Sulfate Crust
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Sulfate Crust
Sulfate crust is a zone observed in the axial (central) parts of burning coal dumps and related sites. It is a zone built mainly by anhydrous sulfate minerals, such as godovikovite and millosevichite. The outer zone can easily be hydrated giving rise to minerals like tschermigite and alunogen. The zone forms due to interaction with hot (even around 600 °C) coal-derived gases (mainly and ) with the "sterile" material (i.e. shales and other rocks serving as the source of , , and other cations) in case of the lack of vents for the gases to escape into the atmosphere.Sokol E. V., Maksimova N. V., Nigmatulina E. N., Sharygin V. V. and Kalugin V. M. 2005: Combustion metamorphism. Publishing House of the SB RAS, Novosibirsk See also * Coal seam fire A coal-seam fire is a burning of an outcrop or underground coal seam. Most coal-seam fires exhibit smouldering combustion, particularly underground coal-seam fires, because of limited atmospheric oxygen availability. Coal-seam ...
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Coal Fire
Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dead plant matter decays into peat and is converted into coal by the heat and pressure of deep burial over millions of years. Vast deposits of coal originate in former wetlands called coal forests that covered much of the Earth's tropical land areas during the late Carboniferous ( Pennsylvanian) and Permian times. Many significant coal deposits are younger than this and originate from the Mesozoic and Cenozoic eras. Coal is used primarily as a fuel. While coal has been known and used for thousands of years, its usage was limited until the Industrial Revolution. With the invention of the steam engine, coal consumption increased. In 2020, coal supplied about a quarter of the world's primary energy and over a third of its electricity. Some iron a ...
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Coal
Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dead plant matter decays into peat and is converted into coal by the heat and pressure of deep burial over millions of years. Vast deposits of coal originate in former wetlands called coal forests that covered much of the Earth's tropical land areas during the late Carboniferous ( Pennsylvanian) and Permian times. Many significant coal deposits are younger than this and originate from the Mesozoic and Cenozoic eras. Coal is used primarily as a fuel. While coal has been known and used for thousands of years, its usage was limited until the Industrial Revolution. With the invention of the steam engine, coal consumption increased. In 2020, coal supplied about a quarter of the world's primary energy and over a third of its electricity. Some iron ...
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Sulfate
The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many are prepared from that acid. Spelling "Sulfate" is the spelling recommended by IUPAC, but "sulphate" was traditionally used in British English. Structure The sulfate anion consists of a central sulfur atom surrounded by four equivalent oxygen atoms in a tetrahedral arrangement. The symmetry is the same as that of methane. The sulfur atom is in the +6 oxidation state while the four oxygen atoms are each in the −2 state. The sulfate ion carries an overall charge of −2 and it is the conjugate base of the bisulfate (or hydrogensulfate) ion, , which is in turn the conjugate base of , sulfuric acid. Organic sulfate esters, such as dimethyl sulfate, are covalent compounds and esters of sulfuric acid. The tetrahedral molecular geometry of th ...
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Godovikovite
Godovikovite is a rare sulfate mineral with the chemical formula: (NH4)Al(SO4)2. Aluminium can partially be substituted by iron. Hydration of godovikovite gives the ammonium alum, tschermigite. The mineral forms cryptocrystalline, often porous, masses, usually of white colour. Single crystals are very small hexagonal blades. Typical environment for godovikovite are burning coal sites (mainly dumps). There the mineral acts, together with millosevichite, as one of the main components of so-called sulfate crust.Jambor J. L. and Grew E. S. 1990: New mineral names. American Mineralogist, 76, pp. 240-246 It was first described in 1988 for an occurrence in the Chelyabinsk coal basin, Chelyabinsk Oblast, Southern Urals The Ural Mountains ( ; rus, Ура́льские го́ры, r=Uralskiye gory, p=ʊˈralʲskʲɪjə ˈɡorɨ; ba, Урал тауҙары) or simply the Urals, are a mountain range that runs approximately from north to south through European ..., Russia, and named f ...
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Millosevichite
Millosevichite is a rare sulfate mineral with the chemical formula Al2(SO4)3. Aluminium is often substituted by iron. It forms finely crystalline and often porous masses. It was first described in 1913 for an occurrence in Grotta dell'Allume, Porto Levante, Vulcano Island, Lipari, Aeolian Islands, Sicily. It was named for Italian mineralogist Federico Millosevich (1875–1942) of the University of Rome. The mineral is mainly known from burning coal dumps, acting as one of the main minerals forming sulfate crust. It can be also found in volcanic solfatara environments.Chesnokov B. V. and Shcherbakova E. P. 1991: Mineralogiya gorelykh otvalov Chelyabinskogo ugolnogo basseina - opyt mineralogii tekhnogenesa. Nauka, Moscow It occurs with native sulfur, sal ammoniac, letovicite, alunogen Alunogen (from French ''alun'', “ alum”), also called feather alum and hair salt is a colourless to white (although often coloured by impurities, such as iron substituting for aluminium) fibrous t ...
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Tschermigite
Tschermigite is a mineral form of ammonium alum, formula N H4 Al( S O4)2·12(H2O). It is found in burning coal seams, bituminous shale and fumaroles. Because of its extreme water solubility it is unlikely to persist except in the dryest of conditions. Discovered in 1852 at Cermiky, also known as Tschermig in Bohemia Bohemia ( ; cs, Čechy ; ; hsb, Čěska; szl, Czechy) is the westernmost and largest historical region of the Czech Republic. Bohemia can also refer to a wider area consisting of the historical Lands of the Bohemian Crown ruled by the Bohem .... It is colorless and named for where it was discovered. References Ammonium minerals Aluminium minerals Sulfate minerals Cubic minerals Minerals in space group 205 {{sulfate-mineral-stub ...
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Alunogen
Alunogen (from French ''alun'', “alum”), also called feather alum and hair salt is a colourless to white (although often coloured by impurities, such as iron substituting for aluminium) fibrous to needle-like aluminium sulfate mineral. It has the chemical formula Al2(SO4)3·17H2O. It is often found on the walls of mines and quarries as a secondary mineral. It can be found in the oxidation zones of some ore deposits as well as on burning coal dumps (i.e., as the product of millosevichite hydration). It also forms as a low temperature deposit in fumaroles. It occurs associated with pyrite, marcasite, halotrichite, pickeringite, epsomite, potash alum, melanterite and gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywall. .... The crystallochemical formula, can be written as: l(H2O) ...
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Ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous waste, particularly among aquatic organisms, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to 45% of the world's food and fertilizers. Around 70% of ammonia is used to make fertilisers in various forms and composition, such as urea and Diammonium phosphate. Ammonia in pure form is also applied directly into the soil. Ammonia, either directly or indirectly, is also a building block for the synthesis of many pharmaceutical products and is used in many commercial cleaning products. It is mainly collected by downward displacement of both air and water. Although common in nature—both terrestrially and in the outer planets of the Solar System—and in wide use, ammonia is both caust ...
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Sulfur Trioxide
Sulfur trioxide (alternative spelling sulphur trioxide, also known as ''nisso sulfan'') is the chemical compound with the formula SO3. It has been described as "unquestionably the most important economically" sulfur oxide. It is prepared on an industrial scale as a precursor to sulfuric acid. Sulfur trioxide exists in several forms - gaseous monomer, crystalline trimer, and solid polymer. Sulfur trioxide is a solid at just below room temperature with a relatively narrow liquid range. Gaseous SO3 is the primary precursor to acid rain. Molecular structure and bonding Monomer The molecule SO3 is trigonal planar. As predicted by VSEPR theory, its structure belongs to the D3h point group. The sulfur atom has an oxidation state of +6 and may be assigned a formal charge value as low as 0 (if all three sulfur-oxygen bonds are assumed to be double bonds) or as high as +2 (if the Octet Rule is assumed). When the formal charge is non-zero, the S-O bonding is assumed to be delocalized. In a ...
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Coal Seam Fire
A coal-seam fire is a burning of an outcrop or underground coal seam. Most coal-seam fires exhibit smouldering combustion, particularly underground coal-seam fires, because of limited atmospheric oxygen availability. Coal-seam fire instances on Earth date back several million years. Due to thermal insulation and the avoidance of rain/snow extinguishment by the crust, underground coal-seam fires are the most persistent fires on Earth and can burn for thousands of years, like Burning Mountain in Australia. Coal-seam fires can be ignited by self-heating of low-temperature oxidation, lightning, wildfires and even arson. Coal-seam fires have been slowly shaping the lithosphere and changing atmosphere, but this pace has become faster and more extensive in modern times, triggered by mining. Coal fires are a serious health and safety hazard, affecting the environment by releasing toxic fumes, reigniting grass, brush, or forest fires, and causing subsidence of surface infrastructure s ...
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Coal
Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dead plant matter decays into peat and is converted into coal by the heat and pressure of deep burial over millions of years. Vast deposits of coal originate in former wetlands called coal forests that covered much of the Earth's tropical land areas during the late Carboniferous ( Pennsylvanian) and Permian times. Many significant coal deposits are younger than this and originate from the Mesozoic and Cenozoic eras. Coal is used primarily as a fuel. While coal has been known and used for thousands of years, its usage was limited until the Industrial Revolution. With the invention of the steam engine, coal consumption increased. In 2020, coal supplied about a quarter of the world's primary energy and over a third of its electricity. Some iron ...
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Coal Mining
Coal mining is the process of extracting coal from the ground. Coal is valued for its energy content and since the 1880s has been widely used to generate electricity. Steel and cement industries use coal as a fuel for extraction of iron from iron ore and for cement production. In the United Kingdom and South Africa, a coal mine and its structures are a colliery, a coal mine is called a 'pit', and the above-ground structures are a 'pit head'. In Australia, "colliery" generally refers to an underground coal mine. Coal mining has had many developments in recent years, from the early days of men tunneling, digging and manually extracting the coal on carts to large open-cut and longwall mines. Mining at this scale requires the use of draglines, trucks, conveyors, hydraulic jacks and shearers. The coal mining industry has a long history of significant negative environmental impacts on local ecosystems, health impacts on local communities and workers, and contributes heavily to th ...
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