Sulfate Chloride
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Sulfate Chloride
The sulfate chlorides are double salts containing both sulfate (SO42–) and chloride (Cl–) anions. They are distinct from the chlorosulfates, which have a chlorine atom attached to the sulfur as the ClSO3− anion. Many minerals in this family exist. Many are found associated with volcano A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plates are ...es and fumaroles. As minerals they are included in the Nickel-Strunz classification group 7.DG. The book ''Hey's Chemical Index of Minerals'' groups these in subgroup 12.2. List Artificial Some "chloride sulfates" are sold as solutions in water and used for water treatment. these include ferric chloride sulfate and polyaluminium sulfate chloride. The solutions may also be called "chlorosulfates" even though they do not contain a chlo ...
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Sulfate
The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many are prepared from that acid. Spelling "Sulfate" is the spelling recommended by IUPAC, but "sulphate" was traditionally used in British English. Structure The sulfate anion consists of a central sulfur atom surrounded by four equivalent oxygen atoms in a tetrahedral arrangement. The symmetry is the same as that of methane. The sulfur atom is in the +6 oxidation state while the four oxygen atoms are each in the −2 state. The sulfate ion carries an overall charge of −2 and it is the conjugate base of the bisulfate (or hydrogensulfate) ion, , which is in turn the conjugate base of , sulfuric acid. Organic sulfate esters, such as dimethyl sulfate, are covalent compounds and esters of sulfuric acid. The tetrahedral molecular geometry of th ...
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Gordaite
Gordaite is a sulfate mineral composed primarily of hydrous zinc sodium sulfate chloride hydroxide with formula: NaZn4(SO4)(OH)6Cl·6H2O. It was named for the discovery location in the Sierra Gorda district of Chile. Gordaite forms as tabular trigonal crystals. Gordaite first appeared after a research dive in September 1984 from the Juan de Fuca Ridge of the northeastern side of the Pacific Ocean. Gordaite was also described from weathered slag deposits as a result of copper smelting in Hettstedt, Germany.Nasdala, L., Witzke, T., Ullrich, B. and Brett, R. (1998): Gordaite n4Na(OH)6(SO4)Cl•6H2O second occurrence in the Juan de Fuca Ridge, and new data. American Mineralogist 83, pg. 1111-1116. The mineral exhibits a hexagonal shape with clear or white (green if cuprian – Cu2+) crystals ranging from planar to broad habit and has a point group of . Gordaite commonly occurs near minerals such as sphalerite, boleite and gypsum. The most recent finding occurred in the San Francisco ...
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Adranosite
Adranosite is a mineral discovered in the La Fossa crater, Vulcano, Aeolian Islands, Italy, with the formula (NH4)4NaAl2(SO4)4Cl(OH)2. Adranosite-(Fe) is the Fe3+ analogue of adranosite, with the formula (NH4)4NaFe2(SO4)4Cl(OH)2.Mitolo, Donatella, et al. "Adranosite-(Fe),(NH4) 4NaFe2 (SO4) 4Cl (OH) 2, a new ammonium sulfate chloride from La Fossa Crater, Vulcano, Aeolian Islands, Italy." The Canadian Mineralogist 51.1 (2013): 57-66. References minerals {{Mineral-stub ...
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Aiolosite
Aiolosite ( IMA symbol: Aio) is a rare sodium bismuth sulfate mineral with the chemical formula NaBi(SO)Cl. Its type locality is Vulcano, Sicily, Italy. Its name comes from the Greek name Aeolus In Greek mythology, Aeolus or Aiolos (; grc, Αἴολος , ) is a name shared by three mythical characters. These three personages are often difficult to tell apart, and even the ancient mythographers appear to have been perplexed about which A ....Aiolosite
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Aiolosite data sheet
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Aubertite
Aubertite is a mineral with the chemical formula CuAl(SO4)2Cl·14H2O. It is colored blue. Its crystals are triclinic pedial. It is transparent. It has vitreous luster. It is not radioactive. Aubertite is rated 2-3 on the Mohs Scale. The sample was collected by J. Aubert (born 1929), assistant director, National Institute of Geophysics, France, in the year 1961. Its type locality is Queténa Mine, Toki Cu deposit, Chuquicamata District, Calama, El Loa Province, Antofagasta Region, Chile Chile, officially the Republic of Chile, is a country in the western part of South America. It is the southernmost country in the world, and the closest to Antarctica, occupying a long and narrow strip of land between the Andes to the east a .... ReferencesWebmineral.com - Aubertite
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Xitieshanite
Xitieshanite is a hydrous iron sulfate–chloride mineral with chemical formula: Fe3+(SO4)Cl·6(H2O). It was discovered in 1983 and named for the discovery location of Xitieshan lead/zinc ore deposit in the Qinghai Province, China. It was approved by the IMA in the year of its discovery. The mineral has also been reported in 2005 from acid mine drainage from a coal mine in Green Valley, Vigo County, Indiana Vigo County ( ) is a county on the western border of the U.S. state of Indiana. According to the 2020 United States Census, it had a population of 105,994 . Its county seat is Terre Haute. Vigo County is included in the Terre Haute metropolita ....Melchiorre, Erik, et al., ''A new occurrence of xitieshanite e3+(SO4)Cl·6H2Ocrystals in acid-mine seepways, Green Valley, Vigo County, Indiana, U.S.A.,'' American Mineralogist, v. 90 no. 10 p. 1518-1521, 2005 Properties Xitieshanite mainly consists of oxygen (56.14%) and iron (17.82%), but otherwise contains chlorine (11.3 ...
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