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Van Hove Singularity
A Van Hove singularity is a singularity (non-smooth point) in the density of states (DOS) of a crystalline solid. The wavevectors at which Van Hove singularities occur are often referred to as critical points of the Brillouin zone. For three-dimensional crystals, they take the form of kinks (where the density of states is not differentiable). The most common application of the Van Hove singularity concept comes in the analysis of optical absorption spectra. The occurrence of such singularities was first analyzed by the Belgian physicist Léon Van Hove in 1953 for the case of phonon densities of states. Theory Consider a one-dimensional lattice of ''N'' particle sites, with each particle site separated by distance ''a'', for a total length of ''L'' = ''Na''. Instead of assuming that the waves in this one-dimensional box are standing waves, it is more convenient to adopt periodic boundary conditions: :k=\frac=n\frac where \lambda is wavelength, and ''n'' is an integer. (Positive ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Singularity (mathematics)
In mathematics, a singularity is a point at which a given mathematical object is not defined, or a point where the mathematical object ceases to be well-behaved in some particular way, such as by lacking differentiability or analyticity. For example, the real function : f(x) = \frac has a singularity at x = 0, where the numerical value of the function approaches \pm\infty so the function is not defined. The absolute value function g(x) = , x, also has a singularity at x = 0, since it is not differentiable there. The algebraic curve defined by \left\ in the (x, y) coordinate system has a singularity (called a cusp) at (0, 0). For singularities in algebraic geometry, see singular point of an algebraic variety. For singularities in differential geometry, see singularity theory. Real analysis In real analysis, singularities are either discontinuities, or discontinuities of the derivative (sometimes also discontinuities of higher order derivatives). There are four kinds of discon ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Local Maximum
In mathematical analysis, the maxima and minima (the respective plurals of maximum and minimum) of a function, known collectively as extrema (the plural of extremum), are the largest and smallest value of the function, either within a given range (the ''local'' or ''relative'' extrema), or on the entire domain (the ''global'' or ''absolute'' extrema). Pierre de Fermat was one of the first mathematicians to propose a general technique, adequality, for finding the maxima and minima of functions. As defined in set theory, the maximum and minimum of a set are the greatest and least elements in the set, respectively. Unbounded infinite sets, such as the set of real numbers, have no minimum or maximum. Definition A real-valued function ''f'' defined on a domain ''X'' has a global (or absolute) maximum point at ''x''∗, if for all ''x'' in ''X''. Similarly, the function has a global (or absolute) minimum point at ''x''∗, if for all ''x'' in ''X''. The value of the function at a m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Optical Properties Of Carbon Nanotubes
The optical properties of carbon nanotubes are highly relevant for materials science. The way those materials interact with electromagnetic radiation is unique in many respects, as evidenced by their peculiar absorption, photoluminescence (fluorescence), and Raman spectra. Carbon nanotubes are unique "one-dimensional" materials, whose hollow fibers (tubes) have a unique and highly ordered atomic and electronic structure, and can be made in a wide range of dimension. The diameter typically varies from 0.4 to 40 nm (i.e., a range of ~100 times). However, the length can reach , implying a length-to-diameter ratio as high as 132,000,000:1; which is unequaled by any other material. Consequently, all the electronic, optical, electrochemical and mechanical properties of the carbon nanotubes are extremely anisotropic (directionally dependent) and tunable. Applications of carbon nanotubes in optics and photonics are still less developed than in other fields. Some properties that ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bechgaard Salt
In organic chemistry, a Bechgaard salt is any one of a number of organic charge-transfer complexes that exhibit superconductivity at low temperatures. They are named for chemist Klaus Bechgaard, who was one of the first scientists to synthesize them and demonstrate their superconductivity with the help of physicist Denis Jérome. Most Bechgaard salt superconductors are extremely low temperature, and lose superconductivity above the 1–2 K range, although the most successful compound in this class superconducts up to almost 12 K. All Bechgaard salts are formed using a small, planar organic molecule as an electron donor, with any of a number of electron acceptors (such as perchlorate, , or tetracyanoethylene, TCNE). All the organic electron donors contain multiply conjugated heterocycles with a number of properties, including planarity, low ionization potential and good orbital overlap between heteroatoms in neighboring donor molecules. These properties help the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Momentum
In Newtonian mechanics, momentum (more specifically linear momentum or translational momentum) is the product of the mass and velocity of an object. It is a vector quantity, possessing a magnitude and a direction. If is an object's mass and is its velocity (also a vector quantity), then the object's momentum is : \mathbf = m \mathbf. In the International System of Units (SI), the unit of measurement of momentum is the kilogram metre per second (kg⋅m/s), which is equivalent to the newton-second. Newton's second law of motion states that the rate of change of a body's momentum is equal to the net force acting on it. Momentum depends on the frame of reference, but in any inertial frame it is a ''conserved'' quantity, meaning that if a closed system is not affected by external forces, its total linear momentum does not change. Momentum is also conserved in special relativity (with a modified formula) and, in a modified form, in electrodynamics, quantum mechanics, quan ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vector Potential
In vector calculus, a vector potential is a vector field whose curl is a given vector field. This is analogous to a ''scalar potential'', which is a scalar field whose gradient is a given vector field. Formally, given a vector field v, a ''vector potential'' is a C^2 vector field A such that \mathbf = \nabla \times \mathbf. Consequence If a vector field v admits a vector potential A, then from the equality \nabla \cdot (\nabla \times \mathbf) = 0 (divergence of the curl is zero) one obtains \nabla \cdot \mathbf = \nabla \cdot (\nabla \times \mathbf) = 0, which implies that v must be a solenoidal vector field. Theorem Let \mathbf : \R^3 \to \R^3 be a solenoidal vector field which is twice continuously differentiable. Assume that decreases at least as fast as 1/\, \mathbf\, for \, \mathbf\, \to \infty . Define \mathbf (\mathbf) = \frac \int_ \frac \, d^3\mathbf. Then, A is a vector potential for , that is, \nabla \times \mathbf =\mathbf. Here, \nabla_y \times ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dipole Operator
In physics, a dipole () is an electromagnetic phenomenon which occurs in two ways: *An electric dipole deals with the separation of the positive and negative electric charges found in any electromagnetic system. A simple example of this system is a pair of charges of equal magnitude but opposite sign separated by some typically small distance. (A permanent electric dipole is called an electret.) *A magnetic dipole is the closed circulation of an electric current system. A simple example is a single loop of wire with constant current through it. A bar magnet is an example of a magnet with a permanent magnetic dipole moment. Dipoles, whether electric or magnetic, can be characterized by their dipole moment, a vector quantity. For the simple electric dipole, the electric dipole moment points from the negative charge towards the positive charge, and has a magnitude equal to the strength of each charge times the separation between the charges. (To be precise: for the definition of the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perturbation Theory (quantum Mechanics)
In quantum mechanics, perturbation theory is a set of approximation schemes directly related to mathematical perturbation for describing a complicated quantum system in terms of a simpler one. The idea is to start with a simple system for which a mathematical solution is known, and add an additional "perturbing" Hamiltonian representing a weak disturbance to the system. If the disturbance is not too large, the various physical quantities associated with the perturbed system (e.g. its energy levels and eigenstates) can be expressed as "corrections" to those of the simple system. These corrections, being small compared to the size of the quantities themselves, can be calculated using approximate methods such as asymptotic series. The complicated system can therefore be studied based on knowledge of the simpler one. In effect, it is describing a complicated unsolved system using a simple, solvable system. Approximate Hamiltonians Perturbation theory is an important tool for de ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fermi's Golden Rule
In quantum physics, Fermi's golden rule is a formula that describes the transition rate (the probability of a transition per unit time) from one energy eigenstate of a quantum system to a group of energy eigenstates in a continuum, as a result of a weak perturbation. This transition rate is effectively independent of time (so long as the strength of the perturbation is independent of time) and is proportional to the strength of the coupling between the initial and final states of the system (described by the square of the matrix element of the perturbation) as well as the density of states. It is also applicable when the final state is discrete, i.e. it is not part of a continuum, if there is some decoherence in the process, like relaxation or collision of the atoms, or like noise in the perturbation, in which case the density of states is replaced by the reciprocal of the decoherence bandwidth. General Although the rule is named after Enrico Fermi, most of the work leading to it ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electronic Band Structure
In solid-state physics, the electronic band structure (or simply band structure) of a solid describes the range of energy levels that electrons may have within it, as well as the ranges of energy that they may not have (called ''band gaps'' or ''forbidden bands''). Band theory derives these bands and band gaps by examining the allowed quantum mechanical wave functions for an electron in a large, periodic lattice of atoms or molecules. Band theory has been successfully used to explain many physical properties of solids, such as electrical resistivity and optical absorption, and forms the foundation of the understanding of all solid-state devices (transistors, solar cells, etc.). Why bands and band gaps occur The electrons of a single, isolated atom occupy atomic orbitals each of which has a discrete energy level. When two or more atoms join together to form a molecule, their atomic orbitals overlap and hybridize. Similarly, if a large number ''N'' of identical atoms come ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fermi Surface
In condensed matter physics, the Fermi surface is the surface in reciprocal space which separates occupied from unoccupied electron states at zero temperature. The shape of the Fermi surface is derived from the periodicity and symmetry of the crystalline lattice and from the occupation of electronic energy bands. The existence of a Fermi surface is a direct consequence of the Pauli exclusion principle, which allows a maximum of one electron per quantum state. The study of the Fermi surfaces of materials is called fermiology. Theory Consider a spin-less ideal Fermi gas of N particles. According to Fermi–Dirac statistics, the mean occupation number of a state with energy \epsilon_i is given by :\langle n_i\rangle =\frac, where, *\left\langle n_i\right\rangle is the mean occupation number of the i^ state *\epsilon_i is the kinetic energy of the i^ state *\mu is the chemical potential (at zero temperature, this is the maximum kinetic energy the particle can have, i.e. Fermi ene ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
