(Pentamethylcyclopentadienyl)titanium Trichloride
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(Pentamethylcyclopentadienyl)titanium trichloride is an
organotitanium compound Organotitanium chemistry is the science of organotitanium compounds describing their physical properties, synthesis, and reactions. Organotitanium compounds in organometallic chemistry contain carbon-titanium chemical bonds. They are reagents in or ...
with the formula Cp*TiCl3 (Cp* = C5(CH3)5). It is an orange solid. The compound adopts a piano stool geometry. An early synthesis involve the combination of lithium pentamethylcyclopentadienide and
titanium tetrachloride Titanium tetrachloride is the inorganic compound with the formula . It is an important intermediate in the production of titanium metal and the pigment titanium dioxide. is a volatile liquid. Upon contact with humid air, it forms thick clouds o ...
. The compound is an intermediate in the synthesis of
decamethyltitanocene dichloride Decamethyltitanocene dichloride is an organotitanium compound with the formula Cp*2TiCl2 (where Cp* is C5(CH3)5, derived from pentamethylcyclopentadiene). It is a red solid that is soluble in nonpolar organic solvents. The complex has been the ...
. In the presence of organoaluminium compounds and other additives, it catalyzes the polymerization of alkenes.


See also

*
(Cyclopentadienyl)titanium trichloride (Cyclopentadienyl)titanium trichloride is an organotitanium compound with the formula (CH)TiCl. It is a moisture sensitive orange solid. The compound adopts a piano stool geometry. Preparation and reactions (CH)TiCl is prepared by the reaction ...


References

{{DEFAULTSORT:Pentamethyclopentadienyl)titanium trichloride Chloro complexes Titanium compounds Half sandwich compounds