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Thermal Ionisation
Thermal ionization, also known as surface ionization or contact ionization, is a physical process whereby the atoms are desorbed from a hot surface, and in the process are ionized. Thermal ionization is used to make simple ion sources, for mass spectrometry and for generating ion beams. Thermal ionization has seen extensive use in determining atomic weights, in addition to being used in many geological/nuclear applications. Physics The likelihood of ionization is a function of the filament temperature, the work function of the filament substrate and the ionization energy of the element. This is summarised in the Saha-Langmuir equation: :\frac = \frac \exp \Bigg(\frac\Bigg) where ::\frac = ratio of ion number density to neutral number density ::\frac = ratio of statistical weights (degeneracy) of ionic (g_+) and neutral (g_0) states ::W = work function of surface ::\Delta E_I = ionization energy of desorbed element ::k = Boltzmann's constant ::T = surface temperature ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Desorption
Desorption is the physical process where a previously adsorbed substance is released from a surface. This happens when a molecule gains enough energy to overcome the activation barrier of the bounding energy that keeps it in the surface. There are a lot of different types of desorption, depending on the mechanism that separates the adsorbate from the substrate; therefore there is no one equation that describes the process. Note that desorption is the opposite of adsorption, which differs from absorption because it refers to substances being stuck to the surface, as opposed to being absorbed into the bulk. Desorption can occur after a reaction between a catalyst and an adsorbed compound; or during stripping or chromatography which are types of separation processes. Desorption mechanisms Depending on the nature of the adsorbent-to-surface bond, there are a multitude of mechanisms for desorption. The surface bond of a sorbant can be cleaved thermally, through chemical react ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrical Filament
An incandescent light bulb, incandescent lamp or incandescent light globe is an electric light with a wire filament heated until it glows. The filament is enclosed in a glass bulb with a vacuum or inert gas to protect the filament from oxidation. Current is supplied to the filament by terminals or wires embedded in the glass. A bulb socket provides mechanical support and electrical connections. Incandescent bulbs are manufactured in a wide range of sizes, light output, and voltage ratings, from 1.5 volts to about 300 volts. They require no external regulating equipment, have low manufacturing costs, and work equally well on either alternating current or direct current. As a result, the incandescent bulb became widely used in household and commercial lighting, for portable lighting such as table lamps, car headlamps, and flashlights, and for decorative and advertising lighting. Incandescent bulbs are much less efficient than other types of electric lighting, converting le ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Meghnad Saha
Meghnad Saha (6 October 1893 – 16 February 1956) was an Indian astrophysicist who developed the Saha ionization equation, used to describe chemical and physical conditions in stars. His work allowed astronomers to accurately relate the spectral classes of stars to their actual temperatures. He was elected to the Parliament of India in 1952 from Calcutta. Biography Meghnad Saha was born in 1893 in a very poor family in Shaoratoli, a village near Dhaka-Bikrampur, in the former Bengal Presidency of British India (in present-day Village- Shaoratoli, Thana- Kaliakair, District- Gazipur, Bangladesh). Son of Jagannath Saha (a grocer) and Smt. Bhubneshwari Devi, Meghnad struggled to rise in life. During his early schooling he was forced to leave Dhaka Collegiate School because he participated in the Swadeshi movement. He earned his Indian School Certificate from Dhaka College. He was also a student at the Presidency College, Kolkata and Rajabazar Science College CU. As a stude ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Irving Langmuir
Irving Langmuir (; January 31, 1881 – August 16, 1957) was an American chemist, physicist, and engineer. He was awarded the Nobel Prize in Chemistry in 1932 for his work in surface chemistry. Langmuir's most famous publication is the 1919 article "The Arrangement of Electrons in Atoms and Molecules" in which, building on Gilbert N. Lewis's cubical atom theory and Walther Kossel's chemical bonding theory, he outlined his "concentric theory of atomic structure". Langmuir became embroiled in a priority dispute with Lewis over this work; Langmuir's presentation skills were largely responsible for the popularization of the theory, although the credit for the theory itself belongs mostly to Lewis. While at General Electric from 1909 to 1950, Langmuir advanced several fields of physics and chemistry, inventing the gas-filled incandescent lamp and the hydrogen welding technique. The Langmuir Laboratory for Atmospheric Research near Socorro, New Mexico, was named in his honor, as wa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tungsten
Tungsten, or wolfram, is a chemical element with the symbol W and atomic number 74. Tungsten is a rare metal found naturally on Earth almost exclusively as compounds with other elements. It was identified as a new element in 1781 and first isolated as a metal in 1783. Its important ores include scheelite and wolframite, the latter lending the element its alternate name. The free element is remarkable for its robustness, especially the fact that it has the highest melting point of all known elements barring carbon (which sublimes at normal pressure), melting at . It also has the highest boiling point, at . Its density is , comparable with that of uranium and gold, and much higher (about 1.7 times) than that of lead. Polycrystalline tungsten is an intrinsically brittle and hard material (under standard conditions, when uncombined), making it difficult to work. However, pure single-crystalline tungsten is more ductile and can be cut with a hard-steel hacksaw. Tungsten occurs in many ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Osmium
Osmium (from Greek grc, ὀσμή, osme, smell, label=none) is a chemical element with the symbol Os and atomic number 76. It is a hard, brittle, bluish-white transition metal in the platinum group that is found as a trace element in alloys, mostly in platinum ores. Osmium is the densest naturally occurring element. When experimentally measured using X-ray crystallography, it has a density of . Manufacturers use its alloys with platinum, iridium, and other platinum-group metals to make fountain pen nib tipping, electrical contacts, and in other applications that require extreme durability and hardness. Osmium is among the rarest elements in the Earth's crust, making up only 50 parts per trillion ( ppt). It is estimated to be about 0.6 parts per billion in the universe and is therefore the rarest precious metal. Characteristics Physical properties Osmium has a blue-gray tint and is the densest stable element; it is approximately twice as dense as lead and narrowly denser tha ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is toxic, even in small amounts, especially to children. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Strontium
Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to air. Strontium has physical and chemical properties similar to those of its two vertical neighbors in the periodic table, calcium and barium. It occurs naturally mainly in the minerals celestine and strontianite, and is mostly mined from these. Both strontium and strontianite are named after Strontian, a village in Scotland near which the mineral was discovered in 1790 by Adair Crawford and William Cruickshank; it was identified as a new element the next year from its crimson-red flame test color. Strontium was first isolated as a metal in 1808 by Humphry Davy using the then newly discovered process of electrolysis. During the 19th century, strontium was mostly used in the production of sugar from sugar beets (see strontian p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Radiometric Dating
Radiometric dating, radioactive dating or radioisotope dating is a technique which is used to date materials such as rocks or carbon, in which trace radioactive impurities were selectively incorporated when they were formed. The method compares the abundance of a naturally occurring radioactive isotope within the material to the abundance of its decay products, which form at a known constant rate of decay. The use of radiometric dating was first published in 1907 by Bertram Boltwood and is now the principal source of information about the absolute age of rocks and other geological features, including the age of fossilized life forms or the age of Earth itself, and can also be used to date a wide range of natural and man-made materials. Together with stratigraphic principles, radiometric dating methods are used in geochronology to establish the geologic time scale. Among the best-known techniques are radiocarbon dating, potassium–argon dating and uranium–lead dating. By al ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermal Ionization Mass Spectrometry
Thermal ionization mass spectrometry (TIMS) is also known as surface ionization and is a highly sensitive isotope mass spectrometry characterization technique. The isotopic ratios of radionuclides are used to get an accurate measurement for the elemental analysis of a sample. Singly charged ions of the sample are formed by the thermal ionization effect. A chemically purified liquid sample is placed on a metal filament which is then heated to evaporate the solvent. The removal of an electron from the purified sample is consequently achieved by heating the filament enough to release an electron, which then ionizes the atoms of the sample. TIMS utilizes a magnetic sector mass analyzer to separate the ions based on their mass to charge ratio. The ions gain velocity by an electrical potential gradient and are focused into a beam by electrostatic lenses. The ion beam then passes through the magnetic field of the electromagnet where it is partitioned into separate ion beams based on the io ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
