Whole Number Rule
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Whole Number Rule
In chemistry, the whole number rule states that the masses of the isotopes are whole number multiples of the mass of the hydrogen atom. The rule is a modified version of Prout's hypothesis proposed in 1815, to the effect that atomic weights are multiples of the weight of the hydrogen atom. It is also known as the Aston whole number rule after Francis W. Aston who was awarded the Nobel Prize in Chemistry in 1922 "for his discovery, by means of his mass spectrograph, of isotopes, in a large number of non-radioactive elements, and for his enunciation of the whole-number rule." Law of definite proportions The law of definite proportions was formulated by Joseph Proust around 1800 and states that all samples of a chemical compound will have the same elemental composition by mass. The atomic theory of John Dalton expanded this concept and explained matter as consisting of discrete atoms with one kind of atom for each element combined in fixed proportions to form compounds. Prout's hy ...
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Francis William Aston
Francis William Aston FRS (1 September 1877 – 20 November 1945) was a British chemist and physicist who won the 1922 Nobel Prize in Chemistry for his discovery, by means of his mass spectrograph, of isotopes in many non-radioactive elements and for his enunciation of the whole number rule. He was a fellow of the Royal Society and Fellow of Trinity College, Cambridge. Biography Early life Francis Aston was born in Harborne, now part of Birmingham, on 1 September 1877. He was the third child and second son of William Aston and Fanny Charlotte Hollis. He was educated at the Harborne Vicarage School and later Malvern College in Worcestershire where he was a boarder. In 1893 Francis William Aston began his university studies at Mason College (which was then external college of University of London) where he was taught physics by John Henry Poynting and chemistry by Frankland and Tilden. From 1896 on he conducted additional research on organic chemistry in a private laborat ...
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Mass Spectrometer
Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a '' mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures. A mass spectrum is a type of plot of the ion signal as a function of the mass-to-charge ratio. These spectra are used to determine the elemental or isotopic signature of a sample, the masses of particles and of molecules, and to elucidate the chemical identity or structure of molecules and other chemical compounds. In a typical MS procedure, a sample, which may be solid, liquid, or gaseous, is ionized, for example by bombarding it with a beam of electrons. This may cause some of the sample's molecules to break up into positively charged fragments or simply become positively charged without fragmenting. These ions (fragments) are then separated accor ...
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Mass Number
The mass number (symbol ''A'', from the German word ''Atomgewicht'' tomic weight, also called atomic mass number or nucleon number, is the total number of protons and neutrons (together known as nucleons) in an atomic nucleus. It is approximately equal to the ''atomic'' (also known as ''isotopic'') mass of the atom expressed in atomic mass units. Since protons and neutrons are both baryons, the mass number ''A'' is identical with the baryon number ''B'' of the nucleus (and also of the whole atom or ion). The mass number is different for each isotope of a given chemical element, and the difference between the mass number and the atomic number ''Z'' gives the number of neutrons (''N'') in the nucleus: . The mass number is written either after the element name or as a superscript to the left of an element's symbol. For example, the most common isotope of carbon is carbon-12, or , which has 6 protons and 6 neutrons. The full isotope symbol would also have the atomic numbe ...
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Isotope
Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numbers) due to different numbers of neutrons in their nuclei. While all isotopes of a given element have almost the same chemical properties, they have different atomic masses and physical properties. The term isotope is formed from the Greek roots isos ( ἴσος "equal") and topos ( τόπος "place"), meaning "the same place"; thus, the meaning behind the name is that different isotopes of a single element occupy the same position on the periodic table. It was coined by Scottish doctor and writer Margaret Todd in 1913 in a suggestion to the British chemist Frederick Soddy. The number of protons within the atom's nucleus is called its atomic number and is equal to the number of electrons in the neutral (non-ionized) atom. Each atom ...
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The Nobel Foundation
The Nobel Foundation ( sv, Nobelstiftelsen) is a private institution founded on 29 June 1900 to manage the finances and administration of the Nobel Prizes. The foundation is based on the last will of Alfred Nobel, the inventor of dynamite. It also holds Nobel Symposia on important breakthroughs in science and topics of cultural or social significance. History , born on 21 October 1833 in Stockholm Sweden, was a chemist, engineer, innovator, armaments manufacturer and the inventor of dynamite. He owned Bofors, a major armaments manufacturer, which he had redirected from its original business as an iron and steel mill. Nobel held 355 different patents, dynamite being the most famous. Nobel amassed a sizeable personal fortune during his lifetime, thanks mostly to this invention. In 1896 Nobel died of a stroke in his villa in San Remo, Italy where he had lived his final years.AFP"Alfred Nobel's last will and testament", '' The Local''(5 October 2009): accessed 14 January 2009. ...
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Nobel Prize In Physics
) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then "MDCCCXXXIII" above, followed by (smaller) "OB•" then "MDCCCXCVI" below. , awarded_for = Outstanding contributions for humankind in the field of Physics , presenter = Royal Swedish Academy of Sciences , location = Stockholm, Sweden , date = , reward = 9 million Swedish kronor (2017) , year = 1901 , holder_label = Most recently awarded to , holder = Alain Aspect, John Clauser, and Anton Zeilinger , most_awards = John Bardeen (2) , website nobelprize.org, previous = 2021 , year2=2022, main=2022, next= 2023 The Nobel Prize in Physics is a yearly award given by the Royal Swedish Academy of Sciences for those who have made the most outstanding contributions for humankind in the field of physics. I ...
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Nature (journal)
''Nature'' is a British weekly scientific journal founded and based in London, England. As a multidisciplinary publication, ''Nature'' features peer-reviewed research from a variety of academic disciplines, mainly in science and technology. It has core editorial offices across the United States, continental Europe, and Asia under the international scientific publishing company Springer Nature. ''Nature'' was one of the world's most cited scientific journals by the Science Edition of the 2019 '' Journal Citation Reports'' (with an ascribed impact factor of 42.778), making it one of the world's most-read and most prestigious academic journals. , it claimed an online readership of about three million unique readers per month. Founded in autumn 1869, ''Nature'' was first circulated by Norman Lockyer and Alexander Macmillan as a public forum for scientific innovations. The mid-20th century facilitated an editorial expansion for the journal; ''Nature'' redoubled its efforts in ...
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Neutron
The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behave similarly within the nucleus, and each has a mass of approximately one atomic mass unit, they are both referred to as nucleons. Their properties and interactions are described by nuclear physics. Protons and neutrons are not elementary particles; each is composed of three quarks. The chemical properties of an atom are mostly determined by the configuration of electrons that orbit the atom's heavy nucleus. The electron configuration is determined by the charge of the nucleus, which is determined by the number of protons, or atomic number. The number of neutrons is the neutron number. Neutrons do not affect the electron configuration, but the sum of atomic and neutron numbers is the mass of the nucleus. Atoms of a chemical element t ...
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James Chadwick
Sir James Chadwick, (20 October 1891 – 24 July 1974) was an English physicist who was awarded the 1935 Nobel Prize in Physics for his discovery of the neutron in 1932. In 1941, he wrote the final draft of the MAUD Report, which inspired the U.S. government to begin serious atom bomb research efforts. He was the head of the British team that worked on the Manhattan Project during World War II. He was knighted in Britain in 1945 for his achievements in physics. Chadwick graduated from the Victoria University of Manchester in 1911, where he studied under Ernest Rutherford (known as the "father of nuclear physics"). At Manchester, he continued to study under Rutherford until he was awarded his MSc in 1913. The same year, Chadwick was awarded an 1851 Research Fellowship from the Royal Commission for the Exhibition of 1851. He elected to study beta radiation under Hans Geiger in Berlin. Using Geiger's recently developed Geiger counter, Chadwick was able to demonst ...
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Atomic Mass
The atomic mass (''m''a or ''m'') is the mass of an atom. Although the SI unit of mass is the kilogram (symbol: kg), atomic mass is often expressed in the non-SI unit dalton (symbol: Da) – equivalently, unified atomic mass unit (u). 1 Da is defined as of the mass of a free carbon-12 atom at rest in its ground state. The protons and neutrons of the nucleus account for nearly all of the total mass of atoms, with the electrons and nuclear binding energy making minor contributions. Thus, the numeric value of the atomic mass when expressed in daltons has nearly the same value as the mass number. Conversion between mass in kilograms and mass in daltons can be done using the atomic mass constant m_= = 1\ \rm . The formula used for conversion is: :1\ = m_ = 1.660\ 539\ 066\ 60(50)\times 10^\ \mathrm , where M_ is the molar mass constant, N_ is the Avogadro constant, and M(^\mathrm) is the experimentally determined molar mass of carbon-12. The relative isotopic mass ...
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Atomic Number
The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of an atomic nucleus. For ordinary nuclei, this is equal to the proton number (''n''p) or the number of protons found in the nucleus of every atom of that element. The atomic number can be used to uniquely identify ordinary chemical elements. In an ordinary uncharged atom, the atomic number is also equal to the number of electrons. For an ordinary atom, the sum of the atomic number ''Z'' and the neutron number ''N'' gives the atom's atomic mass number ''A''. Since protons and neutrons have approximately the same mass (and the mass of the electrons is negligible for many purposes) and the mass defect of the nucleon binding is always small compared to the nucleon mass, the atomic mass of any atom, when expressed in unified atomic mass units (making a quantity called the " relative isotopic mass"), is within 1% of the whole number ''A''. Atoms with the same atomic number b ...
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Groves And Chadwick 830308
Groves may refer to: __NOTOC__ Places * The Groves, an area of York, England * Groves, Texas, U.S., a city * Groves High School (other), several schools * Groves Stadium, home of BB&T Field, an American football venue in Winston-Salem, North Carolina Ships * USS ''Groves'' (DE-543), a U.S. Navy destroyer escort cancelled during construction in 1944 * USS ''Stephen W. Groves'' (FFG-29), a U.S. Navy guided-missile frigate in commission since 1982 Other uses * The Groves family, a prominent British theatre family dating back to the Regency era. * Groves (surname), including a list of people with the surname * ''Grove's Dictionary of Music and Musicians ''The New Grove Dictionary of Music and Musicians'' is an encyclopedic dictionary of music and musicians. Along with the German-language ''Die Musik in Geschichte und Gegenwart'', it is one of the largest reference works on the history and theo ...'', an earlier version of ''The New Grove Dictionary of Music and Mu ...
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