1,2-Cyclohexanedione is an
organic compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The ...
with the formula (CH)(CO). It is one of three isomeric
cyclohexanedione Cyclohexanedione may refer to:
* 1,2-Cyclohexanedione
* 1,3-Cyclohexanedione
1,3-Cyclohexanedione is an organic compound with the formula (CH2)4(CO)2. It is one of three isomeric cyclohexanediones. It is a colorless compound that occurs natura ...
s. It is a colorless compound that is soluble in a variety of organic solvents. It can be prepared by oxidation of
cyclohexanone
Cyclohexanone is the organic compound with the formula (CH2)5CO. The molecule consists of six-carbon cyclic molecule with a ketone functional group. This colorless oily liquid has an odor reminiscent of acetone. Over time, samples of cyclohexan ...
by
selenium dioxide
Selenium dioxide is the chemical compound with the formula SeO2. This colorless solid is one of the most frequently encountered compounds of selenium.
Properties
Solid SeO2 is a one-dimensional polymer, the chain consisting of alternating seleniu ...
. The
enol
In organic chemistry, alkenols (shortened to enols) are a type of reactive structure or intermediate in organic chemistry that is represented as an alkene ( olefin) with a hydroxyl group attached to one end of the alkene double bond (). The te ...
is about 1 kcal/mol more stable than the diketo form.
Numerous
diimine
Diimines are organic compounds containing two imine (RCH=NR') groups. Common derivatives are 1,2-diketones and 1,3-diimines. These compounds are used as ligands and as precursors to heterocycles. Diimines are prepared by condensation reactions ...
and dioxime ligands have been prepared from this diketone. It condenses with 1,2-
diamine
A diamine is an amine with exactly two amino groups. Diamines are used as monomers to prepare polyamides, polyimides, and polyureas. The term ''diamine'' refers mostly to primary diamines, as those are the most reactive.
In terms of quantities p ...
s to give diaza heterocycles.
References
{{DEFAULTSORT:Cyclohexanedione, 1, 2-
Diketones
Cyclic ketones