Tellurium Dioxide
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Tellurium Dioxide
Tellurium dioxide (TeO2) is a solid oxide of tellurium. It is encountered in two different forms, the yellow orthorhombic mineral tellurite, β-TeO2, and the synthetic, colourless tetragonal (paratellurite), α-TeO2. Most of the information regarding reaction chemistry has been obtained in studies involving paratellurite, α-TeO2.W.R.McWhinnie (1995) ''Tellurium - Inorganic chemistry'' Encyclopedia of Inorganic Chemistry Ed. R. Bruce King (1994) John Wiley & Sons Preparation Paratellurite, α-TeO2, is produced by reacting tellurium with O2: :Te + O2 → TeO2 An alternative preparation is to dehydrate tellurous acid, H2TeO3, or to thermally decompose basic tellurium nitrate, Te2O4·HNO3, above 400 °C. Physical properties The longitudinal speed of sound in Tellurium dioxide is at around room temperature. Chemical properties TeO2 is barely soluble in water and soluble in strong acids and alkali metal hydroxides. It is an amphoteric substance and therefore can act both ...
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Orthorhombic
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal. Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , row oC, column Primitive, where the cell parameters are given as a1 = a2, α = β = 90° it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primit ...
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Tellurite (ion)
The tellurite ion is . A tellurite (compound), for example sodium tellurite, is a compound that contains this ion. They are typically colorless or white salts, which in some ways are comparable to sulfite. A mineral with the formula TeO2 is called tellurite. Structure and reactions Tellurite dianion is pyramidal, like selenite and sulfite. The anion has C3v symmetry. Tellurites can be reduced to elemental tellurium by electrolysis or a strong reducing agent. When fused with nitrate salts, tellurite salts oxidize to tellurates (). Upon acidification of aqueous solutions of tellurite salts, solid hydrated tellurium dioxide (TeO2) precipitates. This reaction allows the separation of tellurium from selenium since selenous acid remains soluble at low pH. The intermediate in the protonation occurs at oxygen to give eO2(OH)sup>−. Uses Potassium tellurite (K2TeO3) is used together with agar as part of a selective medium for growth of some bacteria (Clauberg medium). Coryneba ...
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Optical Fibre
An optical fiber, or optical fibre in Commonwealth English, is a flexible, transparent fiber made by drawing glass (silica) or plastic to a diameter slightly thicker than that of a human hair. Optical fibers are used most often as a means to transmit light between the two ends of the fiber and find wide usage in fiber-optic communications, where they permit transmission over longer distances and at higher bandwidths (data transfer rates) than electrical cables. Fibers are used instead of metal wires because signals travel along them with less loss; in addition, fibers are immune to electromagnetic interference, a problem from which metal wires suffer. Fibers are also used for illumination and imaging, and are often wrapped in bundles so they may be used to carry light into, or images out of confined spaces, as in the case of a fiberscope. Specially designed fibers are also used for a variety of other applications, some of them being fiber optic sensors and fiber lasers. Op ...
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Silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and most abundant families of materials, existing as a compound of several minerals and as a synthetic product. Notable examples include fused quartz, fumed silica, silica gel, opal and aerogels. It is used in structural materials, microelectronics (as an Insulator (electricity), electrical insulator), and as components in the food and pharmaceutical industries. Structure In the majority of silicates, the silicon atom shows tetrahedral coordination geometry, tetrahedral coordination, with four oxygen atoms surrounding a central Si atomsee 3-D Unit Cell. Thus, SiO2 forms 3-dimensional network solids in which each silicon atom is covalently bonded in a tetrahedral manner to 4 oxygen atoms. In contrast, CO2 is a linear ...
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Raman Amplification
Raman amplification "Raman effect"
. ''''. is based on the stimulated (SRS) phenomenon, when a lower frequency 'signal' induces the of a higher-frequency 'pump' photon in an optical medium in the nonlinear regime. As a result of this, another 'sign ...
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Optical Waveguide
An optical waveguide is a physical structure that guides electromagnetic waves in the optical spectrum. Common types of optical waveguides include optical fiber waveguides, transparent dielectric waveguides made of plastic and glass, liquid light guides, and liquid waveguides. Optical waveguides are used as components in integrated optical circuits or as the transmission medium in local and long-haul optical communication systems. Optical waveguides can be classified according to their geometry (planar, strip, or fiber waveguides), mode structure (single-mode, multi-mode), refractive index distribution (step or gradient index), and material (glass, polymer, semiconductor). Total internal reflection The basic principles behind optical waveguides can be described using the concepts of geometrical or ray optics, as illustrated in the diagram. Light passing into a medium with higher refractive index bends toward the normal by the process of refraction (Figure a.). Take, for examp ...
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Electromagnetic Spectrum
The electromagnetic spectrum is the range of frequencies (the spectrum) of electromagnetic radiation and their respective wavelengths and photon energies. The electromagnetic spectrum covers electromagnetic waves with frequencies ranging from below one hertz to above 1025 hertz, corresponding to wavelengths from thousands of kilometers down to a fraction of the size of an atomic nucleus. This frequency range is divided into separate bands, and the electromagnetic waves within each frequency band are called by different names; beginning at the low frequency (long wavelength) end of the spectrum these are: radio waves, microwaves, infrared, visible light, ultraviolet, X-rays, and gamma rays at the high-frequency (short wavelength) end. The electromagnetic waves in each of these bands have different characteristics, such as how they are produced, how they interact with matter, and their practical applications. There is no known limit for long and short wavelengths. Extreme ultr ...
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Infrared
Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around 1 millimeter (300 GHz) to the nominal red edge of the visible spectrum, around 700  nanometers (430  THz). Longer IR wavelengths (30 μm-100 μm) are sometimes included as part of the terahertz radiation range. Almost all black-body radiation from objects near room temperature is at infrared wavelengths. As a form of electromagnetic radiation, IR propagates energy and momentum, exerts radiation pressure, and has properties corresponding to both those of a wave and of a particle, the photon. It was long known that fires emit invisible heat; in 1681 the pioneering experimenter Edme Mariotte showed that glass, though transparent to sunlight, obstructed radiant heat. In 1800 the astronomer Sir William Herschel discovered ...
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Refractive Indices
In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium. The refractive index determines how much the path of light is bent, or refraction, refracted, when entering a material. This is described by Snell's law of refraction, , where ''θ''1 and ''θ''2 are the angle of incidence (optics), angle of incidence and angle of refraction, respectively, of a ray crossing the interface between two media with refractive indices ''n''1 and ''n''2. The refractive indices also determine the amount of light that is reflectivity, reflected when reaching the interface, as well as the critical angle for total internal reflection, their intensity (Fresnel's equations) and Brewster's angle. The refractive index can be seen as the factor by which the speed and the wavelength of the radiation are reduced with respect to their vacuum values: the speed of light in a medium is , and simil ...
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Acousto-optic
Acousto-optics is a branch of physics that studies the interactions between sound waves and light waves, especially the diffraction of laser light by ultrasound (or sound in general) through an ultrasonic grating. Introduction Optics has had a very long and full history, from ancient Greece, through the renaissance and modern times. As with optics, acoustics has a history of similar duration, again starting with the ancient Greeks. In contrast, the acousto-optic effect has had a relatively short history, beginning with Brillouin predicting the diffraction of light by an acoustic wave, being propagated in a medium of interaction, in 1922. This was then confirmed with experimentation in 1932 by Debye and Sears, and also by Lucas and Biquard. The particular case of diffraction on the first order, under a certain angle of incidence, (also predicted by Brillouin), has been observed by Rytow in 1935. Raman and Nath (1937) have designed a general ideal model of interaction taking i ...
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