Zinc Pest
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Zinc Pest
Zinc pest (from German ''Zinkpest''), also known as zinc rot and zamak rot, is a destructive, intercrystalline corrosion process of zinc alloys containing lead impurities. Prepared under the direction of the ASM International Handbook Committee. While impurities of the alloy are the primary cause of the problem, environmental conditions such as high humidity (greater than 65%) may accelerate the process. It was first discovered to be a problem in 1923, and primarily affects die-cast zinc articles that were manufactured during the 1920s through 1950s. The New Jersey Zinc Company developed zamak alloys in 1929 using 99.99% pure zinc metal to avoid the problem, and articles made after 1960 are usually considered free of the risk of zinc pest since the use of purer materials and more controlled manufacturing conditions make zinc pest degradation unlikely. Affected objects may show surface irregularities such as small cracks and fractures, blisters or pitting. Over time, the materia ...
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Märklin 344 - Zinkpest
Gebr. Märklin & Cie. GmbH or Märklin (MÄRKLIN or MAERKLIN in capital letters) is a German toy company. The company was founded in 1859 and is based at Göppingen in Baden-Württemberg. Although it originally specialised in doll house accessories, today it is best known for model railways and technical toys. In some parts of Germany and in Sweden, the company's name is almost synonymous with model railways. History Märklin was founded by Theodor Friedrich Wilhelm Märklin in 1859. Märklin released its first wind-up train with carriages that ran on standardised track in 1891, noting that railway toys had the potential to follow the common practice of doll's houses, in which the initial purchase would be enhanced and expanded with more accessories for years after the initial purchase. To this end, Märklin offered additional rolling stock and track with which to expand its boxed sets. Märklin is responsible for the creation of several popular model railway gauges or sc ...
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Collecting
The hobby of collecting includes seeking, locating, acquiring, organizing, cataloging, displaying, storing, and maintaining items that are of interest to an individual ''collector''. Collections differ in a wide variety of respects, most obviously in the nature and scope of the objects contained, but also in purpose, presentation, and so forth. The range of possible subjects for a collection is practically unlimited, and collectors have realised a vast number of these possibilities in practice, although some are much more popular than others. In collections of manufactured items, the objects may be antique or simply collectable. Antiques are collectable items at least 100 years old, while other collectables are arbitrarily recent. The word ''vintage'' describes relatively old collectables that are not yet antiques. Collecting is a childhood hobby for some people, but for others a lifelong pursuit or something started in adulthood. Collectors who begin early in life often modi ...
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Bronze Disease
Bronze disease is an irreversible and nearly :wikt:inexorable, inexorable corrosion process that occurs when chlorides come into contact with bronze or other List of copper alloys, copper-bearing alloys. It can occur as both a dark green coating, or as a much lighter whitish fuzzy or furry green coating. It is not a bacterial infection, but the result of a chemical reaction with the chlorides that usually occurs due to contamination of the bronze object by saltwater or from burial in specific types of soil where chloride salts are present. If not treated, complete destruction of the affected artifact is possible. Treatment is very difficult, costly and not always effective. Transfer of chlorides from the contaminated artefact to other artefacts can spread the condition. Description Bronze disease is the chloride corrosion of cuprous (copper-based) artifacts. It was originally thought to be caused by bacteria. It is contagious in that the chlorides which cause it can spread the ...
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Tin Pest
Tin is a chemical element with the symbol Sn (from la, stannum) and atomic number 50. Tin is a silvery-coloured metal. Tin is soft enough to be cut with little force and a bar of tin can be bent by hand with little effort. When bent, the so-called "tin cry" can be heard as a result of twinning in tin crystals; this trait is shared by indium, cadmium, zinc, and mercury in the solid state. Pure tin after solidifying presents a mirror-like appearance similar to most metals. In most tin alloys (such as pewter) the metal solidifies with a dull gray color. Tin is a post-transition metal in group 14 of the periodic table of elements. It is obtained chiefly from the mineral cassiterite, which contains stannic oxide, . Tin shows a chemical similarity to both of its neighbors in group 14, germanium and lead, and has two main oxidation states, +2 and the slightly more stable +4. Tin is the 49th most abundant element on Earth and has, with 10 stable isotopes, the largest n ...
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Wet Storage Stain
Wet storage stain, more commonly known as white rust or white corrosion, is a type of zinc corrosion. It is called wet storage stain because it occurs when a fresh zinc surface is stored in a wet environment with limited oxygen and carbon dioxide sources; the restriction in air is usually due to the items being stacked on one another or otherwise stored in close quarters. This type of corrosion does not usually occur to zinc surfaces that have had time to form their normal layers of corrosion protection.. Chemistry Wet storage stain is a white, crumbly, and porous substance that is a mixture of three chemical compounds: 2ZnCO3·3Zn(OH)2, ZnO, and β-Zn(OH)2. Underneath the white coating is usually a dark gray surface. The corrosion product is very voluminous; it is approximately 100 times greater in volume than the zinc consumed. Because of this the corrosion is not usually detrimental to the usability of the item, unless the zinc surface is only a thin coating, such as zinc elect ...
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Lincoln Cent
The Lincoln cent (sometimes called the Lincoln penny) is a one-cent coin that has been struck by the United States Mint since 1909. The obverse or heads side was designed by Victor David Brenner, as was the original reverse, depicting two stalks of wheat (thus "wheat pennies", struck 1909–1958). The coin has seen several reverse, or tails, designs and now bears one by Lyndall Bass depicting a Union shield. All coins struck by the United States government with a value of of a dollar are called cents because the United States has always minted coins using decimals. The penny nickname is a carryover from the coins struck in England, which went to decimals for coins in 1971. In 1905, sculptor Augustus Saint-Gaudens was hired by the Mint to redesign the cent and the four gold coins, which did not require congressional approval. Two of Saint-Gaudens's proposed designs for the cent were eventually adapted for the gold pieces, but Saint-Gaudens died in before submitting additional des ...
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Oxalic Acid
Oxalic acid is an organic acid with the systematic name ethanedioic acid and formula . It is the simplest dicarboxylic acid. It is a white crystalline solid that forms a colorless solution in water. Its name comes from the fact that early investigators isolated oxalic acid from flowering plants of the genus ''Oxalis'', commonly known as wood-sorrels. It occurs naturally in many foods. Excessive ingestion of oxalic acid or prolonged skin contact can be dangerous. Oxalic acid has much greater acid strength than acetic acid. It is a reducing agent and its conjugate base, known as oxalate (), is a chelating agent for metal cations. Typically, oxalic acid occurs as the dihydrate with the formula . History The preparation of salts of oxalic acid (crab acid) from plants had been known, at least since 1745, when the Dutch botanist and physician Herman Boerhaave isolated a salt from wood sorrel. By 1773, François Pierre Savary of Fribourg, Switzerland had isolated oxalic acid from i ...
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Vinegar
Vinegar is an aqueous solution of acetic acid and trace compounds that may include flavorings. Vinegar typically contains 5–8% acetic acid by volume. Usually, the acetic acid is produced by a double fermentation, converting simple sugars to ethanol using yeast, and ethanol to acetic acid by acetic acid bacteria. Many types of vinegar are available, depending on source materials. It is now mainly used in the culinary arts as a flavorful, acidic cooking ingredient, or in pickling. Various types are used as condiments or garnishes, including balsamic vinegar and malt vinegar. As the most easily manufactured mild acid, it has a wide variety of industrial and domestic uses, including use as a household cleaner. Etymology The word "vinegar" arrived in Middle English from Old French (''vyn egre''; sour wine), which in turn derives from Latin: ''vinum'' (wine) + ''acer'' (sour). Chemistry The conversion of ethanol (CH3CH2OH) and oxygen (O2) to acetic acid (CH3COOH) takes plac ...
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Rail Transport Modelling
Railway modelling (UK, Australia, New Zealand, and Ireland) or model railroading (US and Canada) is a hobby in which rail transport systems are modelled at a reduced Scale (ratio), scale. The scale models include locomotives, rolling stock, streetcars, rail tracks, tracks, Railway signal, signalling, Crane (machine), cranes, and landscapes including: countryside, roads, bridges, buildings, vehicles, harbors, urban landscape, model figures, lights, and features such as rivers, hills, tunnels, and canyons. The earliest model railways were the 'carpet railways' in the 1840s. The first documented model railway was the Railway of the Prince Imperial (French: Chemin de fer du Prince impérial) built in 1859 by emperor Napoleon III for his then 3-year-old son, also Napoleon, in the grounds of the Château de Saint-Cloud in Paris. It was powered by clockwork and ran in a figure-of-eight. Electric trains appeared around the start of the 20th century, but these were crude likenesses. M ...
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Die-cast Toy
A die-cast toy is a toy or a collectible model produced by using the die-casting method of putting molten lead, zinc alloy or plastic in a mold to produce a particular shape. Such toys are made of metal, with plastic, rubber, glass, or other machined metal parts. Wholly plastic toys are made by a similar process of injection molding, but the two methods are distinct because of the properties of the materials. Process The metal used in die-casting is either a lead alloy (used early on), or more commonly, Zamak (called ''Mazak'' in the UK), an alloy of zinc with small quantities of aluminium and copper. Lead or iron are impurities that must be carefully avoided in Zamac, as they give rise to a deterioration of the metal most commonly called zinc pest. The terms white metal or pot metal are also used when applied to alloys based more on lead or iron. The most common die-cast vehicles are scale models of automobiles, aircraft, military vehicles, construction equipment, and trains, ...
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Irreversible Process
In science, a process that is not reversible is called irreversible. This concept arises frequently in thermodynamics. All complex natural processes are irreversible, although a phase transition at the coexistence temperature (e.g. melting of ice cubes in water) is well approximated as reversible. In thermodynamics, a change in the thermodynamic state of a system and all of its surroundings cannot be precisely restored to its initial state by infinitesimal changes in some property of the system without expenditure of energy. A system that undergoes an irreversible process may still be capable of returning to its initial state. Because entropy is a state function, the change in entropy of the system is the same whether the process is reversible or irreversible. However, the impossibility occurs in restoring the environment to its own initial conditions. An irreversible process increases the total entropy of the system and its surroundings. The second law of thermodynamics can be ...
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Dinky Liners With Zinc Pest
Dinky may refer to: Arts and entertainment * Dinky Toys, a brand of die-cast toy vehicles * Dinky (film), a 1935 film starring Jackie Cooper * Dinky Bossetti, protagonist of the 1990 film ''Welcome Home, Roxy Carmichael'', played by Winona Ryder * title character of ''Dinky Dog'', an animated segment on ''The All-New Popeye Hour'' TV series * Dinky Doodle, a cartoon character created by Walter Lantz in 1924 * Dinky Duck, a character in 14 Terrytoons cartoons from 1939 to 1957 * protagonist of the novel ''Dinky Hocker Shoots Smack'' by Marijane Meaker (under the pen name M. E. Kerr) and its TV adaptation * Dinky Little, a character in ''The Littles'' children's novel series and TV series of the same name * Dinky Doo, a placeholder name for a background baby unicorn in the children's cartoon '' My Little Pony: Friendship Is Magic'' People * Dinky Bingham (born 1963), African-American singer, musician, songwriter and producer * nickname of Corazon Soliman (born 1953), Filipino polit ...
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