Xenon Fluorides
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Xenon Fluorides
Three different xenon fluorides, all exergonic and stable, are known: *Xenon difluoride, XeF2 *Xenon tetrafluoride, XeF4 *Xenon hexafluoride Xenon hexafluoride is a noble gas compound with the formula XeF6. It is one of the three binary fluorides of xenon, the other two being XeF2 and XeF4. All known are exergonic and stable at normal temperatures. XeF6 is the strongest fluorinati ..., XeF6 {{Short pages monitor ...
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Xenon Difluoride
Xenon difluoride is a powerful fluorinating agent with the chemical formula , and one of the most stable xenon compounds. Like most covalent inorganic fluorides it is moisture-sensitive. It decomposes on contact with water vapor, but is otherwise stable in storage. Xenon difluoride is a dense, colourless crystalline solid. It has a nauseating odour and low vapor pressure. Structure Xenon difluoride is a linear molecule with an Xe–F bond length of in the vapor stage, and 200 pm in the solid phase. The packing arrangement in solid shows that the fluorine atoms of neighbouring molecules avoid the equatorial region of each molecule. This agrees with the prediction of VSEPR theory, which predicts that there are 3 pairs of non-bonding electrons around the equatorial region of the xenon atom. At high pressures, novel, non-molecular forms of xenon difluoride can be obtained. Under a pressure of ~50 GPa Grading in education is the process of applying standardized ...
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Xenon Tetrafluoride
Xenon tetrafluoride is a chemical compound with chemical formula . It was the first discovered binary compound of a noble gas. It is produced by the chemical reaction of xenon with fluorine: : Xe + 2  → This reaction is exothermic, releasing an energy of 251  kJ/mol. Xenon tetrafluoride is a colorless crystalline solid that sublimes at 117 °C. Its structure was determined by both NMR spectroscopy and X-ray crystallography in 1963. The structure is square planar, as has been confirmed by neutron diffraction studies. According to VSEPR theory, in addition to four fluoride ligands, the xenon center has two lone pairs of electrons. These lone pairs are mutually ''trans''. Synthesis Xenon tetrafluoride is produced by heating a mixture of xenon and fluorine in a 1:5 molar ratio in a nickel container to 400 °C. Some xenon difluoride () and xenon hexafluoride () is also produced, where increased temperature or decreased fluorine concentration in the input ...
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