Triple Product Rule
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Triple Product Rule
The triple product rule, known variously as the cyclic chain rule, cyclic relation, cyclical rule or Euler's chain rule, is a formula which relates partial derivatives of three interdependent variables. The rule finds application in thermodynamics, where frequently three variables can be related by a function of the form ''f''(''x'', ''y'', ''z'') = 0, so each variable is given as an implicit function of the other two variables. For example, an equation of state for a fluid relates temperature, pressure, and volume in this manner. The triple product rule for such interrelated variables ''x'', ''y'', and ''z'' comes from using a reciprocity relation on the result of the implicit function theorem, and is given by :\left(\frac\right)\left(\frac\right)\left(\frac\right) = -1, where each factor is a partial derivative of the variable in the numerator, considered to be a function of the other two. The advantage of the triple product rule is that by rearranging terms, one can deri ...
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Partial Derivative
In mathematics, a partial derivative of a function of several variables is its derivative with respect to one of those variables, with the others held constant (as opposed to the total derivative, in which all variables are allowed to vary). Partial derivatives are used in vector calculus and differential geometry. The partial derivative of a function f(x, y, \dots) with respect to the variable x is variously denoted by It can be thought of as the rate of change of the function in the x-direction. Sometimes, for z=f(x, y, \ldots), the partial derivative of z with respect to x is denoted as \tfrac. Since a partial derivative generally has the same arguments as the original function, its functional dependence is sometimes explicitly signified by the notation, such as in: :f'_x(x, y, \ldots), \frac (x, y, \ldots). The symbol used to denote partial derivatives is ∂. One of the first known uses of this symbol in mathematics is by Marquis de Condorcet from 1770, who used it for ...
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Mathematical Analysis
Analysis is the branch of mathematics dealing with continuous functions, limit (mathematics), limits, and related theories, such as Derivative, differentiation, Integral, integration, measure (mathematics), measure, infinite sequences, series (mathematics), series, and analytic functions. These theories are usually studied in the context of Real number, real and Complex number, complex numbers and Function (mathematics), functions. Analysis evolved from calculus, which involves the elementary concepts and techniques of analysis. Analysis may be distinguished from geometry; however, it can be applied to any Space (mathematics), space of mathematical objects that has a definition of nearness (a topological space) or specific distances between objects (a metric space). History Ancient Mathematical analysis formally developed in the 17th century during the Scientific Revolution, but many of its ideas can be traced back to earlier mathematicians. Early results in analysis were i ...
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Multivariable Calculus
Multivariable calculus (also known as multivariate calculus) is the extension of calculus in one variable to calculus with functions of several variables: the differentiation and integration of functions involving several variables, rather than just one. Multivariable calculus may be thought of as an elementary part of advanced calculus. For advanced calculus, see calculus on Euclidean space. The special case of calculus in three dimensional space is often called vector calculus. Typical operations Limits and continuity A study of limits and continuity in multivariable calculus yields many counterintuitive results not demonstrated by single-variable functions. For example, there are scalar functions of two variables with points in their domain which give different limits when approached along different paths. E.g., the function. :f(x,y) = \frac approaches zero whenever the point (0,0) is approached along lines through the origin (y=kx). However, when the origin is appr ...
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Laws Of Thermodynamics
The laws of thermodynamics are a set of scientific laws which define a group of physical quantities, such as temperature, energy, and entropy, that characterize thermodynamic systems in thermodynamic equilibrium. The laws also use various parameters for thermodynamic processes, such as thermodynamic work and heat, and establish relationships between them. They state empirical facts that form a basis of precluding the possibility of certain phenomena, such as perpetual motion. In addition to their use in thermodynamics, they are important fundamental laws of physics in general, and are applicable in other natural sciences. Traditionally, thermodynamics has recognized three fundamental laws, simply named by an ordinal identification, the first law, the second law, and the third law.Guggenheim, E.A. (1985). ''Thermodynamics. An Advanced Treatment for Chemists and Physicists'', seventh edition, North Holland, Amsterdam, .Kittel, C. Kroemer, H. (1980). ''Thermal Physics'', second edit ...
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Articles Containing Proofs
Article often refers to: * Article (grammar), a grammatical element used to indicate definiteness or indefiniteness * Article (publishing), a piece of nonfictional prose that is an independent part of a publication Article may also refer to: Government and law * Article (European Union), articles of treaties of the European Union * Articles of association, the regulations governing a company, used in India, the UK and other countries * Articles of clerkship, the contract accepted to become an articled clerk * Articles of Confederation, the predecessor to the current United States Constitution *Article of Impeachment, a formal document and charge used for impeachment in the United States * Articles of incorporation, for corporations, U.S. equivalent of articles of association * Articles of organization, for limited liability organizations, a U.S. equivalent of articles of association Other uses * Article, an HTML element, delimited by the tags and * Article of clothing, an ite ...
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Phase Velocity
The phase velocity of a wave is the rate at which the wave propagates in any medium. This is the velocity at which the phase of any one frequency component of the wave travels. For such a component, any given phase of the wave (for example, the crest) will appear to travel at the phase velocity. The phase velocity is given in terms of the wavelength (lambda) and time period as :v_\mathrm = \frac. Equivalently, in terms of the wave's angular frequency , which specifies angular change per unit of time, and wavenumber (or angular wave number) , which represent the angular change per unit of space, :v_\mathrm = \frac. To gain some basic intuition for this equation, we consider a propagating (cosine) wave . We want to see how fast a particular phase of the wave travels. For example, we can choose , the phase of the first crest. This implies , and so . Formally, we let the phase and see immediately that and . So, it immediately follows that : \frac = -\frac \frac = \frac ...
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State Variables
A state variable is one of the set of variables that are used to describe the mathematical "state" of a dynamical system. Intuitively, the state of a system describes enough about the system to determine its future behaviour in the absence of any external forces affecting the system. Models that consist of coupled first-order differential equations are said to be in state-variable form. Examples *In mechanical systems, the position coordinates and velocities of mechanical parts are typical state variables; knowing these, it is possible to determine the future state of the objects in the system. *In thermodynamics, a state variable is an independent variable of a state function. Examples include internal energy, enthalpy, temperature, pressure, volume and entropy. Heat and work are not state functions, but process functions. *In electronic/electrical circuits, the voltages of the nodes and the currents through components in the circuit are usually the state variables. In any e ...
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Ideal Gas Law
The ideal gas law, also called the general gas equation, is the equation of state of a hypothetical ideal gas. It is a good approximation of the behavior of many gases under many conditions, although it has several limitations. It was first stated by Benoît Paul Émile Clapeyron in 1834 as a combination of the empirical Boyle's law, Charles's law, Avogadro's law, and Gay-Lussac's law. The ideal gas law is often written in an empirical form: pV = nRT where p, V and T are the pressure, volume and temperature; n is the amount of substance; and R is the ideal gas constant. It can also be derived from the microscopic kinetic theory, as was achieved (apparently independently) by August Krönig in 1856 and Rudolf Clausius in 1857. Equation The state of an amount of gas is determined by its pressure, volume, and temperature. The modern form of the equation relates these simply in two main forms. The temperature used in the equation of state is an absolute temperature: the appropria ...
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Chain Rule
In calculus, the chain rule is a formula that expresses the derivative of the composition of two differentiable functions and in terms of the derivatives of and . More precisely, if h=f\circ g is the function such that h(x)=f(g(x)) for every , then the chain rule is, in Lagrange's notation, :h'(x) = f'(g(x)) g'(x). or, equivalently, :h'=(f\circ g)'=(f'\circ g)\cdot g'. The chain rule may also be expressed in Leibniz's notation. If a variable depends on the variable , which itself depends on the variable (that is, and are dependent variables), then depends on as well, via the intermediate variable . In this case, the chain rule is expressed as :\frac = \frac \cdot \frac, and : \left.\frac\_ = \left.\frac\_ \cdot \left. \frac\_ , for indicating at which points the derivatives have to be evaluated. In integration, the counterpart to the chain rule is the substitution rule. Intuitive explanation Intuitively, the chain rule states that knowing the instantaneous rate of cha ...
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Exact Differential
In multivariate calculus, a differential or differential form is said to be exact or perfect (''exact differential''), as contrasted with an inexact differential, if it is equal to the general differential dQ for some differentiable function Q in an orthogonal coordinate system. An exact differential is sometimes also called a ''total differential'', or a ''full differential'', or, in the study of differential geometry, it is termed an exact form. The integral of an exact differential over any integral path is path-independent, and this fact is used to identify state functions in thermodynamics. Overview Definition Even if we work in three dimensions here, the definitions of exact differentials for other dimensions are structurally similar to the three dimensional definition. In three dimensions, a form of the type :A(x,y,z) \,dx + B(x,y,z) \,dy + C(x,y,z) \,dz is called a differential form. This form is called ''exact'' on an open domain D \subset \mathbb^3 in spac ...
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Neighbourhood (mathematics)
In topology and related areas of mathematics, a neighbourhood (or neighborhood) is one of the basic concepts in a topological space. It is closely related to the concepts of open set and interior. Intuitively speaking, a neighbourhood of a point is a set of points containing that point where one can move some amount in any direction away from that point without leaving the set. Definitions Neighbourhood of a point If X is a topological space and p is a point in X, then a of p is a subset V of X that includes an open set U containing p, p \in U \subseteq V \subseteq X. This is also equivalent to the point p \in X belonging to the topological interior of V in X. The neighbourhood V need be an open subset X, but when V is open in X then it is called an . Some authors have been known to require neighbourhoods to be open, so it is important to note conventions. A set that is a neighbourhood of each of its points is open since it can be expressed as the union of open sets ...
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