Thermate
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Thermate
Thermate is a variation of thermite and is an incendiary pyrotechnic composition that can generate short bursts of very high temperatures focused on a small area for a short period of time. It is used primarily in incendiary grenades. The main chemical reaction in thermate is the same as in thermite: an aluminothermic reaction between powdered aluminium and a metal oxide. Thermate can also utilize magnesium or other similar elements in place of aluminium. In addition to thermite, thermate sometimes contains sulfur and sometimes barium nitrate, both of which increase its thermal effect, create flame in burning, and significantly reduce the ignition temperature. Various mixtures of these compounds can be called thermate, but to avoid confusion with thermate-TH3, one can refer to them as thermite variants or analogs. The composition by weight of Thermate-TH3 (in military use) is 68.7% thermite, 29.0% barium nitrate, 2.0% sulfur and 0.3% binder (such as polybutadiene acrylonitril ...
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Thermite
Thermite () is a pyrotechnic composition of metal powder and metal oxide. When ignited by heat or chemical reaction, thermite undergoes an exothermic reduction-oxidation (redox) reaction. Most varieties are not explosive, but can create brief bursts of heat and high temperature in a small area. Its form of action is similar to that of other fuel-oxidizer mixtures, such as black powder. Thermites have diverse compositions. Fuels include aluminum, magnesium, titanium, zinc, silicon, and boron. Aluminum is common because of its high boiling point and low cost. Oxidizers include bismuth(III) oxide, boron(III) oxide, silicon(IV) oxide, chromium(III) oxide, manganese(IV) oxide, iron(III) oxide, iron(II,III) oxide, copper(II) oxide, and lead(II,IV) oxide. The reaction, also called the Goldschmidt process, is used for thermite welding, often used to join railway tracks. Thermites have also been used in metal refining, disabling munitions, and in incendiary weapons. Some thermite-like ...
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Incendiary Ammunition
Incendiary ammunition is a type of ammunition that contains a chemical that, upon hitting a hard obstacle, has the characteristic of causing fire/setting flammable materials in the vincinity of the impact on fire. World War I The first time incendiary ammunition was widely used was in World War I, more specifically in 1916. At the time, phosphorus was the primary ingredient in the incendiary charge and ignited upon firing, leaving a trail of blue smoke. These early forms were also known as "smoke tracers" because of this. Though deadly, the effective range of these bullets was only 350 yards (320 m), as the phosphorus charge burned quickly. Incendiary bullets called "Buckingham" ammunition were supplied to early British night fighters for use against military zeppelins threatening the British Isles. The flammable hydrogen gas of the zeppelins made incendiary bullets much more deadly than standard ones which would pass through the outer skin without igniting the gas. Similar ...
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Pyrotechnic Composition
A pyrotechnic composition is a substance or mixture of substances designed to produce an effect by heat, light, sound, gas/smoke or a combination of these, as a result of non-detonative self-sustaining exothermic reaction, exothermic chemical reactions. Pyrotechnic substances do not rely on oxygen from external sources to sustain the reaction. Types Basic types of pyrotechnic compositions are: * flash powder – burns very fast, produces explosions and/or bright flashes of light * gunpowder – burns slower than flash powder, produces large amount of gases * solid propellants – produce large amount of hot gases, used as sources of kinetic energy for rockets and projectiles * pyrotechnic initiators – produce large amount of heat, flames, and/or hot sparks, used to ignite other compositions * gas generators – produce large amount of gas, either high volume at short time (for actuators and ejection charges, often using solid propellants) or controlled flow rate (e.g. chemical ...
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Grenade
A grenade is an explosive weapon typically thrown by hand (also called hand grenade), but can also refer to a shell (explosive projectile) shot from the muzzle of a rifle (as a rifle grenade) or a grenade launcher. A modern hand grenade generally consists of an explosive charge ("filler"), a detonator mechanism, an internal striker to trigger the detonator, and a safety lever secured by a cotter pin. The user removes the safety pin before throwing, and once the grenade leaves the hand the safety lever gets released, allowing the striker to trigger a primer that ignites a fuze (sometimes called the delay element), which burns down to the detonator and explodes the main charge. Grenades work by dispersing fragments (fragmentation grenades), shockwaves (high-explosive, anti-tank and stun grenades), chemical aerosols (smoke and gas grenades) or fire ( incendiary grenades). Fragmentation grenades ("frags") are probably the most common in modern armies, and when the word ''gren ...
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Aluminothermic Reaction
Aluminothermic reactions are exothermic chemical reactions using aluminum as the reducing agent at high temperature. The process is industrially useful for production of alloys of iron. The most prominent example is the thermite reaction between iron oxides and aluminum to produce iron itself: : Fe2O3 + 2 Al → 2 Fe + Al2O3 This specific reaction is however not relevant to the most important application of aluminothermic reactions, the production of ferroalloys. For the production of iron, a cheaper reducing agent, coke, is used instead via the carbothermic reaction. History Aluminothermy started from the experiments of Russian scientist Nikolay Beketov at the University of Kharkiv in Ukraine, who proved that aluminum restored metals from their oxides under high temperatures. The reaction was first used for the carbon-free reduction of metal oxides. The reaction is highly exothermic, but it has a high activation energy since strong interatomic bonds in the solids m ...
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Aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has a great affinity towards oxygen, and forms a protective layer of oxide on the surface when exposed to air. Aluminium visually resembles silver, both in its color and in its great ability to reflect light. It is soft, non-magnetic and ductile. It has one stable isotope, 27Al; this isotope is very common, making aluminium the twelfth most common element in the Universe. The radioactivity of 26Al is used in radiodating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ is small and highly charged; as such, it is polarizing, and bonds aluminium forms tend towards covalency. The strong affinity tow ...
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Metal Oxide
An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials considered pure elements often develop an oxide coating. For example, aluminium foil develops a thin skin of Al2O3 (called a passivation layer) that protects the foil from further corrosion.Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford:Butterworth-Heinemann. . Stoichiometry (the measurable relationship between reactants and chemical equations of a equation or reaction) Oxides are extraordinarily diverse in terms of stoichiometries and in terms of the structures of each stoichiometry. Most elements form oxides of more than one stoichiometry. A well known example is carbon monoxide and carbon dioxide.Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry ...
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Sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. Sulfur is the tenth most abundant element by mass in the universe and the fifth most on Earth. Though sometimes found in pure, native form, sulfur on Earth usually occurs as sulfide and sulfate minerals. Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India, ancient Greece, China, and ancient Egypt. Historically and in literature sulfur is also called brimstone, which means "burning stone". Today, almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas and petroleum.. Downloahere The greatest commercial use of the element is the production o ...
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Barium Nitrate
Barium nitrate is the inorganic compound with the chemical formula Ba( NO3)2. It, like most barium salts, is colorless, toxic, and water-soluble. It burns with a green flame and is an oxidizer; the compound is commonly used in pyrotechnics. Manufacture, occurrence, and reactions Barium nitrate is manufactured by two processes that start with the main source material for barium, the carbonate. The first involves dissolving barium carbonate in nitric acid, allowing any iron impurities to precipitate, then filtered, evaporated, and crystallized. The second requires combining barium sulfide with nitric acid. It occurs naturally as the very rare mineral nitrobarite. At elevated temperatures, barium nitrate decomposes to barium oxide: : 2Ba(NO3)2 → 2BaO + 4NO2 + O2 Applications Barium nitrate is used in the production of BaO-containing materials. Military Although no longer produced, Baratol is an explosive composed of barium nitrate, TNT and binder; the high density of barium ni ...
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Flame
A flame (from Latin ''flamma'') is the visible, gaseous part of a fire. It is caused by a highly exothermic chemical reaction taking place in a thin zone. When flames are hot enough to have ionized gaseous components of sufficient density they are then considered plasma. Mechanism Color and temperature of a flame are dependent on the type of fuel involved in the combustion, as, for example, when a lighter is held to a candle. The applied heat causes the fuel molecules in the candle wax to vaporize (if this process happens in inert atmosphere without oxidizer, it is called pyrolysis). In this state they can then readily react with oxygen in the air, which gives off enough heat in the subsequent exothermic reaction to vaporize yet more fuel, thus sustaining a consistent flame. The high temperature of the flame causes the vaporized fuel molecules to decompose, forming various incomplete combustion products and free radicals, and these products then react with each other and with ...
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Secretary Of The United States Army
The secretary of the Army (SA or SECARMY) is a senior civilian official within the United States Department of Defense, with statutory responsibility for all matters relating to the United States Army: manpower, personnel, reserve affairs, installations, environmental issues, weapons systems and equipment acquisition, communications and financial management. The secretary of the Army is nominated by the president of the United States and confirmed by the United States Senate. The secretary is a non-Cabinet-level official, subordinate to the secretary of Defense. This position was created on September 18, 1947, replacing the secretary of war, when the Department of War was split into the Department of the Army and Department of the Air Force. On May 28, 2021, Christine Wormuth was sworn in as the 25th (and current) secretary of the Army, the first woman to serve in the role. Roles and responsibilities The Army senior leadership consists of two civilians; the secretary of the ...
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Binder (material)
A binder or binding agent is any material or substance that holds or draws other materials together to form a cohesive whole mechanically, chemically, by adhesion or cohesion. In a more narrow sense, binders are liquid or dough-like substances that harden by a chemical or physical process and bind fibres, filler powder and other particles added into it. Examples include glue, adhesive and thickening. Examples of mechanical binders are bond stones in masonry and tie beams in timber framing. Classification Binders are loosely classified as organic ( bitums, animal and plant glues, polymers) and inorganic ( lime, cement, gypsum, liquid glass, etc.). These can be either metallic or ceramic as well as polymeric depending on the nature of the main material. For example, in the compound WC-Co (Tungsten Carbide used in cutting tools) Co constitutes the binding agent for the WC particles. Based on their chemical resistance, binders are classified by the field of use: non-hydra ...
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