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Superexchange
Superexchange, or Kramers–Anderson superexchange, is the strong (usually) antiferromagnetic coupling between two next-to-nearest neighbour cations through a non-magnetic anion. In this way, it differs from direct exchange, in which there is coupling between nearest neighbor cations not involving an intermediary anion. Superexchange is a result of the electrons having come from the same donor atom and being coupled with the receiving ions' spins. If the two next-to-nearest neighbor positive ions are connected at 90 degrees to the bridging non-magnetic anion, then the interaction can be a ferromagnetic interaction. Superexchange was proposed by Hendrik Kramers in 1934, when he noticed that in crystals like MnO, there are Mn atoms that interact with one another despite having nonmagnetic oxygen atoms between them. Phillip Anderson later refined Kramers' model in 1950. A set of semi-empirical rules were developed by John B. Goodenough and in the 1950s. These rules, now referred ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hendrik Anthony Kramers
Hendrik Anthony "Hans" Kramers (17 December 1894 – 24 April 1952) was a Dutch physicist who worked with Niels Bohr to understand how electromagnetic waves interact with matter and made important contributions to quantum mechanics and statistical physics. Background and education Hans Kramers was born on 17 December 1894 in Rotterdam. the son of Hendrik Kramers, a physician, and Jeanne Susanne Breukelman. In 1912 Hans finished secondary education ( HBS) in Rotterdam, and studied mathematics and physics at the University of Leiden, where he obtained a master's degree in 1916. Kramers wanted to obtain foreign experience during his doctoral research, but his first choice of supervisor, Max Born in Göttingen, was not reachable because of the First World War. Because Denmark was neutral in this war, as was the Netherlands, he travelled (by ship, overland was impossible) to Copenhagen, where he visited unannounced the then still relatively unknown Niels Bohr. Bohr took him on as a Ph ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Double Exchange
The double-exchange mechanism is a type of a magnetic exchange that may arise between ions in different oxidation states. First proposed by Clarence Zener, this theory predicts the relative ease with which an electron may be exchanged between two species and has important implications for whether materials are ferromagnetic, antiferromagnetic, or exhibit spiral magnetism. For example, consider the 180 degree interaction of Mn- O-Mn in which the Mn "eg" orbitals are directly interacting with the O "2p" orbitals, and one of the Mn ions has more electrons than the other. In the ground state, electrons on each Mn ion are aligned according to the Hund's rule Hund's rule of maximum multiplicity is a rule based on observation of atomic spectra, which is used to predict the ground state of an atom or molecule with one or more open electronic shells. The rule states that for a given electron configuration ...: If O gives up its spin-up electron to Mn4+, its vacant orbital can then be ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Exchange Interaction
In chemistry and physics, the exchange interaction (with an exchange energy and exchange term) is a quantum mechanical effect that only occurs between identical particles. Despite sometimes being called an exchange force in an analogy to classical force, it is not a true force as it lacks a force carrier. The effect is due to the wave function of indistinguishable particles being subject to exchange symmetry, that is, either remaining unchanged (symmetric) or changing sign (antisymmetric) when two particles are exchanged. Both bosons and fermions can experience the exchange interaction. For fermions, this interaction is sometimes called Pauli repulsion and is related to the Pauli exclusion principle. For bosons, the exchange interaction takes the form of an effective attraction that causes identical particles to be found closer together, as in Bose–Einstein condensation. The exchange interaction alters the expectation value of the distance when the wave functions of two or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heisenberg Model (quantum)
The quantum Heisenberg model, developed by Werner Heisenberg, is a statistical mechanical model used in the study of critical points and phase transitions of magnetic systems, in which the spins of the magnetic systems are treated quantum mechanically. It is related to the prototypical Ising model, where at each site of a lattice, a spin \sigma_i \in \ represents a microscopic magnetic dipole to which the magnetic moment is either up or down. Except the coupling between magnetic dipole moments, there is also a multipolar version of Heisenberg model called the multipolar exchange interaction. Overview For quantum mechanical reasons (see exchange interaction or ), the dominant coupling between two dipoles may cause nearest-neighbors to have lowest energy when they are ''aligned''. Under this assumption (so that magnetic interactions only occur between adjacent dipoles) and on a 1-dimensional periodic lattice, the Hamiltonian can be written in the form :\hat H = -J \sum_^ \si ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ferromagnetic
Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials are the familiar metals noticeably attracted to a magnet, a consequence of their large magnetic permeability. Magnetic permeability describes the induced magnetization of a material due to the presence of an ''external'' magnetic field, and it is this temporarily induced magnetization inside a steel plate, for instance, which accounts for its attraction to the permanent magnet. Whether or not that steel plate acquires a permanent magnetization itself, depends not only on the strength of the applied field, but on the so-called coercivity of that material, which varies greatly among ferromagnetic materials. In physics, several different types of material magnetism are distinguished. Ferromagnetism (along with the similar effect ferrimagneti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hubbard Model
The Hubbard model is an approximate model used to describe the transition between conducting and insulating systems. It is particularly useful in solid-state physics. The model is named for John Hubbard. The Hubbard model states that each electron experiences competing forces: one pushes it to tunnel to neighboring atoms, while the other pushes it away from its neighbors. Its Hamiltonian thus has two terms: a kinetic term allowing for tunneling ("hopping") of particles between lattice sites and a potential term reflecting on-site interaction. The particles can either be fermions, as in Hubbard's original work, or bosons, in which case the model is referred to as the "Bose–Hubbard model". The Hubbard model is a useful approximation for particles in a periodic potential at sufficiently low temperatures, where all the particles may be assumed to be in the lowest Bloch band, and long-range interactions between the particles can be ignored. If interactions between particles ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Philip Warren Anderson
Philip Warren Anderson (December 13, 1923 – March 29, 2020) was an American theoretical physicist and Nobel laureate. Anderson made contributions to the theories of localization, antiferromagnetism, symmetry breaking (including a paper in 1962 discussing symmetry breaking in particle physics, leading to the development of the Standard Model around 10 years later), and high-temperature superconductivity, and to the philosophy of science through his writings on emergent phenomena. Anderson is also responsible for naming the field of physics that is now known as condensed matter physics. Education and early life Anderson was born in Indianapolis, Indiana, and grew up in Urbana, Illinois. His father, Harry Warren Anderson, was a professor of plant pathology at the University of Illinois at Urbana; his maternal grandfather was a mathematician at Wabash College, where Anderson's father studied; and his maternal uncle was a Rhodes Scholar who became a professor of English, also a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Antiferromagnetic
In materials that exhibit antiferromagnetism, the magnetic moments of atoms or molecules, usually related to the spins of electrons, align in a regular pattern with neighboring spins (on different sublattices) pointing in opposite directions. This is, like ferromagnetism and ferrimagnetism, a manifestation of ordered magnetism. The phenomenon of antiferromagnetism was first introduced by Lev Landau in 1933. Generally, antiferromagnetic order may exist at sufficiently low temperatures, but vanishes at and above the Néel temperature – named after Louis Néel, who had first identified this type of magnetic ordering. Above the Néel temperature, the material is typically paramagnetic. Measurement When no external field is applied, the antiferromagnetic structure corresponds to a vanishing total magnetization. In an external magnetic field, a kind of ferrimagnetic behavior may be displayed in the antiferromagnetic phase, with the absolute value of one of the sublattice magne ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Scalar Product
In mathematics, the dot product or scalar productThe term ''scalar product'' means literally "product with a scalar as a result". It is also used sometimes for other symmetric bilinear forms, for example in a pseudo-Euclidean space. is an algebraic operation that takes two equal-length sequences of numbers (usually coordinate vectors), and returns a single number. In Euclidean geometry, the dot product of the Cartesian coordinates of two vectors is widely used. It is often called the inner product (or rarely projection product) of Euclidean space, even though it is not the only inner product that can be defined on Euclidean space (see Inner product space for more). Algebraically, the dot product is the sum of the products of the corresponding entries of the two sequences of numbers. Geometrically, it is the product of the Euclidean magnitudes of the two vectors and the cosine of the angle between them. These definitions are equivalent when using Cartesian coordinates. In ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hamiltonian (quantum Mechanics)
Hamiltonian may refer to: * Hamiltonian mechanics, a function that represents the total energy of a system * Hamiltonian (quantum mechanics), an operator corresponding to the total energy of that system ** Dyall Hamiltonian, a modified Hamiltonian with two-electron nature ** Molecular Hamiltonian, the Hamiltonian operator representing the energy of the electrons and nuclei in a molecule * Hamiltonian (control theory), a function used to solve a problem of optimal control for a dynamical system * Hamiltonian path, a path in a graph that visits each vertex exactly once * Hamiltonian group, a non-abelian group the subgroups of which are all normal * Hamiltonian economic program The Hamiltonian economic program was the set of measures that were proposed by American Founding Father and first Secretary of the Treasury Alexander Hamilton in four notable reports and implemented by the US Congress during George Washington's ..., the economic policies advocated by Alexander Hamilton ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perturbation Theory
In mathematics and applied mathematics, perturbation theory comprises methods for finding an approximate solution to a problem, by starting from the exact solution of a related, simpler problem. A critical feature of the technique is a middle step that breaks the problem into "solvable" and "perturbative" parts. In perturbation theory, the solution is expressed as a power series in a small parameter The first term is the known solution to the solvable problem. Successive terms in the series at higher powers of \varepsilon usually become smaller. An approximate 'perturbation solution' is obtained by truncating the series, usually by keeping only the first two terms, the solution to the known problem and the 'first order' perturbation correction. Perturbation theory is used in a wide range of fields, and reaches its most sophisticated and advanced forms in quantum field theory. Perturbation theory (quantum mechanics) describes the use of this method in quantum mechanics. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Clarence Zener
Clarence Melvin Zener (December 1, 1905 – July 2, 1993) was the American physicist who first (1934) described the property concerning the breakdown of electrical insulators. These findings were later exploited by Bell Labs in the development of the Zener diode, which was duly named after him. Zener was a theoretical physicist with a background in mathematics who conducted research in a wide range of subjects including: superconductivity, metallurgy, ferromagnetism, elasticity, fracture mechanics, diffusion, and geometric programming. Life Zener was born in Indianapolis, Indiana and earned his PhD in physics under Edwin Kemble at Harvard in 1929. His thesis was titled ''Quantum Mechanics of the Formation of Certain Types of Diatomic Molecules''. In 1957 he received the Bingham Medal for his work in rheology, in 1959 the John Price Wetherill Medal from The Franklin Institute, in 1965 the Albert Souveur Achievement Award, in 1974 the Gold Medal from American Society for Metal ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
