Thermal Maturity
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Thermal Maturity
In petroleum geology, the maturity of a rock is a measure of its state in terms of hydrocarbon generation. Maturity is established using a combination of geochemical and basin modelling techniques. Rocks with high total organic carbon, (termed source rocks), will alter under increasing temperature such that the organic molecules slowly mature into hydrocarbons (see diagenesis). Source rocks are therefore broadly categorised as ''immature'' (no hydrocarbon generation), ''sub-mature'' (limited hydrocarbon generation), ''mature'' (extensive hydrocarbon generation) and ''overmature'' (most hydrocarbons have been generated). The maturity of a source rock can also be used as an indicator of its hydrocarbon ''potential''. That is, if a rock is sub-mature, then it has a much higher potential to generate further hydrocarbons than one that is overmature. See also * Van Krevelen diagram Van Krevelen diagrams are graphical plots developed by Dirk Willem van Krevelen (chemist and professo ...
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Petroleum Geology
Petroleum geology is the study of origin, occurrence, movement, accumulation, and exploration of hydrocarbon fuels. It refers to the specific set of geological disciplines that are applied to the search for hydrocarbons (oil exploration). Sedimentary basin analysis Petroleum geology is principally concerned with the evaluation of seven key elements in sedimentary basins: * Source * Reservoir * Seal * Trap * Timing * Maturation * Migration In general, all these elements must be assessed via a limited 'window' into the subsurface world, provided by one (or possibly more) exploration wells. These wells present only a 1-dimensional segment through the Earth, and the skill of inferring 3-dimensional characteristics from them is one of the most fundamental in petroleum geology. Recently, the availability of inexpensive, high quality 3D seismic data (from reflection seismology) and data from various electromagnetic geophysical techniques (such as magnetotellurics) has greatly aide ...
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Rock (geology)
In geology, rock (or stone) is any naturally occurring solid mass or aggregate of minerals or mineraloid matter. It is categorized by the minerals included, its chemical composition, and the way in which it is formed. Rocks form the Earth's outer solid layer, the crust, and most of its interior, except for the liquid outer core and pockets of magma in the asthenosphere. The study of rocks involves multiple subdisciplines of geology, including petrology and mineralogy. It may be limited to rocks found on Earth, or it may include planetary geology that studies the rocks of other celestial objects. Rocks are usually grouped into three main groups: igneous rocks, sedimentary rocks and metamorphic rocks. Igneous rocks are formed when magma cools in the Earth's crust, or lava cools on the ground surface or the seabed. Sedimentary rocks are formed by diagenesis and lithification of sediments, which in turn are formed by the weathering, transport, and deposition of existing ro ...
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Hydrocarbon
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or exemplified by the odors of gasoline and lighter fluid. They occur in a diverse range of molecular structures and phases: they can be gases (such as methane and propane), liquids (such as hexane and benzene), low melting solids (such as paraffin wax and naphthalene) or polymers (such as polyethylene and polystyrene). In the fossil fuel industries, ''hydrocarbon'' refers to the naturally occurring petroleum, natural gas and coal, and to their hydrocarbon derivatives and purified forms. Combustion of hydrocarbons is the main source of the world's energy. Petroleum is the dominant raw-material source for organic commodity chemicals such as solvents and polymers. Most anthropogenic (human-generated) emissions of greenhouse gases are carbon di ...
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Geochemistry
Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the entire Solar System, and has made important contributions to the understanding of a number of processes including mantle convection, the formation of planets and the origins of granite and basalt. It is an integrated field of chemistry and geology. History The term ''geochemistry'' was first used by the Swiss-German chemist Christian Friedrich Schönbein in 1838: "a comparative geochemistry ought to be launched, before geognosy can become geology, and before the mystery of the genesis of our planets and their inorganic matter may be revealed." However, for the rest of the century the more common term was "chemical geology", and there was little contact between geologists and chemists. Geochemistry emerged as a separate discipline after ...
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Basin Modelling
Basin modelling is the term broadly applied to a group of geological disciplines that can be used to analyse the formation and evolution of sedimentary basins, often but not exclusively to aid evaluation of potential hydrocarbon reserves. At its most basic, a basin modelling exercise must assess: # The burial history of the basin (see back-stripping). # The thermal history of the basin (see thermal history modelling). # The maturity history of the source rock In petroleum geology, source rock is rock which has generated hydrocarbons or which could generate hydrocarbons. Source rocks are one of the necessary elements of a working petroleum system. They are organic-rich sediments that may have been depos ...s. # The expulsion, migration and trapping of hydrocarbons. By doing so, valuable inferences can be made about such matters as hydrocarbon generation and timing, maturity of potential source rocks and migration paths of expelled hydrocarbons. References * Duppenbecker S. J. ...
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Total Organic Carbon
Total organic carbon (TOC) is the amount of carbon found in an organic compound and is often used as a non-specific indicator of water quality or cleanliness of pharmaceutical manufacturing equipment. TOC may also refer to the amount of organic carbon in soil, or in a geological formation, particularly the source rock for a petroleum play; 2% is a rough minimum. For marine surface sediments average TOC content is 0.5% in the deep ocean, and 2% along the eastern margins. A typical analysis for total carbon (TC) measures both the total organic carbon (TOC) present and the complementing total inorganic carbon (TIC), the latter representing the amount of non-organic carbon, like carbon in carbonate minerals. Subtracting the inorganic carbon from the total carbon yields TOC. Another common variant of TOC analysis involves removing the TIC portion first and then measuring the leftover carbon. This method involves purging an acidified sample with carbon-free air or nitrogen prior to mea ...
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Source Rock
In petroleum geology, source rock is rock which has generated hydrocarbons or which could generate hydrocarbons. Source rocks are one of the necessary elements of a working petroleum system. They are organic-rich sediments that may have been deposited in a variety of environments including deep water marine, lacustrine and deltaic. Oil shale can be regarded as an organic-rich but immature source rock from which little or no oil has been generated and expelled. Subsurface source rock mapping methodologies make it possible to identify likely zones of petroleum occurrence in sedimentary basins as well as shale gas plays. Types of source rocks Source rocks are classified from the types of kerogen that they contain, which in turn governs the type of hydrocarbons that will be generated: * Type I source rocks are formed from algal remains deposited under anoxic conditions in deep lakes: they tend to generate waxy crude oils when submitted to thermal stress during deep burial. * Type ...
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Temperature
Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied on various reference points and thermometric substances for definition. The most common scales are the Celsius scale with the unit symbol °C (formerly called ''centigrade''), the Fahrenheit scale (°F), and the Kelvin scale (K), the latter being used predominantly for scientific purposes. The kelvin is one of the seven base units in the International System of Units (SI). Absolute zero, i.e., zero kelvin or −273.15 °C, is the lowest point in the thermodynamic temperature scale. Experimentally, it can be approached very closely but not actually reached, as recognized in the third law of thermodynamics. It would be impossible to extract energy as heat from a body at that temperature. Temperature is important in all fields of natur ...
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Molecule
A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and ''molecule'' is often used when referring to polyatomic ions. A molecule may be homonuclear, that is, it consists of atoms of one chemical element, e.g. two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, e.g. water (two hydrogen atoms and one oxygen atom; H2O). In the kinetic theory of gases, the term ''molecule'' is often used for any gaseous particle regardless of its composition. This relaxes the requirement that a molecule contains two or more atoms, since the noble gases are individual atoms. Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not consid ...
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Diagenesis
Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a role as sediments become buried much deeper in the Earth's crust. In the early stages, the transformation of poorly consolidated sediments into sedimentary rock (lithification) is simply accompanied by a reduction in porosity and water expulsion (clay sediments), while their main mineralogical assemblages remain unaltered. As the rock is carried deeper by further deposition above, its organic content is progressively transformed into kerogens and bitumens. The process of diagenesis excludes surface alteration (weathering) and deep metamorphism. There is no sharp boundary between diagenesis and metamorphism, but the latter occurs at higher temperatures and pressures. Hydrothermal solutions, meteoric groundwater, rock porosity, permeability, ...
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Van Krevelen Diagram
Van Krevelen diagrams are graphical plots developed by Dirk Willem van Krevelen (chemist and professor of fuel technology at the TU Delft) and used to assess the origin and maturity of kerogen and petroleum. The diagram cross-plots the hydrogen:carbon atomic ratio as a function of the oxygen:carbon atomic ratio. Beginning around 2003, the diagrams are often used to visualize data from mass spectrometry analysis, used for mixtures other than kerogen and petroleum. For example, the diagrams have been used in one analysis of the components in Scotch whiskey. Types of kerogen Different types of kerogen have differing potentials to produce oil during maturation. These various types of kerogen can be distinguished on a van Krevelen diagram. See also * Petroleum geology * Maturity (geology) In petroleum geology, the maturity of a rock is a measure of its state in terms of hydrocarbon generation. Maturity is established using a combination of geochemical and basin modelling techn ...
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Geochemistry
Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the entire Solar System, and has made important contributions to the understanding of a number of processes including mantle convection, the formation of planets and the origins of granite and basalt. It is an integrated field of chemistry and geology. History The term ''geochemistry'' was first used by the Swiss-German chemist Christian Friedrich Schönbein in 1838: "a comparative geochemistry ought to be launched, before geognosy can become geology, and before the mystery of the genesis of our planets and their inorganic matter may be revealed." However, for the rest of the century the more common term was "chemical geology", and there was little contact between geologists and chemists. Geochemistry emerged as a separate discipline after ...
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