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Tributyltin Compounds
Tributyltin (TBT) is an umbrella term for a class of organotin compounds which contain the (C4H9)3 Sn group, with a prominent example being tributyltin oxide. For 40 years TBT was used as a biocide in anti-fouling paint, commonly known as bottom paint, applied to the hulls of oceangoing vessels. Bottom paint improves ship performance and durability as it reduces the rate of biofouling, the growth of organisms on the ship's hull. The TBT slowly leaches out into the marine environment where it is highly toxic toward nontarget organisms. TBT toxicity can lead to biomagnification or bioaccumulation within such nontarget organisms like invertebrates, vertebrates, and a variety of mammals. TBT is also an obesogen. After it led to collapse of local populations of organisms, TBT was banned. Chemical properties TBT, or tributyltin, tributylstannyl or tributyl stannic hydride compounds are organotin compounds. They have three butyl groups covalently bonded to a tin(IV) centre.Davies, Alwy ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tributyltin Oxide Structure
Tributyltin (TBT) is an umbrella term for a class of organotin compounds which contain the (C4H9)3 Sn group, with a prominent example being tributyltin oxide. For 40 years TBT was used as a biocide in anti-fouling paint, commonly known as bottom paint, applied to the hulls of oceangoing vessels. Bottom paint improves ship performance and durability as it reduces the rate of biofouling, the growth of organisms on the ship's hull. The TBT slowly leaches out into the marine environment where it is highly toxic toward nontarget organisms. TBT toxicity can lead to biomagnification or bioaccumulation within such nontarget organisms like invertebrates, vertebrates, and a variety of mammals. TBT is also an obesogen. After it led to collapse of local populations of organisms, TBT was banned. Chemical properties TBT, or tributyltin, tributylstannyl or tributyl stannic hydride compounds are organotin compounds. They have three butyl groups covalently bonded to a tin(IV) centre.Davies, Alwy ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dog Whelk
The dog whelk, dogwhelk, or Atlantic dogwinkle (''Nucella lapillus'') is a species of predatory sea snail, a carnivorous marine gastropod in the family Muricidae, the rock snails. ''Nucella lapillus'' was originally described by Carl Linnaeus in his landmark 1758 10th edition of ''Systema Naturae'' as ''Buccinum lapillus'' (the basionym). "Dog whelk" can also refer to the Nassariidae. Distribution This species is found around the coasts of Europe and in the northern west Atlantic coast of North America. It also can be found in estuarine waters along the Atlantic coasts. This species prefers rocky shores, where it eats mussels and acorn barnacles.Colin Little, J. A. Kitching, 1996''The Biology of Rocky Shores'' pp. 140-145. Shell description The dog whelk shell is small and rounded with a pointed spire and a short, straight siphonal canal (a groove on the underside of the shell) and a deep anal canal. The overall shell shape varies quite widely according to the degree of ex ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
International Convention On The Control Of Harmful Anti-fouling Systems On Ships
The International Convention on the Control of Harmful Anti-fouling Systems in Ships (AFS Convention) is a 2001 International Maritime Organization (IMO) treaty whereby states agree to prohibit the use of harmful anti-fouling paints and other anti-fouling systems that contain harmful substances. In particular, the use of the organotin tributyltin is prohibited, since leaching of that chemical from the hulls of ships has been shown to cause deformations in oysters and sex changes in whelks. The convention was concluded in London on 5 October 2001 and entered into force on 17 September 2008. As of November 2018, it has been ratified by 81 states, which includes 79 United Nations member states plus the Cook Islands and Niue. A ratifying state agrees to enforce the prohibitions of the convention on all ships flying its flag ''and'' on any ship that enters a port, shipyard, or offshore terminal of the state. The 81 ratifying states represent approximately 94 per cent of the gross to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rotterdam Convention
The Rotterdam Convention (formally, the Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade) is a multilateral treaty to promote shared responsibilities in relation to importation of hazardous chemicals. The convention promotes open exchange of information and calls on exporters of hazardous chemicals to use proper labeling, include directions on safe handling, and inform purchasers of any known restrictions or bans. Signatory nations can decide whether to allow or ban the importation of chemicals listed in the treaty, and exporting countries are obliged to make sure that producers within their jurisdiction comply. In 2012, the Secretariats of the Basel and Stockholm conventions, as well as the UNEP-part of the Rotterdam Convention Secretariat, merged to a single Secretariat with a matrix structure serving the three conventions. The three conventions now hold back to back Conferences of the Parties a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organotin Compounds
Organotin compounds or stannanes are chemical compounds based on tin with hydrocarbon substituents. Organotin chemistry is part of the wider field of organometallic chemistry. The first organotin compound was diethyltin diiodide (), discovered by Edward Frankland in 1849. The area grew rapidly in the 1900s, especially after the discovery of the Grignard reagents, which are useful for producing Sn–C bonds. The area remains rich with many applications in industry and continuing activity in the research laboratory. Structure Organotin compounds are generally classified according to their oxidation states. Tin(IV) compounds are much more common and more useful. Organic derivatives of tin(IV) The tetraorgano derivatives are invariably tetrahedral. Compounds of the type SnRR'R''R have been resolved into individual enantiomers. Organotin halides Organotin chlorides have the formula for values of ''n'' up to 3. Bromides, iodides, and fluorides are also known but less important. These ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
International Maritime Organization
The International Maritime Organization (IMO, French: ''Organisation maritime internationale'') is a specialised agency of the United Nations responsible for regulating shipping. The IMO was established following agreement at a UN conference held in Geneva in 1948 and the IMO came into existence ten years later, meeting for the first time in 1959. Headquartered in London, United Kingdom, IMO currently has 175 Member States and three Associate Members. The IMO's primary purpose is to develop and maintain a comprehensive regulatory framework for shipping and its remit today includes maritime safety, environmental concerns, legal matters, technical co-operation, maritime security and the efficiency of shipping. IMO is governed by an assembly of members which meets every two years. Its finance and organization is administered by a council of 40 members elected from the assembly. The work of IMO is conducted through five committees and these are supported by technical subcommitte ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Toothed Whale
The toothed whales (also called odontocetes, systematic name Odontoceti) are a parvorder of cetaceans that includes dolphins, porpoises, and all other whales possessing teeth, such as the beaked whales and sperm whales. Seventy-three species of toothed whales are described. They are one of two living groups of cetaceans, the other being the baleen whales (Mysticeti), which have baleen instead of teeth. The two groups are thought to have diverged around 34 million years ago (mya). Toothed whales range in size from the and vaquita to the and sperm whale. Several species of odontocetes exhibit sexual dimorphism, in that there are size or other morphological differences between females and males. They have streamlined bodies and two limbs that are modified into flippers. Some can travel at up to 20 knots. Odontocetes have conical teeth designed for catching fish or squid. They have well-developed hearing, that is well adapted for both air and water, so much so that some can surviv ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bottlenose Dolphin
Bottlenose dolphins are aquatic mammals in the genus ''Tursiops.'' They are common, cosmopolitan members of the family Delphinidae, the family of oceanic dolphins. Molecular studies show the genus definitively contains two species: the common bottlenose dolphin (''Tursiops truncatus'') and the Indo-Pacific bottlenose dolphin (''Tursiops aduncus''). Others, like the Burrunan dolphin (''Tursiops (aduncus) australis''), may be alternately considered their own species or be subspecies of ''T. aduncus''. Bottlenose dolphins inhabit warm and temperate seas worldwide, being found everywhere except for the Arctic and Antarctic Circle regions. Their name derives from the Latin ''tursio'' (dolphin) and ''truncatus'' for their characteristic truncated teeth. Numerous investigations of bottlenose dolphin intelligence have been conducted, examining mimicry, use of artificial language, object categorization, and self-recognition. They can use tools (sponging; using marine sponges to forage ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sea Otter
The sea otter (''Enhydra lutris'') is a marine mammal native to the coasts of the northern and eastern North Pacific Ocean. Adult sea otters typically weigh between , making them the heaviest members of the weasel family, but among the smallest marine mammals. Unlike most marine mammals, the sea otter's primary form of insulation is an exceptionally thick coat of fur, the densest in the animal kingdom. Although it can walk on land, the sea otter is capable of living exclusively in the ocean. The sea otter inhabits nearshore environments, where it dives to the sea floor to forage. It preys mostly on marine invertebrates such as sea urchins, various mollusks and crustaceans, and some species of fish. Its foraging and eating habits are noteworthy in several respects. Its use of rocks to dislodge prey and to open shells makes it one of the few mammal species to use tools. In most of its range, it is a keystone species, controlling sea urchin populations which would otherwise in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Skipjack Tuna
The skipjack tuna (''Katsuwonus pelamis'') is a medium-sized perciform fish in the tuna family, Scombridae. It is otherwise known as the balaya (Sri Lanka), bakulan/kayu (North Borneo), tongkol/aya (Malay Peninsula/Indonesia), aku (Hawaii), cakalang (Indonesia), katsuo, arctic bonito, mushmouth, oceanic bonito, striped tuna or victor fish. It grows up to 1 m (3 ft) in length. It is a cosmopolitan pelagic fish found in tropical and warm-temperate waters. It is a very important species for fisheries. Description It is a streamlined, fast-swimming pelagic fish, common in tropical waters throughout the world, where it inhabits surface waters in large shoals (up to 50,000 fish), feeding on fish, crustaceans, cephalopods, and mollusks. It is an important prey species for sharks and large pelagic fishes and is often used as live bait when fishing for marlin. It has no scales, except on the lateral line and the corselet (a band of large, thick scales forming a circle around th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Japanese Rice Fish
The Japanese rice fish (''Oryzias latipes''), also known as the medaka, is a member of genus ''Oryzias'' ( ricefish), the only genus in the subfamily Oryziinae. This small (up to about ) native of East Asia is a denizen of rice paddies, marshes, ponds, slow-moving streams and tide pools. It is euryhaline, occurring in both brackish and freshwater. It became popular as an aquarium fish because of its hardiness and pleasant coloration: its coloration varies from creamy-white to yellowish in the wild to white, creamy-yellow, or orange in aquarium-bred individuals. Bright yellow, red or green transgenic populations, similar to GloFish, have also been developed, but are banned from sale in the EU. The medaka has been a popular pet since the 17th century in Japan. After fertilization, the female carries her eggs attached anterior to the anal fin for a period before depositing them on plants or similar things. Ecology Medaka live in small ponds, shallow rivers, and rice fields. Th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Masculinization
Virilization or masculinization is the biological development of adult male characteristics in young males or females. Most of the changes of virilization are produced by androgens. Virilization is most commonly used in three medical and biology of sex contexts: prenatal biological sexual differentiation, the postnatal changes of typical chromosomal male (46, XY) puberty, and excessive androgen effects in typical chromosomal females (46, XX). It is also the intended result of androgen replacement therapy in males with delayed puberty and low testosterone. Prenatal virilization In the prenatal period, virilization refers to closure of the perineum, thinning and wrinkling (rugation) of the scrotum, growth of the penis, and closure of the urethral groove to the tip of the penis. In this context, ''masculinization'' is synonymous with ''virilization.'' Prenatal virilization of genetic females and undervirilization of genetic males are common causes of ambiguous genitalia and int ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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