Vinylester
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Vinylester
Vinyl ester resin, or often just vinyl ester, is a resin produced by the esterification of an epoxy resin with acrylic or methacrylic acids. The "vinyl" groups refer to these ester substituents, which are prone to polymerize and thus an inhibitor is usually added. The diester product is then dissolved in a reactive solvent, such as styrene, to approximately 35–45 percent content by weight. Polymerization is initiated by free radicals, which are generated by UV-irradiation or peroxides. 352px, Bis-GMA a typical "vinyl ester" derived from bisphenol A diglycidyl ether. This thermosetting polymer, thermoset material can be used as an alternative to polyester and epoxy materials as the thermoset polymer matrix in composite materials, where its characteristics, strengths, and bulk cost are intermediate between polyester and epoxy. Vinyl ester has lower resin viscosity (approx. 200 cps) than polyester (approx. 500cps) and epoxy (approx. 900cps). Uses In homebuilt airplanes, the Glas ...
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Epoxy
Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also collectively called ''epoxy''. The IUPAC name for an epoxide group is an oxirane. Epoxy resins may be reacted (cross-linked) either with themselves through catalytic homopolymerisation, or with a wide range of co-reactants including polyfunctional amines, acids (and acid anhydrides), phenols, alcohols and thiols (usually called mercaptans). These co-reactants are often referred to as hardeners or curatives, and the cross-linking reaction is commonly referred to as curing. Reaction of polyepoxides with themselves or with polyfunctional hardeners forms a thermosetting polymer, often with favorable mechanical properties and high thermal and chemical resistance. Epoxy has a wide range of applications, including metal coatings, composites, use in ...
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Glastar
The Glasair GlaStar (sometimes Glastar) is an American amateur-built aircraft that was designed by Tom Hamilton and produced by Stoddard-Hamilton Aircraft and later Glasair Aviation. It was first flown in 1994 and was superseded in production by the Glasair Sportsman 2+2 c. 2005. When it was available the aircraft was supplied as a kit for amateur construction.Bertrand, Noel; Rene Coulon; et al: ''World Directory of Leisure Aviation 2003-04'', page 183. Pagefast Ltd, Lancaster UK, 2003. ISSN 1368-485XDowney, Julia: ''1999 Kit Aircraft Directory'', Kitplanes, Volume 15, Number 12, December 1998, page 68. Primedia Publications. ISSN 0891-1851Purdy, Don: ''AeroCrafter - Homebuilt Aircraft Sourcebook'', page 262. BAI Communications. Design and development The GlaStar features a strut-braced high-wing, a two-seats-in-side-by-side configuration enclosed cockpit accessed via doors, fixed tricycle landing gear or conventional landing gear and a single engine in tractor configuration. ...
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Plastics
Plastics are a wide range of synthetic polymers, synthetic or semi-synthetic materials that use polymers as a main ingredient. Their Plasticity (physics), plasticity makes it possible for plastics to be Injection moulding, moulded, Extrusion, extruded or Compression molding, pressed into solid objects of various shapes. This adaptability, plus a wide range of other properties, such as being lightweight, durable, flexible, and inexpensive to produce, has led to its widespread use. Plastics typically are made through human industrial systems. Most modern plastics are derived from petrochemical, fossil fuel-based chemicals like natural gas or petroleum; however, recent industrial methods use variants made from renewable materials, such as corn or cotton derivatives. 9.2 billion tonnes of plastic are estimated to have been made between 1950 and 2017. More than half this plastic has been produced since 2004. In 2020, 400 million tonnes of plastic were produced. If global trends on pl ...
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Epichlorohydrin
Epichlorohydrin (abbreviated ECH) is an organochlorine compound and an epoxide. Despite its name, it is not a halohydrin. It is a colorless liquid with a pungent, garlic-like odor, moderately soluble in water, but miscible with most polar organic solvents. It is a chiral molecule generally existing as a racemic mixture of right-handed and left-handed enantiomers. Epichlorohydrin is a highly reactive electrophilic compound and is used in the production of glycerol, plastics, epoxy glues and resins, epoxy diluents and elastomers. Production Epichlorohydrin is traditionally manufactured from allyl chloride in two steps, beginning with the addition of hypochlorous acid, which affords a mixture of two isomeric alcohols: : In the second step, this mixture is treated with base to give the epoxide: : In this way, more than 800,000 tons (1997) of epichlorohydrin are produced annually. Glycerol routes Epichlorohydrin was first described in 1848 by Marcellin Berthelot. The comp ...
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Polycarbonate
Polycarbonates (PC) are a group of thermoplastic polymers containing carbonate groups in their chemical structures. Polycarbonates used in engineering are strong, tough materials, and some grades are optically transparent. They are easily worked, molded, and thermoformed. Because of these properties, polycarbonates find many applications. Polycarbonates do not have a unique resin identification code (RIC) and are identified as "Other", 7 on the RIC list. Products made from polycarbonate can contain the precursor monomer bisphenol A (BPA). Structure Carbonate esters have planar OC(OC)2 cores, which confers rigidity. The unique O=C bond is short (1.173 Å in the depicted example), while the C-O bonds are more ether-like (the bond distances of 1.326 Å for the example depicted). Polycarbonates received their name because they are polymers containing carbonate groups (−O−(C=O)−O−). A balance of useful features, including temperature resistance, impact resistance and o ...
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Resin
In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on naturally occurring resins. Plants secrete resins for their protective benefits in response to injury. The resin protects the plant from insects and pathogens. Resins confound a wide range of herbivores, insects, and pathogens, while the volatile phenolic compounds may attract benefactors such as parasitoids or predators of the herbivores that attack the plant. Composition Most plant resins are composed of terpenes. Specific components are alpha-pinene, beta-pinene, delta-3 carene, and sabinene, the monocyclic terpenes limonene and terpinolene, and smaller amounts of the tricyclic sesquiterpenes, longifolene, caryophyllene, and delta-cadinene. Some resins also contain a high proportion of resin acids. Rosins on the other hand are less ...
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Bisphenol A
Bisphenol A (BPA) is a chemical compound primarily used in the manufacturing of various plastics. It is a colourless solid which is soluble in most common organic solvents, but has very poor solubility in water. BPA is produced on an industrial scale by the condensation of phenol and acetone, and has a global production scale which is expected to reach 10 million tonnes in 2022. BPA's largest single application is as a co-monomer in the production of polycarbonates, which accounts for 65–70% of all BPA production. The manufacturing of epoxy resins and vinyl ester resins account for 25–30% of BPA use. The remaining 5% is used as a major component of several high-performance plastics, and as a minor additive in PVC, polyurethane, thermal paper, and several other materials. It is not a plasticizer, although it is often wrongly labelled as such. The health effects of BPA have been the subject of prolonged public and scientific debate. BPA is a xenoestrogen, exhibiting hormone ...
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BS4994
BS4994 (formally: British Standard 4994:1987) is the "specification for the design and construction of vessels and storage tanks in reinforced plastics". It specifies a code of practice for use by manufacturers of such containers. With the publication of BS EN 13121-3, BS 4994:1987 Specification for design and construction of vessels and tanks in reinforced plastics is declared obsolescent, which will still cover those tanks still in service as tanks made from GRP are generally accepted to have a long working life. Dual laminate construction, simple FRP with glass mats, or a combination of unidirectional filament winding are common. DUAL LAMINATE : A thermoplastic lining material, preferably 3mm to 5mm thick sheet functions as a corrosion barrier. This thermoplastic liner is not considered to contribute mechanical strength. FRP which is constructed over this lining provides the strength requirements for materials to withstand design conditions like pressure, vacuum, hydrostatic loa ...
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FRP Tanks And Vessels
FRP ( Fibreglass Reinforced Plastics, also known as GRP, or Glass Reinforced Plastics) is a modern composite material of construction for chemical plant equipment like tanks and vessels. Chemical equipment that range in size from less than a metre to 20 metres are fabricated using FRP as material of construction. FRP Chemical Equipments are manufactured mainly by Hand Lay-up and filament winding processes. BS4994 still remains a key standard for this class of items. Dual Laminate Due to the corrosion resistant nature of FRP, the tank can be made entirely from the composite, or a second liner can be used. In either case, the inner liner is made using different material properties than the structural portion (Hence the name dual (meaning two) and laminate (a word commonly used for a layer of a composite material)) The liner, if made of FRP is usually resin rich and utilizes a different type of glass, called "C-Glass", while the structural portion uses "E-Glass". The thermoplasti ...
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Fiberglass
Fiberglass (American English) or fibreglass (Commonwealth English) is a common type of fiber-reinforced plastic using glass fiber. The fibers may be randomly arranged, flattened into a sheet called a chopped strand mat, or woven into glass cloth. The plastic matrix may be a thermoset polymer matrix—most often based on thermosetting polymers such as epoxy, polyester resin, or vinyl ester resin—or a thermoplastic. Cheaper and more flexible than carbon fiber, it is stronger than many metals by weight, non- magnetic, non-conductive, transparent to electromagnetic radiation, can be molded into complex shapes, and is chemically inert under many circumstances. Applications include aircraft, boats, automobiles, bath tubs and enclosures, swimming pools, hot tubs, septic tanks, water tanks, roofing, pipes, cladding, orthopedic casts, surfboards, and external door skins. Other common names for fiberglass are glass-reinforced plastic (GRP), glass-fiber reinforced plastic (GFRP) or GF ...
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Glasair
Glasair Aviation USA, LLC is a Chinese-owned aircraft manufacturer based in Arlington, Washington that produces the Glasair and Sportsman 2+2 line of homebuilt aircraft. More than 3000 Glasair kits have been delivered worldwide. History Tom Hamilton began flight testing the Glasair TD and founded Stoddard-Hamilton Aircraft in 1979. Glasair Aviation was formed in 2001 when Thomas W. Wathen purchased the Glasair assets from bankrupt Stoddard-Hamilton Aircraft, Inc. and signed an agreement with Arlington Aircraft Development, Inc. (AADI) to buy all rights to and assets of the GlaStar model. In July 2012 the company was sold to the Jilin Hanxing Group, which formed a new company Glasair Aircraft USA, LLC. The company indicated that it intended to certify the Glastar design and otherwise retain production in Arlington, Washington. Its chairman said that purchasing Glasair was "the first step in a very long journey" and envisioned the company producing trainers for flight schools ...
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Acrylic Acid
Acrylic acid (IUPAC: propenoic acid) is an organic compound with the formula CH2=CHCOOH. It is the simplest unsaturated carboxylic acid, consisting of a vinyl group connected directly to a carboxylic acid terminus. This colorless liquid has a characteristic acrid or tart smell. It is miscible with water, alcohols, ethers, and chloroform. More than a million tons are produced annually. History The word "acrylic" was coined in 1843, for a chemical derivative of acrolein, an acrid-smelling oil derived from glycerol. Production Acrylic acid is produced by oxidation of propylene, which is a byproduct of the production of ethylene and gasoline: : 2 CH2=CHCH3 + 3 O2 → 2 CH2=CHCO2H + 2 H2O Historical methods Because acrylic acid and its esters have long been valued commercially, many other methods have been developed. Most have been abandoned for economic or environmental reasons. An early method was the hydrocarboxylation of acetylene (" Reppe chemistry"): : This method re ...
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