties of the hydrogen atom to serve as a precision frequency reference.
Both the proton and electron of a hydrogen atom have sp ...
. It is commonly observed in astronomical settings such as
hydrogen clouds in our galaxy and others. Because of its long lifetime, the line has an extremely small
natural width, so most broadening is due to
Doppler shift
The Doppler effect or Doppler shift (or simply Doppler, when in context) is the change in frequency of a wave in relation to an observer who is moving relative to the wave source. It is named after the Austrian physicist Christian Doppler, who d ...
s caused by bulk motion or nonzero temperature of the emitting regions.
Discovery
During the 1930s, it was noticed that there was a radio "hiss" that varied on a daily cycle and appeared to be extraterrestrial in origin. After initial suggestions that this was due to the Sun, it was observed that the radio waves seemed to propagate from the
centre of the Galaxy. These discoveries were published in 1940 and were noted by
Jan Oort
Jan Hendrik Oort ( or ; 28 April 1900 – 5 November 1992) was a Dutch astronomer who made significant contributions to the understanding of the Milky Way and who was a pioneer in the field of radio astronomy. His ''New York Times'' obituary ...
who knew that significant advances could be made in astronomy if there were
emission line
A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to iden ...
s in the radio part of the spectrum. He referred this to
Hendrik van de Hulst
Hendrik Christoffel "Henk" van de Hulst (19 November 1918 – 31 July 2000) was a Dutch astronomer and mathematician.
In 1944, while a student in Utrecht, he predicted the existence of the 21 cm hyperfine line of neutral interstellar hydrogen. ...
who, in 1944, predicted that
neutral
Neutral or neutrality may refer to:
Mathematics and natural science Biology
* Neutral organisms, in ecology, those that obey the unified neutral theory of biodiversity
Chemistry and physics
* Neutralization (chemistry), a chemical reaction in ...
hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, an ...
could produce radiation at a
frequency
Frequency is the number of occurrences of a repeating event per unit of time. It is also occasionally referred to as ''temporal frequency'' for clarity, and is distinct from ''angular frequency''. Frequency is measured in hertz (Hz) which is eq ...
of due to two closely spaced energy levels in the
ground state
The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. ...
of the
hydrogen atom
A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral atom contains a single positively charged proton and a single negatively charged electron bound to the nucleus by the Coulomb force. Atomic hydrogen consti ...
.
The 21 cm line (1420.4 MHz) was first detected in 1951 by and
Purcell
Henry Purcell (, rare: September 1659 – 21 November 1695) was an English composer.
Purcell's style of Baroque music was uniquely English, although it incorporated Italian and French elements. Generally considered among the greatest En ...
at
Harvard University
Harvard University is a private Ivy League research university in Cambridge, Massachusetts. Founded in 1636 as Harvard College and named for its first benefactor, the Puritan clergyman John Harvard, it is the oldest institution of higher le ...
, and published after their data was corroborated by Dutch astronomers Muller and Oort, and by
Christiansen __NOTOC__
Christiansen () is a Danish and Norwegian patronymic surname, literally meaning ''son of Christian''. The spelling variant Kristiansen has identical pronunciation. Christiansen is the sixteenth most common name in Denmark, but is shared ...
and Hindman in Australia. After 1952 the first maps of the neutral hydrogen in the Galaxy were made, and revealed for the first time the spiral structure of the
Milky Way
The Milky Way is the galaxy that includes our Solar System, with the name describing the galaxy's appearance from Earth: a hazy band of light seen in the night sky formed from stars that cannot be individually distinguished by the naked eye ...
.
Uses
In radio astronomy
The 21 cm spectral line appears within the
radio spectrum
The radio spectrum is the part of the electromagnetic spectrum with frequencies from 0 Hz to 3,000 GHz (3 THz). Electromagnetic waves in this frequency range, called radio waves, are widely used in modern technology, particula ...
(in the
L band of the
UHF band of the
microwave window to be exact). Electromagnetic energy in this range can easily pass through the Earth's atmosphere and be observed from the Earth with little interference.
Assuming that the hydrogen atoms are uniformly distributed throughout the galaxy, each line of sight through the galaxy will reveal a hydrogen line. The only difference between each of these lines is the Doppler shift that each of these lines has. Hence, one can calculate the relative speed of each arm of our galaxy. The
rotation curve
The rotation curve of a disc galaxy (also called a velocity curve) is a plot of the orbital speeds of visible stars or gas in that galaxy versus their radial distance from that galaxy's centre. It is typically rendered graphically as a plot, and ...
of our galaxy has been calculated using the hydrogen line. It is then possible to use the plot of the rotation curve and the velocity to determine the distance to a certain point within the galaxy.
Hydrogen line observations have also been used indirectly to calculate the mass of galaxies, to put limits on any changes over time of the universal
gravitational constant
The gravitational constant (also known as the universal gravitational constant, the Newtonian constant of gravitation, or the Cavendish gravitational constant), denoted by the capital letter , is an empirical physical constant involved in ...
and to study the dynamics of individual galaxies.
In cosmology
The line is of great interest in
Big Bang
The Big Bang event is a physical theory that describes how the universe expanded from an initial state of high density and temperature. Various cosmological models of the Big Bang explain the evolution of the observable universe from the ...
cosmology because it is the only known way to probe the "dark ages" from
recombination to
reionization
In the fields of Big Bang theory and cosmology, reionization is the process that caused matter in the universe to reionize after the lapse of the " dark ages".
Reionization is the second of two major phase transitions of gas in the universe (t ...
. Including the
redshift
In physics, a redshift is an increase in the wavelength, and corresponding decrease in the frequency and photon energy, of electromagnetic radiation (such as light). The opposite change, a decrease in wavelength and simultaneous increase in f ...
, this line will be observed at frequencies from 200 MHz to about 9 MHz on Earth. It potentially has two applications. First, by
mapping the intensity of redshifted 21 centimeter radiation it can, in principle, provide a very precise picture of the
matter power spectrum
The matter power spectrum describes the density contrast of the universe (the difference between the local density and the mean density) as a function of scale. It is the Fourier transform of the matter correlation function. On large scales, ...
in the period after recombination. Second, it can provide a picture of how the universe was re‑ionized, as neutral hydrogen which has been ionized by radiation from stars or quasars will appear as holes in the 21 cm background.
However, 21 cm observations are very difficult to make. Ground-based experiments to observe the faint signal are plagued by interference from television transmitters and the
ionosphere
The ionosphere () is the ionized part of the upper atmosphere of Earth, from about to above sea level, a region that includes the thermosphere and parts of the mesosphere and exosphere. The ionosphere is ionized by solar radiation. It plays an ...
, so they must be made from very secluded sites with care taken to eliminate interference. Space based experiments, even on the far side of the Moon (where they would be sheltered from interference from terrestrial radio signals), have been proposed to compensate for this. Little is known about other effects, such as
synchrotron emission
Synchrotron radiation (also known as magnetobremsstrahlung radiation) is the electromagnetic radiation emitted when relativistic charged particles are subject to an acceleration perpendicular to their velocity (). It is produced artificially in ...
and
free–free emission on the galaxy. Despite these problems, 21 cm observations, along with space-based gravitational wave observations, are generally viewed as the next great frontier in observational cosmology, after the
cosmic microwave background polarization.
Relevance to the search for non-human intelligent life
The
Pioneer plaque
The Pioneer plaques are a pair of gold-anodized aluminum plaques that were placed on board the 1972 ''Pioneer 10'' and 1973 ''Pioneer 11'' spacecraft, featuring a pictorial message, in case either ''Pioneer 10'' or ''11'' is intercepted by inte ...
, attached to the
Pioneer 10
''Pioneer 10'' (originally designated Pioneer F) is an American space probe, launched in 1972 and weighing , that completed the first mission to the planet Jupiter. Thereafter, ''Pioneer 10'' became the first of five artificial objects to ach ...
and
Pioneer 11
''Pioneer 11'' (also known as ''Pioneer G'') is a robotic space probe launched by NASA on April 5, 1973, to study the asteroid belt, the environment around Jupiter and Saturn, solar winds, and cosmic rays. It was the first probe to encounter ...
spacecraft, portrays the hyperfine transition of neutral hydrogen and used the wavelength as a standard scale of measurement. For example, the height of the woman in the image is displayed as eight times 21 cm, or 168 cm. Similarly the frequency of the hydrogen spin-flip transition was used for a unit of time in a map to Earth included on the Pioneer plaques and also the
Voyager 1
''Voyager 1'' is a space probe launched by NASA on September 5, 1977, as part of the Voyager program to study the outer Solar System and interstellar space beyond the Sun's heliosphere. Launched 16 days after its twin ''Voyager 2'', ''Voya ...
and
Voyager 2
''Voyager 2'' is a space probe launched by NASA on August 20, 1977, to study the outer planets and interstellar space beyond the Sun's heliosphere. As a part of the Voyager program, it was launched 16 days before its twin, ''Voyager 1'', on a ...
probes. On this map, the position of the Sun is portrayed relative to 14
pulsar
A pulsar (from ''pulsating radio source'') is a highly magnetized rotating neutron star that emits beams of electromagnetic radiation out of its magnetic poles. This radiation can be observed only when a beam of emission is pointing toward Ea ...
s whose rotation period circa 1977 is given as a multiple of the frequency of the hydrogen spin-flip transition. It is theorized by the plaque's creators that an advanced civilization would then be able to use the locations of these pulsars to locate the
Solar System
The Solar SystemCapitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Solar S ...
at the time the spacecraft were launched.
The 21 cm hydrogen line is considered a favorable frequency by the
SETI
The search for extraterrestrial intelligence (SETI) is a collective term for scientific searches for intelligent extraterrestrial life, for example, monitoring electromagnetic radiation for signs of transmissions from civilizations on other p ...
program in their search for signals from potential extraterrestrial civilizations. In 1959, Italian physicist
Giuseppe Cocconi
Giuseppe Cocconi (1914–2008) was an Italian physicist who was director of the Proton Synchrotron at CERN in Geneva.
He is known for his work in particle physics and for his involvement with SETI where he wrote, " e probability of success is d ...
and American physicist
Philip Morrison
Philip Morrison (November 7, 1915 – April 22, 2005) was a professor of physics at the Massachusetts Institute of Technology (MIT). He is known for his work on the Manhattan Project during World War II, and for his later work in quantum physi ...
published "Searching for interstellar communications", a paper proposing the 21 cm hydrogen line and the potential of microwaves in the search for interstellar communications. According to George Basalla, the paper by Cocconi and Morrison "provided a reasonable theoretical basis" for the then-nascent SETI program. Similarly,
Pyotr Makovetsky proposed SETI use a frequency which is equal to either
: × ≈
or
:
2 × ≈
Since
is an
irrational number
In mathematics, the irrational numbers (from in- prefix assimilated to ir- (negative prefix, privative) + rational) are all the real numbers that are not rational numbers. That is, irrational numbers cannot be expressed as the ratio of two integ ...
, such a frequency could not possibly be produced in a natural way as a
harmonic
A harmonic is a wave with a frequency that is a positive integer multiple of the ''fundamental frequency'', the frequency of the original periodic signal, such as a sinusoidal wave. The original signal is also called the ''1st harmonic'', the ...
, and would clearly signify its artificial origin. Such a signal would not be overwhelmed by the H I line itself, or by any of its harmonics.
See also
*
Balmer series
The Balmer series, or Balmer lines in atomic physics, is one of a set of six named series describing the spectral line emissions of the hydrogen atom. The Balmer series is calculated using the Balmer formula, an empirical equation discovered b ...
*
Chronology of the universe
The chronology of the universe describes the history and future of the universe according to Big Bang cosmology.
Research published in 2015 estimates the earliest stages of the universe's existence as taking place 13.8 billion years ago, wit ...
*
Dark Ages Radio Explorer
The Dark Ages Radio Explorer (DARE) mission is a proposed concept lunar orbiter intended to identify redshifted emanations from primeval hydrogen atoms just as the first stars began to emit light. DARE will use the precisely redshifted 21-cm tr ...
*
Hydrogen spectral series
The emission spectrum of atomic hydrogen has been divided into a number of spectral series, with wavelengths given by the Rydberg formula. These observed spectral lines are due to the electron making transitions between two energy levels in an ...
*
H-alpha
H-alpha (Hα) is a specific deep-red visible spectral line in the Balmer series with a wavelength of 656.28 nm in air and 656.46 nm in vacuum; it occurs when a hydrogen electron falls from its third to second lowest energy level. H-alph ...
, the visible red spectral line with wavelength of 656.28
nanometer
330px, Different lengths as in respect to the molecular scale.
The nanometre (international spelling as used by the International Bureau of Weights and Measures; SI symbol: nm) or nanometer (American and British English spelling differences#-re ...
s
*
Rydberg formula
In atomic physics, the Rydberg formula calculates the wavelengths of a spectral line in many chemical elements. The formula was primarily presented as a generalization of the Balmer series for all atomic electron transitions of hydrogen. It was ...
*
Schelling point
In game theory, a focal point (or Schelling point) is a solution that people tend to choose by default in the absence of communication. The concept was introduced by the American economist Thomas Schelling in his book ''The Strategy of Conflict'' ( ...
*
Timeline of the Big Bang
The chronology of the universe describes the history and future of the universe according to Big Bang cosmology.
Research published in 2015 estimates the earliest stages of the universe's existence as taking place 13.8 billion years ago, with ...
Footnotes
References
Cosmology
*
*
*
*
*
*
*
*
External links
*
* — Ewen and Purcell's original paper
* — PAST experiment description
*
*
*
{{Portal bar, Physics, Chemistry, Astronomy, Stars, Spaceflight, Outer space, Solar System
Hydrogen physics
Emission spectroscopy
Radio astronomy
Physical cosmology
Astrochemistry
Hydrogen