Disperse dye is a category of
synthetic dye
A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution and ...
intended for
polyester and related hydrophobic fibers. Disperse dyes are polar molecules containing anthraquinone or azo groups. It is estimated that 85% of disperse dyes are
azos or
anthraquinone dye
Anthraquinone dyes are an abundant group of dyes comprising a anthraquinone unit as the shared structural element. Anthraquinone itself is colourless, but red to blue dyes are obtained by introducing electron donor groups such as hydroxy or amino ...
s.
History
The history of disperse dye production is closely related to the synthesis of
cellulose acetate
In biochemistry, cellulose acetate refers to any acetate ester of cellulose, usually cellulose diacetate. It was first prepared in 1865. A bioplastic, cellulose acetate is used as a film base in photography, as a component in some coatings, and ...
fibres. Disperse dyes were invented in 1923-24.
Fundamentals of dyeing
Disperse dyes are
non-ionic
An ion () is an atom or molecule with a net electrical charge.
The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
in nature and partially
soluble
In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution.
The extent of the solubi ...
in water. The interaction of dye molecule and polymer takes place with
Van der Waals and
dipole
In physics, a dipole () is an electromagnetic phenomenon which occurs in two ways:
*An electric dipole deals with the separation of the positive and negative electric charges found in any electromagnetic system. A simple example of this system ...
forces. Disperse dyes have better diffusion at boiling to a higher temperature.
Examples
*
Disperse Orange 1
Disperse Orange 1, or 4-anilino-4'-nitroazobenzene, is an azo dye. Commercial samples contain approximately 25% dye by weight, with the remaining mass consisting of NaCl
Sodium chloride , commonly known as salt (although sea salt also cont ...
is an
azo dye.
*
Disperse Red 9
Disperse Red 9, or 1-(methylamino)anthraquinone, is a red dye derived from anthraquinone. Disperse Red 9 is used in some older red and violet-red colored smoke formulations. It is used in the M18 colored smoke grenade and also often in dye packs ...
is a red dye derived from
anthraquinone
Anthraquinone, also called anthracenedione or dioxoanthracene, is an aromatic organic compound with formula . Isomers include various quinone derivatives. The term anthraquinone however refers to the isomer, 9,10-anthraquinone (IUPAC: 9,10-dioxoan ...
.
*
Disperse Red 11
Disperse Red 11, or 1,4-diamino-2-methoxyanthraquinone, is a red disperse dye derived from anthraquinone. It is water insoluble.
Disperse Red 11 can be used in plastics and textiles industry to dye polyvinylchloride, polyester, polyamide, and ...
, also called C.I. 62015 and 1,4-diamino-2-methoxy anthraquinone, is another anthraquinone dye.
*
Disperse Red 60
Disperse Red 60, or 1-amino-4-hydroxy-2-phenoxyanthraquinone, is a popular disperse dye of the anthraquinone
Anthraquinone, also called anthracenedione or dioxoanthracene, is an aromatic organic compound with formula . Isomers include various qui ...
is also an anthraquinone dye.
*
Disperse Yellow 26 is a yellow disperse dye.
*
Disperse Yellow 42 is prepared by the reaction of two equivalents of
aniline
Aniline is an organic compound with the formula C6 H5 NH2. Consisting of a phenyl group attached to an amino group, aniline is the simplest aromatic amine. It is an industrially significant commodity chemical, as well as a versatile starti ...
with 4-chloro-3-nitro
benzenesulfonyl chloride
Benzenesulfonyl chloride is an organosulfur compound with the formula C6H5SO2Cl. It is a colourless viscous oil that dissolves in organic solvents, but reacts with compounds containing reactive N-H and O-H bonds. It is mainly used to prepare sulfo ...
.
References
{{Dyeing
Dyes