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Season Cracking
Season cracking is a form of stress-corrosion cracking of brass cartridge cases originally reported from British forces in India. During the monsoon season, military activity was temporarily reduced, and ammunition was stored in stables until the dry weather returned. Many brass cartridges were subsequently found to be cracked, especially where the case was crimped to the bullet. It was not until 1921 that the phenomenon was explained by Moor, Beckinsale and Mallinson: ammonia from horse urine, combined with the residual stress in the cold-drawn metal of the cartridges, was responsible for the cracking. Season cracking is characterised by deep brittle cracks which penetrate into affected components. If the cracks reach a critical size, the component can suddenly fracture, sometimes with disastrous results. However, if the concentration of ammonia is very high, then attack is much more severe, and attack over all exposed surfaces occurs. The problem was solved by annealing the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Brass SCC2
Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different mechanical, electrical, and chemical properties. It is a substitutional alloy: atoms of the two constituents may replace each other within the same crystal structure. Brass is similar to bronze, another copper alloy, that uses tin instead of zinc. Both bronze and brass may include small proportions of a range of other elements including arsenic (As), lead (Pb), phosphorus (P), aluminium (Al), manganese (Mn), and silicon (Si). Historically, the distinction between the two alloys has been less consistent and clear, and modern practice in museums and archaeology increasingly avoids both terms for historical objects in favor of the more general "copper alloy". Brass has long been a popular material for decoration due to its bright, gold-like appearance; being used for drawer pulls and doorknobs. It has also been widely used to make utensils because of its low melting ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bronze
Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals (including aluminium, manganese, nickel, or zinc) and sometimes non-metals, such as phosphorus, or metalloids such as arsenic or silicon. These additions produce a range of alloys that may be harder than copper alone, or have other useful properties, such as ultimate tensile strength, strength, ductility, or machinability. The three-age system, archaeological period in which bronze was the hardest metal in widespread use is known as the Bronze Age. The beginning of the Bronze Age in western Eurasia and India is conventionally dated to the mid-4th millennium BCE (~3500 BCE), and to the early 2nd millennium BCE in China; elsewhere it gradually spread across regions. The Bronze Age was followed by the Iron Age starting from about 1300 BCE and reaching most of Eurasia by about 500 BCE, although bronze continued to be much more widely used than it is in mod ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reliability Engineering
Reliability engineering is a sub-discipline of systems engineering that emphasizes the ability of equipment to function without failure. Reliability describes the ability of a system or component to function under stated conditions for a specified period of time. Reliability is closely related to availability, which is typically described as the ability of a component or system to function at a specified moment or interval of time. The reliability function is theoretically defined as the probability of success at time t, which is denoted R(t). This probability is estimated from detailed (physics of failure) analysis, previous data sets or through reliability testing and reliability modelling. Availability, testability, maintainability and maintenance, repair and operations, maintenance are often defined as a part of "reliability engineering" in reliability programs. Reliability often plays the key role in the cost-effectiveness of systems. Reliability engineering deals with the p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Engineering Concepts
Engineering is the use of scientific principles to design and build machines, structures, and other items, including bridges, tunnels, roads, vehicles, and buildings. The discipline of engineering encompasses a broad range of more specialized fields of engineering, each with a more specific emphasis on particular areas of applied mathematics, applied science, and types of application. See glossary of engineering. The term ''engineering'' is derived from the Latin ''ingenium'', meaning "cleverness" and ''ingeniare'', meaning "to contrive, devise". Definition The American Engineers' Council for Professional Development (ECPD, the predecessor of ABET) has defined "engineering" as: The creative application of scientific principles to design or develop structures, machines, apparatus, or manufacturing processes, or works utilizing them singly or in combination; or to construct or operate the same with full cognizance of their design; or to forecast their behavior under specific ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion. In the most common use of the word, this means electrochemical oxidation of metal in reaction with an oxidant such as oxygen, hydrogen or hydroxide. Rusting, the formation of iron oxides, is a well-known example of electrochemical corrosion. This type of damage typically produces oxide(s) or salt(s) of the original metal and results in a distinctive orange colouration. Corrosion can also occur in materials other than metals, such as ceramics or polymers, although in this context, the term "degradation" is more common. Corrosion degrades the useful properties of materials and structures including strength, appearance and permeability to liquids and gases. Many structural ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hairline Crack
A stress fracture is a fatigue-induced bone fracture caused by repeated stress over time. Instead of resulting from a single severe impact, stress fractures are the result of accumulated injury from repeated submaximal loading, such as running or jumping. Because of this mechanism, stress fractures are common overuse injuries in athletes. Stress fractures can be described as small cracks in the bone, or hairline fractures. Stress fractures of the foot are sometimes called "march fractures" because of the injury's prevalence among heavily marching soldiers. Stress fractures most frequently occur in weight-bearing bones of the lower extremities, such as the tibia and fibula (bones of the lower leg), metatarsal and navicular bones (bones of the foot). Less common are stress fractures to the femur, pelvis, and sacrum. Treatment usually consists of rest followed by a gradual return to exercise over a period of months. Signs and symptoms Stress fractures are typically discovered after ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Schweizer's Reagent
Schweizer's reagent is the metal ammine complex with the formula u(NH3)4(H2O)2OH)2. This deep-blue compound is used in purifying cellulose. It is prepared by precipitating copper(II) hydroxide from an aqueous solution of copper sulfate using sodium hydroxide or ammonia, then dissolving the precipitate in a solution of ammonia. It forms an azure solution. Evaporation of these solutions leaves light blue residue of copper hydroxide, reflecting the lability of the copper-ammonia bonding. If conducted under a stream of ammonia, then deep blue needle-like crystals of the tetrammine form. In presence of oxygen, concentrated solutions give rise to nitrites Cu(NO2)2(NH3)''n''. The nitrite results from oxidation of the ammonia. Reactions with cellulose Schweizer's reagent was once used in production of cellulose products such as rayon and cellophane (see cupro). Cellulose, which is quite insoluble in water (hence its utility as clothing), dissolves in the presence of Schweizer's reagent ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Copper(II) Oxide
Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite. It is a product of copper mining and the precursor to many other copper-containing products and chemical compounds. Production It is produced on a large scale by pyrometallurgy, as one stage in extracting copper from its ores. The ores are treated with an aqueous mixture of ammonium carbonate, ammonia, and oxygen to give copper(I) and copper(II) ammine complexes, which are extracted from the solids. These complexes are decomposed with steam to give CuO. It can be formed by heating copper in air at around 300–800°C: : 2 Cu + O2 → 2 CuO For laboratory uses, pure copper(II) oxide is better prepared by heating copper(II) nitrate, copper(II) hydroxide, or basic copper(II) carbonate: : 2 Cu(NO3)2(s) → 2 CuO(s) + 4 NO2(g) + O2(g) (180° ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rayon
Rayon is a semi-synthetic fiber, made from natural sources of regenerated cellulose, such as wood and related agricultural products. It has the same molecular structure as cellulose. It is also called viscose. Many types and grades of viscose fibers and films exist. Some imitate the feel and texture of natural fibers such as silk, wool, cotton, and linen. The types that resemble silk are often called artificial silk. The fibre is used to make textiles for clothing and other purposes. Rayon production involves solubilizing cellulose to allow turning the fibers into required form. Three common ways to solubilize are the cuprammonium process, not in use today, using ammoniacal solutions of copper salts; the viscose process, the most common today, using alkali and carbon sulfide; and the Lyocell process, using amine oxide. The last avoids the neurotoxic carbon sulfide of the viscose process but is also more expensive. Rayon and its variants Rayon is produced by dissolving cel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cuprammonium
Schweizer's reagent is the metal ammine complex with the formula u(NH3)4(H2O)2OH)2. This deep-blue compound is used in purifying cellulose. It is prepared by precipitating copper(II) hydroxide from an aqueous solution of copper sulfate using sodium hydroxide or ammonia, then dissolving the precipitate in a solution of ammonia. It forms an azure solution. Evaporation of these solutions leaves light blue residue of copper hydroxide, reflecting the lability of the copper-ammonia bonding. If conducted under a stream of ammonia, then deep blue needle-like crystals of the tetrammine form. In presence of oxygen, concentrated solutions give rise to nitrites Cu(NO2)2(NH3)''n''. The nitrite results from oxidation of the ammonia. Reactions with cellulose Schweizer's reagent was once used in production of cellulose products such as rayon and cellophane (see cupro). Cellulose, which is quite insoluble in water (hence its utility as clothing), dissolves in the presence of Schweizer's reagent ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Stress-corrosion Cracking
Stress corrosion cracking (SCC) is the growth of crack formation in a corrosive environment. It can lead to unexpected and sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. SCC is highly chemically specific in that certain alloys are likely to undergo SCC only when exposed to a small number of chemical environments. The chemical environment that causes SCC for a given alloy is often one which is only mildly corrosive to the metal. Hence, metal parts with severe SCC can appear bright and shiny, while being filled with microscopic cracks. This factor makes it common for SCC to go undetected prior to failure. SCC often progresses rapidly, and is more common among alloys than pure metals. The specific environment is of crucial importance, and only very small concentrations of certain highly active chemicals are needed to produce catastrophic cracking, often leading to devastating and unexpected failure.ASM Internation ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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