1,3-Cyclopentanedione is an
organic compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The ...
with the formula (CH
2)
3(CO)
2. It is one of two isomeric cyclopentanediones, the other being
1,2-cyclopentanedione
1,2-Cyclopentanedione is the organic compound with the formula (CH2)3(CO)2. It is one of two isomeric cyclopentanediones, the other being 1,3-cyclopentanedione. It was first prepared by base-induced condensation of di
ethylglutarate with dieth ...
. The
enol
In organic chemistry, alkenols (shortened to enols) are a type of reactive structure or intermediate in organic chemistry that is represented as an alkene ( olefin) with a hydroxyl group attached to one end of the alkene double bond (). The te ...
is predicted to be about 1-3 kcal/mol more stable than the diketo form. The enol structure has been confirmed by
X-ray crystallography
X-ray crystallography is the experimental science determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to diffract into many specific directions. By measuring the angles ...
.
Preparation
The compound is prepared by hydrogenation of 2-cyclopentene-1,4-dione using zinc/acetic acid.
References
{{DEFAULTSORT:Cyclopentanedione, 1, 3-
Diketones
Cyclic ketones