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Triethylborane
Triethylborane (TEB), also called triethylboron, is an organoborane (a compound with a B–C bond). It is a colorless pyrophoric liquid. Its chemical formula is or , abbreviated . It is soluble in organic solvents tetrahydrofuran and hexane. Preparation and structure Triethylborane is prepared by the reaction of trimethyl borate with triethylaluminium: :Et3Al + (MeO)3B → Et3B + (MeO)3Al The molecule is monomeric, unlike H3B and Et3Al, which tend to dimerize. It has a planar BC3 core. Applications Turbojet engine Triethylborane was used to ignite the JP-7 fuel in the Pratt & Whitney J58 turbojet/ramjet engines powering the Lockheed SR-71 Blackbird and its predecessor, the A-12 OXCART. Triethylborane is suitable because it ignites readily upon exposure to oxygen. It was chosen as an ignition method for reliability reasons, and in the case of the Blackbird, because JP-7 fuel has very low volatility and is difficult to ignite. Conventional ignition plugs posed a high risk of mal ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Triethylaluminium
Triethylaluminium is one of the simplest examples of an organoaluminium compound. Despite its name it has the formula Al2( C2H5)6 (abbreviated as Al2Et6 or TEA), as it exists as a dimer. This colorless liquid is pyrophoric. It is an industrially important compound, closely related to trimethylaluminium. Structure and bonding The structure and bonding in Al2R6 and diborane are analogous (R = alkyl). Referring to Al2Me6, the Al-C(terminal) and Al-C(bridging) distances are 1.97 and 2.14 Å, respectively. The Al center is tetrahedral. The carbon atoms of the bridging ethyl groups are each surrounded by five neighbors: carbon, two hydrogen atoms and two aluminium atoms. The ethyl groups interchange readily intramolecularly. At higher temperatures, the dimer cracks into monomeric AlEt3. Synthesis and reactions Triethylaluminium can be formed via several routes. The discovery of an efficient route was a significant technological achievement. The multistep process uses aluminium m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Falcon 9
Falcon 9 is a partially reusable medium lift launch vehicle that can carry cargo and crew into Earth orbit, produced by American aerospace company SpaceX. The rocket has two stages. The first (booster) stage carries the second stage and payload to a certain altitude, after which the second stage lifts the payload to its ultimate destination. The rocket evolved through several versions. V1.0 flew from 2010–2013, V1.1 flew from 2013–2016, while V1.2 Full Thrust first launched in 2015, encompassing the Block 5 variant, flying since May 2018. The booster is capable of landing vertically to facilitate reuse. This feat was first achieved on flight 20 in December 2015. Since then, SpaceX has successfully landed boosters over 100 times. Individual boosters have flown as many as 15 flights. Both stages are powered by SpaceX Merlin engines, using cryogenic liquid oxygen and rocket-grade kerosene (RP-1) as propellants. The heaviest payloads flown to geostationary transfer or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lockheed SR-71 Blackbird
The Lockheed SR-71 "Blackbird" is a long-range, high-altitude, Mach 3+ strategic reconnaissance aircraft developed and manufactured by the American aerospace company Lockheed Corporation. It was operated by the United States Air Force (USAF) and NASA. The SR-71 was developed as a black project from the Lockheed A-12 reconnaissance aircraft during the 1960s by Lockheed's Skunk Works division. American aerospace engineer Clarence "Kelly" Johnson was responsible for many of the aircraft's innovative concepts. The shape of the SR-71 was based on that of the A-12, which was one of the first aircraft to be designed with a reduced radar cross-section. Initially, a bomber variant of the A-12 was requested by Curtis LeMay, before the program was focused solely on reconnaissance. Mission equipment for the reconnaissance role included signals intelligence sensors, side looking airborne radar, and a camera; the SR-71 was both longer and heavier than the A-12, allowing it to hold mo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organoborane
Organoborane or organoboron compounds are chemical compounds of boron and carbon that are organic derivatives of BH3, for example trialkyl boranes. Organoboron chemistry or organoborane chemistry is the chemistry of these compounds. Organoboron compounds are important reagents in organic chemistry enabling many chemical transformations, the most important one called hydroboration. Reactions of organoborates and boranes involve the transfer of a nucleophilic group attached to boron to an electrophilic center either inter- or intramolecularly. α,β-Unsaturated borates, as well as borates with a leaving group at the α position, are highly susceptible to intramolecular 1,2-migration of a group from boron to the electrophilic α position. Oxidation or protonolysis of the resulting organoboranes may generate a variety of organic products, including alcohols, carbonyl compounds, alkenes, and halides. Properties of the B-C bond The C-B bond has low polarity (the difference in electron ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pyrophoricity
A substance is pyrophoric (from grc-gre, πυροφόρος, , 'fire-bearing') if it ignites spontaneously in air at or below (for gases) or within 5 minutes after coming into contact with air (for liquids and solids). Examples are organolithium compounds and triethylborane. Pyrophoric materials are often water-reactive as well and will ignite when they contact water or humid air. They can be handled safely in atmospheres of argon or (with a few exceptions) nitrogen. Class D fire extinguishers are designated for use in fires involving pyrophoric materials. A related concept is hypergolicity, in which two compounds spontaneously ignite when mixed. Uses The creation of sparks from metals is based on the pyrophoricity of small metal particles, and pyrophoric alloys are made for this purpose. The sparking mechanisms in lighters and various toys, using ferrocerium; starting fires without matches, using a firesteel; the flintlock mechanism in firearms; and spark testing ferrou ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
JP-7
Turbine Fuel Low Volatility JP-7, commonly known as JP-7 (referred to as Jet Propellant 7 prior to MIL-DTL-38219) is a specialized type of jet fuel developed in 1955 for the United States Air Force (USAF) for use in its supersonic military aircraft, including the SR-71 Blackbird and the Boeing X-51 Waverider. Usage JP-7 was developed for the Pratt & Whitney J58 (JT11D-20) turbojet engine, which was used primarily in the now retired Lockheed SR-71 Blackbird. During flight, the SR-71 could attain speeds in excess of Mach 3+, which was the most efficient cruising speed for the J58 engines. However, very high skin temperatures are generated at this speed due to friction with the air. A new jet fuel was needed that was not affected by the heat, so JP-7 jet fuel, with a high flash point and high thermal stability, was developed for this purpose. The Boeing X-51 Waverider also uses JP-7 fuel in its Pratt & Whitney SJY61 scramjet engine, with fuel capacity of some . As with the SR-71, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetraethyllead
Tetraethyllead (commonly styled tetraethyl lead), abbreviated TEL, is an organolead compound with the formula Pb( C2H5)4. It is a fuel additive, first being mixed with gasoline beginning in the 1920s as a patented octane rating booster that allowed engine compression to be raised substantially. This in turn increased vehicle performance and fuel economy. TEL was first synthesised by German chemist Carl Jacob Löwig in 1853. American chemical engineer Thomas Midgley Jr., who was working for General Motors, was the first to discover its effectiveness as an antiknock agent in 1921, after spending several years attempting to find an additive that was both highly effective and inexpensive. Concerns were later raised over the toxic effects of lead, especially on children. On cars not designed to operate on leaded gasoline, lead and lead oxides coat the catalyst in catalytic converters, rendering them ineffective, and can sometimes foul spark plugs. Starting in the 1970s, many cou ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Radical Initiator
In chemistry, radical initiators are substances that can produce radical species under mild conditions and promote radical reactions. These substances generally possess weak bonds—bonds that have small bond dissociation energies. Radical initiators are utilized in industrial processes such as polymer synthesis. Typical examples are molecules with a nitrogen-halogen bond, azo compounds, and organic and inorganic peroxides. Main types of initiation reaction *Halogens undergo homolytic fission relatively easily. Chlorine, for example, gives two chlorine radicals (Cl•) by irradiation with ultraviolet light. This process is used for chlorination of alkanes. *Azo compounds (R- N=N-R') can be the precursor of two carbon-centered radicals (R• and R'•) and nitrogen gas upon heating and/or by irradiation. For example, AIBN and ABCN yield isobutyronitrile and cyclohexanecarbonitrile radicals, respectively. : *Organic peroxides each have a peroxide bond (- O-O-), which is readi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Radical (chemistry)
In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron. With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most organic radicals have short lifetimes. A notable example of a radical is the hydroxyl radical (HO·), a molecule that has one unpaired electron on the oxygen atom. Two other examples are triplet oxygen and triplet carbene (꞉) which have two unpaired electrons. Radicals may be generated in a number of ways, but typical methods involve redox reactions. Ionizing radiation, heat, electrical discharges, and electrolysis are known to produce radicals. Radicals are intermediates in many chemical reactions, more so than is apparent from the balanced equations. Radicals are important in combustion, atmospheric chemistry, polymerization, plasma chemistry, biochemistry, and many other chemical processes. A majority of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ullmann's Encyclopedia Of Industrial Chemistry
''Ullmann's Encyclopedia of Industrial Chemistry'' is a major reference work related to industrial chemistry by Chemist Fritz Ullmann, first published in 1914, and exclusively in German as "Enzyklopädie der Technischen Chemie" until 1984. History Ullmann's Encyclopedia of Industrial Chemistry is a major reference work related to industrial chemistry by chemist Fritz Ullmann. Its 1st edition was published in German by Fritz Ullmann in 1914. The 4th edition, published 1972 to 1984, already contained 25 volumes. The 5th edition, published 1985 to 1996, was the first version available in English. In 1997, the first online version was published. 2014 marked its centenary. As of 2016, Ullmann's Encyclopedia was in its 7th edition, in 40 volumes including one index volume and more than 1,050 articles (200 more than the 6th edition), approx. 30,000 pages, 22,000 images, 8,000 tables, 19,000 references and 85,000 indices. Editions * 1914–1922: 1st edition in 12 volumes, which can ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Saturn V
Saturn V is a retired American super heavy-lift launch vehicle developed by NASA under the Apollo program for human exploration of the Moon. The rocket was human-rated, with multistage rocket, three stages, and powered with liquid-propellant rocket, liquid fuel. It was flown from 1967 to 1973. It was used for nine crewed flights to the Moon, and to launch Skylab, the first American space station. the Saturn V remains the only launch vehicle to carry humans beyond low Earth orbit (LEO). Saturn V holds records for the heaviest payload launched and largest payload capacity to low Earth orbit: , which included the third stage and unburned propellant needed to send the Apollo command and service module and Apollo Lunar Module, Lunar Module to the Moon. The largest production model of the Saturn (rocket family), Saturn family of rockets, the Saturn V was designed under the direction of Wernher von Braun at the Marshall Space Flight Center in Huntsville, Alabama; the lead contractor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
